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A series of new ternary zinc(II) complexes [Zn(L1-10)(phen)], where phen is 1,10-phenanthroline and H2L1-10 = tridentate Schiff base ligands derived from the condensation of amino acids (glycine, l-phenylalanine, l-valine, l-alanine, and l-leucine) and salicylaldehyde-5-sulfonates (sodium salicylaldehyde-5-sulfonate and sodium 3-methoxy-salicylaldehyde-5-sulfonate), have been synthesized. The complexes were characterized by elemental analysis, IR, UV-vis, 1H NMR, and 13C NMR spectra. The IR spectra of the complexes showed large differences between νas(COO) and νs(COO), Δν (νas(COO) - νs(COO)) of 191-225 cm-1, indicating a monodentate coordination of the carboxylate group. Spectral data... 

Equilibrium constants for formation of a cobalt(II) complex with the bidentate ligand dopamine have been studied with spectrophotometric methods in water + ethanol cosolvent systems at 15, 25, and 35 (±0.1)∈°C and an ionic strength of 0.2 mol·dm-3. The ionic strength was maintained using sodium chloride and a phosphate buffer. The stability constants of the complex and the resulting Gibbs energy changes are obtained. The results are discussed in terms of the effect of solvent on protonation and complexation. © Springer Science+Business Media, LLC 2007  

New water-soluble zinc(II) Schiff-base complexes derived from amino acids (glycine, L-phenylalanine, and L-valine) and salicylaldehyde-5-sulfonates (sodium salicylaldehyde-5-sulfonate and sodium 3-methoxy-salicylaldehyde-5- sulfonate) have been synthesized. The complexes were characterized by elemental analysis, IR, electronic, 1H NMR, and 13C NMR spectra. In the IR spectra of the complexes, the large difference between the asymmetric νas(COO) and symmetric νs(COO) carboxylate stretch, Δν(νas(COO)-νs(COO)) of 199-247 cm-1, indicates monodentate coordination of the carboxylate group. Spectral data showed that in these complexes the ligand is a tridentate ONO moiety, coordinating to the metal... 

Water-soluble cobalt(II) tetradentate Schiff base complexes have been shown to form charge transfer (CT) complexes with a series of nucleoside monophosphates including adenosine-5′-monophosphate (AMP) and cytidine-5′-monophosphate (CMP). The investigated water-soluble cobalt(II) Schiff base complexes are (i) disodium[{bis(5-sulfo-salicylaldehyde)-o-phenylenediiminato}cobalt(II)], Na 2[Co(SO3-salophen)] (1); (ii) disodium[{bis(5-sulfo-salicylaldehyde)-4,5-dimethyl-o-phenylenediiminato} cobalt(II)], Na2[Co(SO3-sal-4,5-dmophen)] (2) and (iii) disodium[{bis(4-methoxy-5-sulfo-salicylaldehyde)-4, 5-dimethyl-o-phenylenediiminato}cobalt(II)], Na2[Co(SO 3-4-meosal-4,5-dmophen)] (3). The formation... 

Capture of discrete nature of nanomaterials is central to predict their behavior in high precision. To this end, various augmented continuum theories have been presented. However, their accuracy is strongly dependent on the recognition of accurate values of associated characteristic length scale parameter, and many ambiguities and uncertainties still remain about them. As main purpose of this study, the accurate values of elasticity tensor elements in the framework of first strain gradient theory are calculated for graphene with trigonal crystal system. A promising way to achieve them could be through molecular mechanics model. So that, the energy, including strain and kinetic energy, based... 

The surface of a topological insulator hosts Dirac electronic states with the spin-momentum locking, which constrains spin orientation perpendicular to electron momentum. As a result, collective plasma excitations in the interacting Dirac liquid manifest themselves as coupled charge- and spin-waves. Here we demonstrate that the presence of the spin component enables effective coupling between plasma waves and spin waves at interfaces between the surface of a topological insulator and insulating magnet. Moreover, the helical nature of spin-momentum locking textures provides the phase winding in the coupling between the spin and plasma waves that makes the spectrum of hybridized spin-plasma... 

Controlling nonlinear systems have always been a challenging problem. Complexity is mostly the result of nonlinear systems behavior dependence on initial conditions and input. Linearization techniques are such kinds of nonlinear systems analysis tools, which can give suitable results in neighborhood of equilibrium points. In addition, phase portraits are very efficient for visualizing the behavior of system in equilibrium points' neighborhood. In this paper, designing a controller for a low order dynamic system with multiple equilibrium points in presence of a sinusoidal disturbance with unknown amplitude and unknown bounded frequency is investigated. The proposed controller is based on a... 

Tridentate Schiff-base ligands derived from condensation of 3-formyl-4-hydroxybenzyl-triphenylphosphonium chloride with glycine, L-alanine, L-valine, L-leucine and L-phenylalanine in the presence of Zn(OAc)2·2H2O form five new water-soluble Zn(II) complexes, which were characterized by elemental analyses, IR, electronic absorption and 1H, 13C NMR spectroscopies. In the IR spectra of the complexes, the difference between the asymmetric and the symmetric carboxylate stretching frequencies is larger than ∼210 cm-1, which implies that the carboxylate groups are monodentate. UV-Vis electronic absorption studies show that Zn(II) functions as a trap for the Schiff-base intermediate. Schiff-base... 

Fluorescence spectroscopy in combination with circular dichroism (CD) spectroscopy were used to investigate the interaction of water-soluble amino acid Schiff base complexes, [Zn(L1,2)(phen)] where phen is 1,10-phenanthroline and H2L1,2 is amino acid Schiff base ligands, with bovine serum albumin (BSA) under the physiological conditions in phosphate buffer solution adjusted to pH 7.0. The quenching mechanism of fluorescence was suggested as static quenching according to the Stern-Volmer equation. Quenching constants were determined using the Stern-Volmer equation to provide a measure of the binding affinity between amino acid Schiff base complexes and BSA. The thermodynamic parameters ΔG, ΔH... 

Hydraulic fracturing is a widely used and efficient technique for enhancing oil extraction from heavy oil sands deposits. Application of this technique has been extended from cemented rocks to uncemented materials, such as oil sands. Models, which have originally been developed for analyzing hydraulic fracturing in rocks, are in general not satisfactory for oil sands. This is due to a high leak-off in oil sands, which causes the mechanism of hydraulic fracturing to be different from that for rocks. A thermal hydro-mechanical fracture finite element model is developed, which is able to simulate hydraulic fracturing under isothermal and non-isothermal conditions. Plane strain or axisymmetric... 

In this part, similar to Part I of this paper, a new two-level method for nonlinear optimal control of large scale systems is introduced. This approach is based on Interaction Balance Principle for coordination of large-scale systems. In the first level, the optimization problems are solved for nonlinear dynamics using a gradient method, and in the second level, the coordination is done using the gradient of errors to improve the convergence rate in compare to the classical Goal Coordination method and obtain the overall optimal solution. The efficacy and advantages of the new approach is shown in an application example. © 2005 IEEE  

Two series of the novel unsymmetrical diimino tetradentate Schiff bases derived from phenylenediamine and 1,3-naphthalene diamine and their vanadyl complexes were synthesized by template and non-template methods and characterized by 1H, 13C NMR, IR, UV-Vis and elemental analysis. These complexes are used as catalysts for the selective aerobic oxidation of cyclohexene. The catalytic activity increases as the number of electron-donor groups decreases, and the catalytic selectivity is varied by changing the substituents on the ligands. The catalytic system described here is an efficient and inexpensive method for the oxidation of olefins, with the advantages of high activity, selectivity,... 

The novel unsymmetrical, diimino-tetradentate Schiff bases derived from 2-[(2-amino-phenylimino)- methyl]-phenol and 2-[1-(2-amino-phenylimino)-ethyl]-phenol were synthesised and characterised by template and non-template methods  

Novel vanadyl Schiff base complexes with the general formula VOLx (x = 7-18) were synthesized and characterized by physicochemical methods. Only an orange polymeric form was obtained for VOL13, both brown polymeric and green monomeric forms were obtained for VOLx, x = 16, 17. These observations suggest that in these complexes oxovanadium(IV) exhibit a coordination number of five. Systematic substitution on the ancillary ligand have allowed V(V)/V(IV) reduction potentials to be tuned over a range of approximately 130mV. The complexes are catalysts for the aerobic oxidation of cyclohexene. Catalytic activity increases with increasing V(V)/V(IV) reduction potential and the catalytic selectivity... 

The unsymmetrical tetradentate Schiff base H2L was prepared by the reaction of salicylaldehyde with the mono Schiff base derived from o-phenylenediamine and o-hydroxyacetophenone (HL1). NiL and CuL complexes were prepared and characterized by 1H NMR, IR and single crystal X-ray structure determination. Crystal data for NiL: triclinic space group P-1, a = 7.190 (2) Å, b = 13.059 (4) Å, c = 17.867 (10) Å, α = 74.888 (10)°, β = 84.206 (10)°, γ = 86.542 (2)° and z = 4. Crystal data for CuL: monoclinic space group P2I/n, a = 12.8209 (6) Å, b = 6.988 (3) Å, c = 18.601 (9) Å, β = 105.15° and z = 4. The Ni and Cu atoms have a slightly distorted square-planar coordination geometry  

The symmetrical and unsymmetrical Schiff base complexes of VO(IV) and Mn(III) derived from 2,2′-diaminobiphenyl and derivatives of salicylaldehyde and 1-hydroxy-2-napnthaldehyde have been synthesized and characterized by elemental analysis, NMR, infrared and electronic absorption spectroscopies, and conductivity measurements. The reaction of the ligands with oxovanadium(IV) was found to be kinetically unfavored, probably due to the small ionic radius of the metal ion, which is not in accordance with the cavity size of the ligands. Copyright © 2005 Taylor & Francis, Inc  

The formation constants for 1:1 molecular complex formation between water-soluble cobalt(II) tetradentate Schiff base complex, disodium[{bis(4- methoxy-5-sulfo-salicylaldehyde)-4,5-dimethyl-o-phenylenediiminato}cobalt(II)], Na2[Co(SO3-4-meosal-4,5-dmophen)], and nucleotides, adenosine-5′-triphosphate (ATP) and cytidine-5′-triphosphate (CTP), in mixed solvent systems of ethanol and water with different volume fractions of ethanol and water have been determined spectrophotometrically at constant ionic strength (I = 0.2 mol dm-3 NaClO4) and temperature 278 K. Trends in the values of formation constants according to the volume fractions of ethanol and water in ethanol and water mixed solvent... 

The mathematical modeling of a bolted joint with a Shape Memory Alloy (SMA) actuator ring is presented. In this way, phase transformation, constitutive and displacement compatibility equations are used. The obtained model is utilized to show how the application of the SMA actuator ring in the bolted joint can help the joint to recover a significant amount of its lost clamping force. The model is run using the experimental data obtained for the Ni-55.7%wt Ti SMA in the companion paper (Part 1). The mechanical properties of SMA are calculated using the mentioned equations and compared to the experimental findings. It is observed that the final clamping force obtained theoretically is close to... 

The response of a Timoshenko beam with uniform cross-section and infinite length supported by a generalized Pasternak-type viscoelastic foundation subjected to an arbitrary-distributed harmonic moving load is studied in this paper. Governing equations are solved using complex Fourier transformation in conjunction with the residue and convolution integral theorems. The solution is directed to compute the deflection, bending moment and shear force distribution along the beam length. A parametric study is carried out for an elliptical load distribution and influences of the load speed and frequency on the beam responses are investigated. © 2004 Elsevier Ltd. All rights reserved