Sharif Digital Repository

Pyrochlore free (x)PMN-(1 - x)PZT ceramics were synthesized successfully by a seeding method. In this method, the mixture of PbO, MgO and Nb2O5 was added to the prepared PZT sol to from PMN-PZT gel. The gel was fired to vaporize the organic contents of gel and obtain powder. Two-step sintering process was used to produce pyrochlore free ceramics. The samples produced by this method showed higher relative densities, lower sintering temperature and higher dielectric properties relative to the mixed oxide method, mostly due to the higher homogeneity of the prepared powder. The measured dielectric properties of PZT-rich and PMN-rich materials were high while the other samples exhibited low... 

In this work, a new method based on the modified Enskog theory (MET) is presented for calculation of transport properties at high densities (ρ > ρc). The main limitation of using the MET is lack of experimental data for co-volume, b0. We have substituted b0 from hard sphere (HS) theory and zero density transport properties from the kinetic theory of gases for HS in the MET expression, because of the fact that dense fluids behave more and less like a HS fluid. As a result, a simple linear expression for the self diffusion (D) and quadratic expressions for viscosity (η) and thermal conductivity (λ) coefficients have been obtained in terms of Y at high densities (ρ > ρc), where Y = (T (∂ p / ∂... 

In this investigation, the crystalline structure of a nanometric CoSi 2 layer, formed in heat treated Co/W x Ta (1-x) /Si(1 0 0) systems, has been studied by XRD analysis. Careful measurements of the diffraction intensities revealed that temporary formation of a metastable diamond cubic structure of CoSi 2 phase, rather than its usual CaF 2 structure, was occurred. It has been shown that formation of this metastable structure depends on the kind of the applied interlayer in addition to the annealing temperature. Among the studied systems with x = 0, 0.25, 0.5, 0.75 and 1, the second and the last systems resulted in growing a (1 0 0) single-texture CoSi 2 layer with the preferred usual CaF 2... 

Epitaxial formation of CoSi2 nanolayer by solid state reaction of Co-Si in refractory metal intermediate-layer and cap-layer systems was investigated. Thin films of Ta and W, as the refractory metal intermediate or cap layers of the Co film, were deposited on Si(100) substrate and then heat-treated. The both interlayers resulted in formation of epitaxial CoSi 2 with (100) crystallographic orientation at 900°C. However, in the Ta intermediated system, the grown CoSi2 layer was thermally unstable at 1000°C, unlike the W system with a stable silicide layer. We found that use of W cap-layer cannot yield an epitaxial CoSi2 phase. But, a Ta cap-layer resulted in formation of epitaxial CoSi2(100)... 

The main concern of steganography (image hiding) methods is to embed a secret image into a host image in such a way that it causes minimum distortion to the host; to make it possible to extract a version of secret image from the host in such a way that the extracted version of secret image be as similar as possible to its original version (this should be possible even after usual attacks on the host image), and to provide ways of embedding secret images with larger size into a given host image. In this paper we propose a method that covers all above mentioned concerns by suggesting the idea of finding from an image data base, the most suitable host for a given secret image. In our method,... 

Surface-enhanced Raman spectroscopy is a highly sensitive phenomenon and a powerful fingerprint detection tool that reflects the small changes in polarizability on the pattern and intensity of Raman signals. The SERS enhancement signals elucidate with the surface-selection rules. In this regard, molecular configuration and adsorption orientation on the surface, in addition to the direction of external electric field, can lead to different patterns of SERS spectra. To evaluate how the variation of these features influences the pattern and reproducibility of the spectra, the chemical charge-transfer SERS spectra for pyridine on silver clusters are calculated for different field directions,... 

PTCR thermistors are thermally sensitive resistors that show positive temperature coefficient of resistance and are good candidates for applications as self-regulating heating elements and thermal control switches. For these applications, the current-time behavior of thermistors is of primary importance. In this work, heat transfer models were developed to simulate the electrothermal behavior of BaTiO3 thermistors. Also, using simulated temperature profiles, thermal stress distributions of the specimen were calculated to predict crack formation at different conditions. At high voltages, the effects of thermal conductivity and heat transfer coefficient were negligible. At low voltages, the... 

Electrospinning is a simple and cheap process for forming one-dimensional (1D) nanofibers with controllable size, morphology, and chemistry. Besides these, the ultrahigh surface area with industrialization capability has attracted extensive interest in the research community. On the other hand, a photocatalytic process is a promising method for degrading organic pollutants that cannot be removed by conventional wastewater treatment. This review focuses on the recent progress of electrospun nanofibers for the photocatalytic degradation of water pollutants. The linkage between the electrospinning technique and the photocatalytic process is classified into two main categories: (1) polymeric... 

The main concern of steganography (image hiding) methods is to embed a secret image into a host image in such a way that the host should remain as similar as possible to its original version. In addition the host image should remain robust with respect to usual attacks. In this paper we present a method that tries to cover all above mentioned concerns. The secret and host images are divided into blocks of size 4 × 4. Each block in secret image is taken as a texture pattern for which the most similar block is found among the blocks of the host image. The embedding procedure is carried on by replacing these small blocks of the secret image with blocks in host image in such a way that least... 

In this paper an integrated core, high reliability, linear-rotational resolver with a simple slotless configuration is proposed. The moving part of the proposed resolver has only one helical winding. While, its stator needs at least two individual windings to be able to determine the linear and angular position in simultaneous linear and rotational, helical, motions. Three different configurations are proposed for the stator's windings: (1) helical and horizontally skewed winding (2) helical and vertically skewed winding (3) horizontally and vertically skewed windings. The influence of the mentioned configurations is discussed in the terms of sensor's accuracy in independent and simultaneous... 

Two-degree-of-freedom (2-DOF) electrical machines require position sensors for their motion control. In comparison with using two independent sensors, using a 2-DOF sensor enhances the closed-loop control system's performance. However, due to the 3-D structure of the 2-DOF sensor, its performance evaluation needs 3-D analysis. Also, due to helical motion the accuracy deterioration of the sensor, under mechanical faults needs more attention. Although the finite element method (FEM) is the best way to simulate such sensors, most of the commercial packages for transient finite element simulations are not able to consider two separate motions simultaneously. Furthermore, FEM has a high... 

Resolver, as an electromagnetic sensor, is widely used in many industrial applications. It can detect the position of the rotary part of the electric machines precisely. In commercial resolvers, excitation winding is connected to the High-Frequency (HF) AC source. The amplitude-modulated voltages induced in signal windings need to be demodulated in order to calculate the envelope of the output signals and detect the position accordingly. On the other hand, in PM-resolver, signal windings are replaced by Hall-effect sensors to measure the DC magnetic ux, which is produced by permanent magnets. In this study, the performance of both AC and DC ux resolvers is investigated under di erent... 

Van der Waals (vdW) heterostructures of two-dimensional monolayers are a relatively new class of materials with highly tunable band alignment, bandgap energy, and bandgap transition type. In this study, we performed density functional theory calculations to investigate how a vdW heterostructure of heptazine-based graphitic carbon nitride (hg-C3N4) and graphitic zinc oxide (g-ZnO) monolayers is formed (hg-C3N4/g-ZnO). This heterostructure is a potential solar-driven photocatalyst for the water-splitting reaction. Upon the formation of the heterostructure, a type-I indirect bandgap (Eg = 2.08 eV) is created with appropriate conduction band minimum and valence band maximum levels relative to... 

Single-phase, outer-rotor squirrel cage induction motors are widely used in ceiling fan applications. Furthermore, they can be employed for pumps, and in-wheel hub drives. In this article, an analytical model based on magnetic equivalent circuit is proposed to evaluate the performance of the motor. The influence of rotor slots' skewing, stator end windings, slots' leakage inductance, and core saturation are included in the model. Furthermore, the windings' copper losses and the core's iron losses are calculated using the proposed model. The results of the presented model are compared with those of time variant finite element analysis (TVFEA) and experimental measurements close agreement... 

Variable Reluctance (VR) resolver is an angular position sensor that is commonly used in the automotive industry. In this paper, A general method for determining the winding configuration of VR resolvers is proposed, that eases the manufacturing process. At first, the operational principle of conventional winding has been presented using mathematical formulations. Following that, the non-overlapping tooth coil winding method, as the ideal winding option for VR resolver, has been extended that can be applied to the VR resolver with arbitrary poles and stator tooth numbers. The method of determining the reference and signal windings presented and used to determine the winding for a 2, 6, and 8... 

In this paper an extended approach to the nonlinear DMC algorithm is proposed, which can handle constrained and MIMO systems under some defined conditions. This extension also admits higher control, M, and prediction, P, horizons that are required to increase the performance of the controller in most practical applications. Simulation results of the proposed method in the control of a stirred tank reactor with 2 inputs and 2 outputs nonlinear model are presented to illustrate effectiveness of the method and its justification. © 2003 IEEE  

Using multiple position sensors in the control system of Two-Degrees of Freedom (2-DOF) motors causes it more complicated than that of conventional 1-DOF ones. However, employing a 2-DOF position sensor in comparison with two independent sensors, reduces the complexity, mass and volume of the system. The common 2-DOF sensors are able to determine the position in linear, rotational, and helical motion. Yet, they suffer from accuracy reduction due to the longitudinal end effect. Therefore, analytical modelling and the relevant compensation methods are discussed. The accuracy of the model is approved by comparing its results with those of 3D time transient finite element method. Afterwards, the... 

Transit assignment is an important problem in the literature of transportation. Almost all competitive algorithms in this area are strategy based. For uncongested transit networks, the problem may be formulated into an optimization problem for which good solution algorithms exist. A variational inequality formulation of the problem with several solution methods is also presented in the literature for congested networks. This paper is devoted to solving a transit assignment problem based on complementarity formulation using path flows. The solution algorithm exploits the three concepts of decomposition, path generation, and linearization. The procedure has been applied on a large-scale... 

We have studied the intramolecular H-bonds existing in cyclic and open forms of glucose using B3LYP/6-311++G(d,p) level, AIM, and NBO methods. The theoretical results indicated that based on acidity values, (ΔHacid), glucose in the open form is more acidic than cyclic form. The acidity values for open and cyclic glucose (332 and 338 kcal/mol) exhibit significantly lower values (i.e., stronger acid) than the reported acidity values for α-/ß-anomers of D-glucopyranose and simple alcohols. Because their conjugate bases are more stabilized through trifurcated and bifurcated intramolecular H-bonds. AIM analysis showed normal H-bonds in the conjugate bases of open glucose (O-Glc), bifurcated, and... 

A limiting problem for a stochastic evolution equation is studied in the paper. In the equation, the linear operator is non-positive with a pure point spectrum, the non-linearity is monotone, and the Brownian motion is cylindrical. It is shown that, in the limit, the mild solution to the evolution equation tends to the solution of an ordinary Ito equation. Copyright © Taylor & Francis, Inc