Sharif Digital Repository

In the present work, a mathematical model was developed based on finite difference method to predict the microporosity distribution in A356 aluminum alloy casting. Heat, mass, and gas conservation equations were solved in this model. Moreover, Darcy's equation was considered in the mushy zone. Results show that the distribution and concentration of microporosities in cast parts vary with both cooling rate and initial gas content. Simulation results were compared with experimental data where proportionally good agreement with experimental results was found. Finally, a complex cast part was simulated presenting the ability of the model to predict the porosities in industrial cast parts  

In the last few years, an increasing attention has been paid to the issues of saving energy and reducing the manufacturing costs in the transport industry which necessitates further efforts to replace traditional materials like steel with lightweight materials such as plastics, aluminum, magnesium, and composites. Metal matrix nanocomposites have turned into an established material in today's industry with an ongoing expansion in their field of applications. In this study, the formation of nanoparticle-aluminum metal matrix composites is described by compocast processing from nanoparticle Al2O3 and the A356 aluminum alloy. In order to optimize the processing parameters, a novel approach is... 

Aluminum metal matrix composites (MMCs) reinforced with nanoceramics are ideal materials for the manufacture of lightweight automotive and other commercial parts. Adaptive neuro-fuzzy inference system combined with particle swarm optimization method is implemented in this research study in order to optimize the parameters in processing of aluminum MMCs. In order to solve the problems associated with poor wettability, agglomeration and gravity segregation of nanoparticles in the melt, a mixture of alumina and aluminum particles was used as the reinforcement instead of raw nanoalumina. Microstructural characterization shows dendritic microstructure for the sand cast and non-dendritic... 

Point matching technique is applied to a pyramidal horn antenna to expand its aperture field in a wide angular range in terms of Gaussian beams using the Jacobi iterative method. The obtained far field pattern is compared with the results of Gabor's Gaussian beam expansion. Convergence, speed, the impact of initial condition and the selection of sample points is discussed. The implemented point matching scheme is almost as fast and accurate as the Gabor's expansion. It can even be faster and more accurate in some cases especially when the Gaussian beams are neither wide-waisted nor narrow-waisted  

In this work the effect of electrolytes on hydrate formation was investigated. To do so, a new model was used in predicting the hydrate formation conditions in presence of both single and mixed electrolyte solutions. The new model is based on the van der Waals - Platteeuw hydrate equation of state. In order to evaluate the values for the activity of water in electrolyte solutions the simplified version of the Ghotbi-Vera Mean Spherical Approximation (SGV-MSA) model was used. According to the SGV-MSA model the ions in the solutions are considered as charged hard spheres with different sizes. The values of the parameters for the SGV-MSA model are independent of temperature and depend only on... 

The present study investigated the effects of initial Hydrogen level and cooling rate on ultimate tensile strength of commercial Al-A319 alloys. Three hydrogen levels (0.01, 0.2, and 0.41 mL/100 grams of melt) and five cooling rate were studied. Total of 45 tensile test bars was prepared (three hydrogen levels × five cooling rate × three repeats). The UTS of the samples was determined though uniaxial tension tests. Furthermore, the microstructures of the samples were studied by standard metallographic technique and image analysis software. Finally the relationship between UTS and microstructurai features—SDAS and fraction of porosity (Fp%)—of the alloys was investigated.Results of tensile... 

The cellular microenvironment can be engineered through the utilization of various nano-patterns and matrix-loaded bioactive molecules. In this study, a multilayer system of electrospun scaffold containing chitosan nanoparticles was introduced to overcome the common problems of instability and burst release of proteins from nanofibrous scaffolds. Bovine serum albumin (BSA)-loaded chitosan nanoparticles was fabricated based on ionic gelation interaction between chitosan and sodium tripolyphosphate. Suspension electrospinning was employed to fabricate poly-e{open}-caprolacton (PCL) containing protein-loaded chitosan nanoparticles with a core-shell structure. To obtain the desired scaffold... 

A 2-D numerical model was developed to predict the shape of weld pool in stationary GTA welding of commercial pure aluminium, without considering fluid flow in the weld pool. A Gaussian current density and heat input distribution on the surface of the workpiece were considered. The parameters of Gaussian distribution were modified by comparing calculated results with experimental ones. It was found that these distribution parameters are functions of applied current and arc length. Effects of arc length, applied current and welding time on the geometry of the weld pool were investigated. To check the validity of the model, a series of experiments were also conducted. In general, the agreement... 

In this research FeCl2/FeCl3/Perlite magnetic nanoparticles (FeCl2/FeCl3/PMNs), as a novel magnetic nanocomposite adsorbent was used for the removal of green malachite (GM) dye from aqueous solution in a batch and fixed bed column. Firstly, FeCl2/FeCl3/PMNs adsorption properties were investigated. Therefore, the solution of FeCl2·4H2O and FeCl3·6H2O by ratio 2/1 was mixed with perlite nanoparticles. The study investigates the effect of process parameters such as pH, adsorbent dosage, contact time and GM dye initial concentration. Next, GM dye was quantitatively evaluated by using the Langmuir, Freundlich and BET isotherms and pseudo-first- and pseudo-second-order kinetic model. The... 

Effects of sprue base size and design on flow pattern during aluminum gravity casting have been investigated by employing different sprue base sizes and using computational fluid dynamics (CFD). Calculations was carried out using SUTCAST simulation software based on solving Navier-Stokes equation and tracing the free surface using SOLA-VOF algorithm. Flow pattern was analyzed with focusing on streamlines and velocity distribution in sprue base, runner and in-gate. Increasing well size was produced a vortex flow at the bottom of sprue base which increased the surface velocity of liquid metal in runner. Using a rather big sprue well could eliminate vena contracta, but in-gate velocity was... 

A novel colorimetric nanosensor is reported for the selective and sensitive determination of cysteine using magnetic-sulfur, nitrogen graphene quantum dots (Fe3O4/S, N-GQDs), and gold nanoparticles (Au NPs). Thus, S, N-GQDs was firstly immobilized on Fe3O4 nanoparticles through its magnetization in the presence of Fe3+ in the alkali solution. The prepared Fe3O4/S, N-GQDs were dispersed in cysteine solution resulting in its quick adsorption on the surface of the Fe3O4/S, N-GQDs through hydrogen bonding interaction. Then, Au NPs solution was added to this mixture that after a short time, the color of Au NPs changed from red to blue, the intensity of surface plasmon resonance peak of Au NPs at... 

Herein, NiO and Co2 O3, NiCo2 O4, and NiCo2 O4 /multi-walled carbon nanotubes nanocomposite were synthesized by the hydrothermal method and characterized by scanning electron micros-copy, energy dispersive spectroscopy, and X-ray diffraction. The photocatalytic activity of the synthesized materials was evaluated by Reactive Red 120 dye degradation. The photocatalytic activity of NiO and Co3 O4 was enhanced not only by the formation of NiCo2 O4, but also by its interaction with the functionalized multiwall carbon nanotubes support. The response surface methodology (RSM) was used to obtain the optimum parameters, including catalyst dosage, initial dye concen-tration, and pH on the dye... 

A novel colorimetric nanosensor is reported for the selective and sensitive determination of cysteine using magnetic-sulfur, nitrogen graphene quantum dots (Fe3O4/S, N-GQDs), and gold nanoparticles (Au NPs). Thus, S, N-GQDs was firstly immobilized on Fe3O4 nanoparticles through its magnetization in the presence of Fe3+ in the alkali solution. The prepared Fe3O4/S, N-GQDs were dispersed in cysteine solution resulting in its quick adsorption on the surface of the Fe3O4/S, N-GQDs through hydrogen bonding interaction. Then, Au NPs solution was added to this mixture that after a short time, the color of Au NPs changed from red to blue, the intensity of surface plasmon resonance peak of Au NPs at... 

Spectrophotometric analysis method based on the combination of the principal component analysis (PCA) with the feed-forward neural network (FFNN) and the radial basis function network (RBFN) was proposed for the simultaneous determination of paracetamol (PAC) and p-aminophenol (PAP). This technique relies on the difference between the kinetic rates of the reactions between analytes and silver nitrate as the oxidizing agent in the presence of polyvinylpyrrolidone (PVP) which is the stabilizer. The reactions are monitored at the analytical wavelength of 420 nm of the localized surface plasmon resonance (LSPR) band of the formed silver nanoparticles (Ag-NPs). Under the optimized conditions, the... 

Surface turbulence during the filling of the mold triggers the entrainment of oxide films, which appears to be detrimental to the soundness of the final casting. Nonpressurized and bottom-gating systems have been employed in order to avoid such casting defects by reducing the surface velocity of the liquid metal. However, recent studies have shown that the melt front velocity in the mold entrance may exceed the critical value in the nonpressurized and bottom-gating systems. Therefore, a study was conducted on numerical simulation melt flow pattern in nonpressurized and bottom-gating systems. It was noted that the liquid metal enters the gate and then mold cavity with a higher velocity by...