Sharif Digital Repository

Due to advances of biotechnology, control of bioprocess has become very important. The goal of this project is to simulate the acetic acid production bioreactor and designing an adaptive PI controller for this reactor. For this goal, a suitable model has been selected from the literature and simulation has shown that the system has a nonlinear dynamical behavior. In order to control the system in a wide range of operating conditions, the adaptive PI controller was designed. In single input-single output case, the concentration of the product is controlled in such a way that the production rate is maximized, assuming that the pH and temperature are kept constant. Then a two input-two... 

Due to the successful experience gained in the process intensification and implementation of Reactive Distillation and Divided Wall Column in industry, Reactive Divided Wall Column have also been considered as a further step in process intensification. One important research area in implementation of RDWCs is their control issue. In the present study, the dynamic simulation of reactive divided wall columns and their control were studied and the adaptive model predictive control was used for the control objectives. Aspen Dynamics software was used for simulation and MATLAB software was utilized for applying the control strategy. The advantage of the applied control method is the use of... 

Oxidative desulfurization (ODS) is one of the desulfurization processes that posseses several important advantages such as mild operating conditions. In the present work, oxidative desulfurization of kerosene with a total sulfur content of 2335 ppm and gas oil with a total sulfur content of 7990 ppm were carefully investigated. By evaluation of different oxidation systems, the hydrogen peroxide-formic acid system was selected for the oxidation of sulfur-containing compounds of the light fuel oils. The effects of main operating parameters of the oxidation system including temperature, hydrogen peroxide to sulfur molar ratio (O/S), and formic acid to sulfur molar ratio (Acid/S) on the... 

The PID controller has been widely used in the industry for many years because of its simple structure and satisfactory performance. If the process is time-varying or has a nonlinear dynamic, the PID controller with constant parameters can not control the process in a wide range of operation and adaptive PID controller should be used. In this thesis, two adaptive controllers proposed in the literature, one for multi-input multi-output (MIMO) affine nonlinear systems and another for single-input single-output (SISO) non-affine nonlinear systems both in the normal form that both of them are extended in to the general form. The latter extended controller includes the MIMO systems. The main... 

Since, presence of sulfur compounds in fuels leads to environmental pollution and deacrese of fuel quality, fuel desulfurization should be considered for enhancing the fuel charachteristics. Electrochemical desulfurization was recogonized as one of desulfurization techniques that uses anode and cathode in an electrolytic environment under mild temperature and pressure. In this research, electrochemical desulfurization of crude gas-oil has been studied over electrodes of copper and stainless steel in the presence of NaOH and sulfuric acid. In this research, the effects of operational prameters like stirring rate, temperature, applied potential, sodium hydroxide/sulfuric acid addition as... 

Most of the Iranian oil reservoirs are reaching end of their natural production life, hence they are suitable candidates for EOR common processes like gas injection and WAG injection. Studies have shown that gas and WAG injection can be applied for optimal oil production. Past studies have been mainly on gas and WAG injection in immiscible or fully miscible conditions and there is a limited amount of data available on performance of these methods in near miscible conditions. Miscible injection is not feasible in old Iranian oil reservoirs due to their depleted pressure. Moreover injection in lower pressures is attractive from both economical and operational standpoints since this reduces the... 

In this work, nanoparticle production via microemulsion method has been investigated from theoretical and experimental points of view. Population balance approach has been used to model nanoparticle formation in an inverse microemulsion system. The study of nanoparticle formation in the inverse microemulsion system of Marlipal O13/40-cyclohexane-water reveals that in low reactants concentrations, the coagulation phenomenon has an important effect on the formation of particles. In this regard, the population balance equations has been developed to consider the coagulation phenomenon in the inverse microemulsion system. The kernel of coagulation has been calculated based on attractive and... 

Because of lower energy consumption and lower capital cost, divided wall columns attracted wide attention. The main challenge of these units is their controllability. In this thesis dynamic simulation and control of a divided wall column is investigated and an adaptive model predictive controller has been used for control purpose. For dynamic simulation the Aspen Dynamics software and for applying control strategy the MATLAB software have been utilized. The model used for model predictive controller has been obtained by using open loop responses of the system. The main advantage of presented work over the existing ones is using the input-output transfer function of the system model instead... 

Due to the high cost and destructive effects of fossil fuels, the biogas production as a renewable and environmentally friendly fuel attracted much attention. In this regard, several targets are considered in this research. First, in order to increase of biogas production yield and accelerating the rate limiting steps in anaerobic digestion of wheat straw (lignocellulosic feedstock), the effect of additives containing trace elements (Fe and Ni) in form of nanoparticles and their salts was investigated through batch experiments. The results showed that addition of nanoparticles or salts resulted in the increase of methane production rate during the first 4 days of experiments. Then, a... 

Researchers have paid more attention to greenhouse cultivation, due to the exacerbation of food and water crisis. Higher production with lower cost could be achieved through greenhouse climate control (temperature, humidity, carbon dioxide concentration). However, greenhouse climate control is a challenging task, because greenhouses have highly interactive nonlinear dynamics and model uncertainties and are subject to input saturation. In light of the fact that Iran is a country with a warm and arid climate, tunnel greenhouses equipped with evaporative cooling system are very common in Iran. Accordingly, this type of greenhouse is considered for modelling, simulation and control in this... 

In this research work, to enhance the performance of the conventional spinning disk reactors, a novel type of spinning disk reactor has been proposed and tested successfully through the synthesis of barium sulfate nanoparticles by means of the reactive precipitation. This reactor consists of two coaxial rotating disks placed horizontally in a cylindrical chamber. The experimental results clearly indicate the capability of the proposed reactor in the synthesis of nanoparticles with the smaller mean particle size and the narrower particle size distribution compared to those obtained in various process intensification devices such that barium sulfate nanoparticles with a mean particle size of... 

This project presents algorithms for intelligent control of the viral load in a HIV-1 infection model. The first part of thesis was dedicated to the study of the three states model adopted to describe the HIV-1 infection. A sensitivity analysis of the model parameters was described and computer simulations were provided to show the influence of the parameters explicitly. Then, an internal model control based on neural networks was implemented on the introduced infection model with including the RTIs and PIs drugs efficacies as control input. A stable adaptive neuro-control approach was presented for affine in the control nonlinear dynamical systems, whose nonlinearities were assumed to be... 

The increasing advancement of computed tomography (CT) systems has led to the recognition of this type of imaging as an accurate and reliable method in diagnosing and assessing damage to humans and materials. Adding dual energy imaging to these systems can increase the material's ability to differentiate in this system and provide higher contrast than usual. Recently, a medical imaging technique has been introduced that uses an X-ray tube and two detector layers on top of each other, each layer absorbing a different energy spectrum.dual layer computed tomography system has been introduced today as a suitable tool for evaluating and diagnosing many diseases, due to the reliability and... 

Defending software against different types of attacks is challenging enough, but for server-side programs it is even harder. The ever-changing nature of technologies used on server-side programs makes it more complex. In this thesis we try to identify these challenges in regard to two specific technologies: multi-service architectures and asynchronous I/O. Then, we present a new framework for running software in asynchronous multi-service architectures with native support for access control rules. Our framework acts as an intermediate between services and can support rules based on the distributed request context that exists between services.
 

Oxidative coupling of methane (OCM) in a fixed bed tubular reactor over Mn-Na2WO4/SiO2 catalyst has been studied. Four kinetic models have been considered for OCM reactions. Based on an objective function and using genetic algorithm, kinetic parameters have been estimated. A reactor tube with 20 mm diameter and 400 mm length surrounded by molten salt for removing heat of reaction has been used for experimental study. Effects of different factors such as CH4/O2 ratio, nitrogen content in feed and contact time are investigated experimentally and by simulation. A good agreement has been observed between simulation and experimental data. Oxidative coupling of methane (OCM) in an industrial fixed... 

In this project, inverse emulsion polymerization (IEP) modeling of poly acrylamid (PAM) using population balance equations (PBEs) has been performed. For this porpuse zero-one and pseudo- bulk models and hybrid model including the zero-one and pseudo- bulk are applied based on the process conditions. The effects of surfactant steric barrier and surfactant reaction with radicals including monomeric radicals on the radical entry rate into the particle have been taken into account for these models. In the modeling, coagulation phenomenon was included by considering the effects of non-DLVO forces such as hydration and steric forces in addition to the DLVO forces. Simulation results for zero-... 

Infrastructural costs of data management, have led people and organizations to outsource their data. This approach is facing with some significant security challenges and risks. The goal of this research, is to present an architecture for secure outsourcing of data in a way that used methods, storage processes, query processing methods and access control mechanisms work together to preserve confidentiality and integrity of outsourced data. In this architecture, the main challenge is transparent placement of some components between client and server in order to prevent user from being aware of communication with a secured server. In order to create this degree of transparency, we need to pay...