Sharif Digital Repository

In this study, a multivariate-based strategy was developed for simultaneous determination of thirteen carcinogenic polycyclic aromatic hydrocarbons (PAHs) in water samples using gold nanoparticles (AuNPs) as solid-phase extraction (SPE) sorbent combined with gas chromatography-flame ionization detector (GC-FID). The extraction technique is based on the strong affinity between citrate capped AuNPs and PAHs. Furthermore, characterization of AuNPs was performed by UV-Vis and TEM techniques. A rotatable central composite design (CCD) combined with multiple linear regression (MLR) was used for designing the extraction procedure and developing models using the GC peak areas of 13 PAHs. Also,... 

In this thesis, the mechanical properties of collagen hydrogels were characterized using Finite Element method and the collagen content effect on the mechanical properties of hydrogels were investigated. Hydrogels samples with different collagen content were assessed which caused diverse mechanical behaviors. Due to the nonlinear behavior of hydrogels, using numerical methods and simulation softwars can be helpful to determine the mechanical properties of these material and save agreat deal of time. Finite Viscoelaticity theory was exploited for a UMAT Subroutine in Abaqus and an special Starin Energy Function was selected to extract the formulations. The agreement between simulation results... 

The purpose of this thesis is sliding mode control of a roll-pitch seeker by considering the zenith pass problem. This problem takes place when the target appears in front of the seeker’s head. First, the mathematical model of the roll and pitch frames is obtained by the Newton-Euler equations of motion. Then, a MIMO sliding mode controller is designed. The performance of the controller is investigated in the presence of model uncertainties and seeker disturbances. The results indicate that the designed controller is robust enough and provides a suitable performance in the stabilization, tracking and guidance loops.
 

Solvent-solvent and solute-solvent interactions were investigated in mixtures of Triton X-100 with water, methanol, ethanol, 1-propanol, tetrahydrofuran and butyl acetate. Solvatochromic parameters, including normalized polarity (E_T^N), dipolarity-polarizability (), hydrogen-bond donar (), and hydrogen-bond acceptor () abilities, were determined in these mixtures. We observed similar behavior for E_T^N and  in TX-100/alcohols mixtures. Parameters confirmed the preferential solvation in mixtures of surfactant and solvents.
Experimental data were handled in preferential solvation model. Six binary systems exhibit a complex behavior for all three indicators. It was shown that... 

The most crucial physical component in human-robot interaction is the head of the robot, which may have the potential to interact via representing facial expressions. There are several different types of robotic heads. This thesis presents the design process and realization of a retro-projected social robotic head, “Taban”. Taban is a cost-effective portable robot with a lifelike robotic face which can produce different facial expressions, different 3D face animation avatars (ranging from different ages, races, and gender) with the help of rear-projector in its head to projects animations onto a translucent 3D printout mask. It has a neck system with two degrees of freedom, a camera in the... 

In contacts, the presence of both variable loading and low-amplitude movements causes a kind of fatigue in these components called FRETTING FATIGUE. fretting fatigue has reduced the life of parts. Due to the high cost of replacing some parts in case of failure, it is necessary to take effective measures to delay this exhaustion. One of the effective solutions that can be applied is the use of coating and surface treatments in the contact areas. In this research, first, the fretting fatigue maps of Ti-6Al-4V alloy have been calculated and drawn according to the recommendations of the ASTM standard by using finite element methods. In the next step, by using experimental experiments, the damage... 

Multi-disciplinary design optimization (MDO) of a surface to air flying vehicle has been done in this research, on the basis of flight simulation. The MDO problem have five disciplines consists of aerodynamic, propulsion, guidance, control, and fire control. Multiple campaign scenarios are defined. The MDO problem has 31 design variables and two objective functions. The objective functions are flying vehicle weight and miss distance. A new meta-heuristic algorithm has been designed to solve multi-objective optimization problems. The new algorithm has been called Multi-objective Adaptive Real-coded Memetic Algorithm (MARCOMA). The MARCOMA can solve large-scale and multi-objective problems and... 

PVDF (polyvinylidene fluoride) magnetic nanocomposite films were prepared by solution casting using two types of nanomagnetic particles: (i) magnetic nanoparticles synthesized by using an alkaline solution of mixed ferrous/ferric salts along with oleic acid as a coating agent at 70˚C; (ii) Fe3O4 nanoparticles prepared by hydrolysis of aqueous solution of ferrous/ferric salts with potassium hydroxide at room temprature. Scanning electron microscopy (SEM) showed that the PVDF magnetic nanocomposite had a porous structure with Fe3O4 nanoparticles dispersed inside the porous polymer matrix. The presence of crystalline magnetite within the polymer matrix was confirmed by X-Ray diffraction method...