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    Characterisation and Preparation of Chitosan-nano Diamond Nanocomposite

    , M.Sc. Thesis Sharif University of Technology Delavar Jolfaee, Zahra (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    Chitosan is a biocompatible and biopolymer with unique characteristics. Nanodiamonds that are basically carbon based nanoparticle have excellent mechanical, thermal stability biocompatibility bahviors. Combination of these two materials helps to the advantage of all the desirable features of both material and compensate low mechanical properties and strength of chitosan. In this study, we examine the composition of different percentages of nanodiamonds in chitosan and effect of modification on properties of the nanocomposites. The thermal behaviour, swelling behaviour and water contact angle of different nanocomposites were analyzed. Finally, to determine the distribution of the... 

    Preparation and Characterization of Unsaturated Polyester Resin/Nanodiamond Nanocomposites

    , M.Sc. Thesis Sharif University of Technology Hashemi, Mohammad Jafar (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    In recent decades, nano-structured materials have been allocated specific position for wide use in various fields. The nano-diamonds has attracted the attention of many researchers. The inherent characteristics of a diamond like spherical structure of nanoparticles and carbon atoms which have used their full capacity in the chemical bonds,also the same surface as the radiography particles which have empty orbital, provides an ability to perform a variety of surface modification on the particle . This article introduces the nanocomposites based on polymer, constituents specification and discuss properties of nanocomposites after mixing components together. Lots of studies was on... 

    Experimental Study of Formation Damage Reduction during Drilling of Horizontal Wells Using Nanoparticles

    , M.Sc. Thesis Sharif University of Technology Shojaei, Nima (Author) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    One the basic challenges during drilling of both vertical and horizontal wellbores is due to mud filtrate invasion into the formation. Addition of nanoparticles to composition of drilling fluid has been recognized as a measure of control and reduction of filtrate invasion. Despite notable advances in formulation of nano-enhanced drilling fluids, effects of surface wettability of nanoparticles on their performance have not been studied with any precision. Moreover, return permeability of a grain packed porous media after extreme invasion by mud filtrate has not been experimentally measured in a radial system, yet. The last but not least, Generation and development of mud cake opposite the... 

    An optimization-based method for prediction of lumbar spine segmental kinematics from the measurements of thorax and pelvic kinematics

    , Article International Journal for Numerical Methods in Biomedical Engineering ; July , 2015 , Volume 31, Issue 12 ; 20407939 (ISSN) Shojaei, I ; Arjmand, N ; Bazrgari, B ; Sharif University of Technology
    Wiley-Blackwell  2015
    Abstract
    Given measurement difficulties, earlier modeling studies have often used some constant ratios to predict lumbar segmental kinematics from measurements of total lumbar kinematics. Recent imaging studies suggested distribution of lumbar kinematics across its vertebrae changes with trunk rotation, lumbar posture, and presence of load. An optimization-based method is presented and validated in this study to predict segmental kinematics from measured total lumbar kinematics. Specifically, a kinematics-driven biomechanical model of the spine is used in a heuristic optimization procedure to obtain a set of segmental kinematics that, when prescribed to the model, were associated with the minimum... 

    Effect of system of initiators on the process cycle of nonisothermal resin transfer molding - Numerical investigation

    , Article Composites Part A: Applied Science and Manufacturing ; Volume 41, Issue 1 , 2010 , Pages 138-145 ; 1359835X (ISSN) Shojaei, A ; Farrahinia, H ; Pishvaie, S.M.R ; Sharif University of Technology
    2010
    Abstract
    The role of initiators with different reactivities on the process cycle of nonisothermal resin transfer molding (RTM) was examined using the numerical simulation. A new process model was developed based on flow, heat and mass transfer equations combined with an appropriate mechanistic kinetics model which elucidates the functions of the initiators in the system. The process cycle of RTM with both single initiator and dual-initiator (combination of two initiators) was analyzed. The numerical simulations revealed that the single initiator with high reactivity reduces the cycle time, but there is a risk of incomplete mold filling and nonuniform temperature distribution. For dual-initiator... 

    Effect of Carbon Fiber on Frictional and Wear Properties of Automotive Brake Pads

    , M.Sc. Thesis Sharif University of Technology Ahmadi Joukani, Farhad (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    In the recent decade, composites have been used in safety system of automobiles due to important characteristics such as high wear resistant and durability, low weight and also low noise pollution, stable friction coefficient, availability and low cost. In recent years, composites have attracted the attention of brake pads manufacturers because of their appropriate thermal and mechanical properties. Fibers play an important role in these material. Carbon fiber due to its features such as high strength, acceptable module, proper heat transfer coefficient and excellent resistant against thermal degradation has been considered by the experts but there is not any comprehensive research on... 

    Preparation and Characterization of Shape Memory Biocompatible Nanocomposites of Polyurethane/Carbon-magnetic Hybrid Nanoparticles

    , Ph.D. Dissertation Sharif University of Technology Salkhi Khasraghi, Samaneh (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    Smart bio-based shape memory polymers with high performance and fast response have the exciting potential to meet the growing need in biomedical applications. A fascinating approach in SMP categories in biomedical field is the development of noncontact activation without increasing the environmental temperature through remote triggering methods, such as magnetic triggering. Magnetically responsive SMPs have received lots of attention in the biomedical applications, especially the non-contact triggering of medical equipment and implants inside the body. In this study, the biocompatible nanocomposite based on shape memory polyurethane acrylates (SMPUAs)/ hybrid carbon-magnetic nanoparticles,... 

    Adhesion modification of polyethylenes for metallization using radiation-induced grafting of vinyl monomers

    , Article Surface and Coatings Technology ; Volume 201, Issue 16-17 , 2007 , Pages 7519-7529 ; 02578972 (ISSN) Shojaei, A ; Fathi, R ; Sheikh, N ; Sharif University of Technology
    2007
    Abstract
    The present paper demonstrates the performance of the radiation grafting technique as a chemically based surface pretreatment method to adhesion modification of polyethylene surfaces toward the metallic layer. Gamma irradiation over a dose range of 4-10 kGy is used for grafting of vinyl monomers including acrylamide (AAm) and 1-vinyl-2-pyrrolidone (NVP) onto the surface of three different polyethylenes including low density polyethylene (LDPE) and two kinds of high density polyethylenes, namely HDPE-1 and HDPE-2. The grafting yield is evaluated based on the weight increase of the samples. It is found that the grafting yield is dominated by the crystallinity of the polyethylene, so that lower... 

    Performance characterization of composite materials based on recycled high-density polyethylene and ground tire rubber reinforced with short glass fibers for structural applications

    , Article Journal of Applied Polymer Science ; Volume 104, Issue 1 , 2007 , Pages 1-8 ; 00218995 (ISSN) Shojaei, A ; Yousefian, H ; Saharkhiz, S ; Sharif University of Technology
    2007
    Abstract
    This study addresses the issue of using recycled materials to obtain low-cost structural products for practical applications. Through the use and re-extrusion of virgin high-density polyethylene (HDPE), the effects of the degradation level of HDPE as a matrix phase on its mechanical properties and the mechanical performance of composites produced with the degraded polyethylene have been examined. The degradation level of HDPE caused by reextrusion has been evaluated by the measurement of the melt flow index and mechanical properties of virgin and degraded HDPEs. The results indicate that the modulus and strength of HDPE significantly increase with the addition of polypropylene filled with 30... 

    Design and Prototype Blood Warmer

    , M.Sc. Thesis Sharif University of Technology Shojaei Mehrizi, Nader (Author) ; Sayyadi, Hassan (Supervisor)
    Abstract
    Warming the injectable blood is a set of methods used to transfuse blood to the supplier (Accident patients, surgery, dialysis). These methods raise the temperature of the injected blood to body temperature. Blood transfusions are performed directly before World War II, so there is no need to heat the blood, Increased need for blood units caused blood banks. In these banks, to prevent the proliferation of pathogens, the temperature of blood units is reduced to 2-6 degrees Celsius. For indirect injection of these blood units, the injection temperature should be brought to the patient's body temperature before injection to prevent the recipient's body temperature from decreasing.In this... 

    Thermally conductive rubber-based composite friction materials for railroad brakes - Thermal conduction characteristics

    , Article Composites Science and Technology ; Volume 67, Issue 13 , 2007 , Pages 2665-2674 ; 02663538 (ISSN) Shojaei, A ; Fahimian, M ; Derakhshandeh, B ; Sharif University of Technology
    2007
    Abstract
    This study deals with the thermal conductivity of rubber-based composite friction materials used in railroad vehicles. Based on a commercially available railroad friction material, called here base material (BM), various friction materials containing different thermally conductive fillers (Cu, brass, Al, Al2O3 and talc) are fabricated and then their thermal conductivities are measured at various contents of the fillers. Addition of the thermally conductive fillers causes an increase in thermal conductivity of the friction material from 0.48 up to 5.8 W/m K, depending on the type and content of the filler. In addition, the experimental results reveal that the thermal conductivity of the... 

    A sustainable approach to replace bleed stream in electrical refining of copper

    , Article Materials Letters: X ; Volume 16 , 2022 ; 25901508 (ISSN) Shojaei, M ; Khayati, G ; Korasani, M ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    Despite extensive studies on electrorefining to remove impurities from copper production units, bleeding electrolytes is the most popular method for controlling impurities due to low operating costs. A controlled cooled-reheat cycle was used to remove impurities in industrial electrolytes of Khatoon Abad copper company. Phase identification and physical study were done by the XRD, SEM, TEM, and FTIR techniques. The results confirmed the possibility of the removal of 23 wt% Ni, 26 wt% Sb, 2.4 wt% As and convention of 6 wt% of As5+ to As3+ at cooled-reheat cycle. © 2022 The Author(s)  

    Investigation of the Effect Recycled Nanosilica from Battery Separator by Pyrolysis Method on Mechanical Properties and Adhesion between Rubber and Steel

    , M.Sc. Thesis Sharif University of Technology Shojaei, Mohammad Reza (Author) ; Pircheraghi, Gholamreza (Supervisor)
    Abstract
    Creating sustainable development in today's human societies is essential, one of the pillars of achieving this important goal is environmental protection. Thus, waste management as a new challenge is leading engineers. Lead-acid battery waste is one of the sources of environmental pollution. Lead-acid battery separators contain 50% recyclable nanosilica. The main challenge of recycling nanosilica from separators is the presence of significant amounts of 6 to 9% wt.% of lead and 5% by weight of other impurities. Therefore, in the present study, lead trapped in the separating pores is removed using mechanical washing or abrasive washing. Then, the quality of recycled nanosilica is evaluated... 

    Phase behavior of mixture of supercritical CO2 + ionic liquid: Thermodynamic consistency test of experimental data

    , Article AIChE Journal ; Volume 59, Issue 10 , 2013 , Pages 3892-3913 ; 00011541 (ISSN) Eslamimanesh, A ; Mohammadi, A. H ; Salamat, Y ; Shojaei, M. J ; Eskandari, S ; Richon, D ; Sharif University of Technology
    2013
    Abstract
    Various models have been applied composed of the Peng-Robinson equation of state (PR-EoS) and the Soave-Redlich-Kwong equation of state (SRK-EoS) associated with three mixing rules including the following: Wong-Sandler (WS), van der Waals one (vdW1), and van der Waals two (vdW2) for phase behavior modeling of mixtures of supercritical CO2+different ionic liquids in vapor-liquid equilibrium (VLE) region. It has been found that the PR EoS implying the WS mixing rule can be used as a reliable thermodynamic model to perform a thermodynamic consistency test on the experimental data of phase behaviors of the supercritical CO2+ionic liquid systems (19 commonly-used ionic liquids have been studied).... 

    An Investigation on the Effect of Carbon Nanotubes on Physical and Mechanical Properties of Elastomers

    , M.Sc. Thesis Sharif University of Technology Saatchi, Mohammad Mahdi (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    Nanostructure matrials have reached a special place to be used in wide applications in recent decades. Among those carbon nanotubes have got much attention due to their excellent mechanical and electrical properties and their ability of developing new nanocomposites, though the issues of perfect dispersion and interaction with polymeric matrix hinders their development. In this work, recent advances on carbon nanotubes (CNTs) and rubbers nanocomposites have been reviewed and the intrinsic potential of carbon nanotubes as reinforcing filler in elastomeric materials has been demonstrated. In experimental section in addition to CNTs, two different grades of CBs, i.e. N330 and super conductive... 

    Finite element modeling of incremental bridge launching and study on behavior of the bridge during construction stages

    , Article International Journal of Civil Engineering ; Volume 13, Issue 1 , 2015 , Pages 112-125 ; 17350522 (ISSN) Shojaei, A ; Tajmir Riahi, H ; Hirmand, M ; Sharif University of Technology
    Iran University of Science and Technology  2015
    Abstract
    Incremental launching is a widespread bridge erection technique which may offer many advantages for bridge designers. Since internal forces of deck vary perpetually during construction stages, simulation and modeling of the bridge behavior, for each step of launching, are tedious and time consuming tasks. The problem becomes much more complicated in construction progression. Considering other load cases such as support settlements or temperature effects makes the problem more intricate. Therefore, modeling of construction stages entails a reliable, simple, economical and fast algorithmic solution. In this paper, a new Finite Element (FE) model for study on static behavior of bridges during... 

    Simulation of three-dimensional flow in compression resin transfer molding by the control volume/finite element method

    , Article Composites Technologies For 2020 ; 2004 , Pages 357-362 ; 9781855738317 (ISBN) Shojaei, A ; Boorboor, D ; Reza Ghaffarian, S ; Sharif University of Technology
    Woodhead Publishing Limited  2004
    Abstract
    In compression resin transfer molding (CRTM), resin injection and mold closing occur during the mold filling stage. In this paper, numerical simulation of threedimensional flow in compression resin transfer molding (CRTM) is presented. Numerical method is based on the control volume/finite element method (CVFEM) and the numerical algorithm to update the flow front at each time step is based on quasi-steady state approach. Numerical scheme presented in this article can be used to predict the flow progression, pressure distribution, mold clamping force in full threedimensional mold. Numerical example provided in the paper demonstrates the effectiveness of the developed numerical simulation in... 

    The Study of Noncovalent Interactions in Several Rhenium Tricarbonyl Complexes Bearing Nitrogen Containing Ligands

    , M.Sc. Thesis Sharif University of Technology Shojaei Khalilabad, Hadis (Author) ; Kia, Reza (Supervisor)
    Abstract
    In this study, synthesis structural and theoretical studies of four rhenium tricarbonyl complexes with 3-cyanobenzaldimino ethylenediamine (3CNbzen) and 2,3,6,7-tetraphenyl-1,4,5,8-tetraazaphenantherene (Ph4TAP) were investigated. The synthesized complexes were characterized by spectroscopic methods and their solid-state structure were determined by single-crystal X-ray diffraction analysis. Using single-crystal X-ray diffraction structure, the intra- and intermolecular interactions of the complexes and their dimers resulted from X-ray Cartesian coordinates were investigated. Furthermore, computational approaches were carried out to confirm the existence of the intra- and intermolecular... 

    High-capacity hierarchically imprinted polymer beads for protein recognition and capture

    , Article Angewandte Chemie - International Edition ; Volume 50, Issue 2 , December , 2011 , Pages 495-498 ; 14337851 (ISSN) Nematollahzadeh, A ; Sun, W ; Aureliano, C. S. A ; Lütkemeyer, D ; Stute, J ; Abdekhodaie, M. J ; Shojaei, A ; Sellergren, B ; Sharif University of Technology
    2011
    Abstract
    Leaving an imprint: Hierarchical protein imprinting starting from wide-pore silica modified with a submonolayer of adsorbed protein (IgG or HSA) leads to an inverse polymeric replica of the silica template that features highly accessible protein-complementary binding sites (see picture). The resulting poly(acrylamide) beads (PIgG or PHSA) feature high binding capacities and can be used to selectively capture the proteins HSA and IgG from blood serum  

    PH responsive Ce(III) loaded polyaniline nanofibers for self-healing corrosion protection of AA2024-T3

    , Article Progress in Organic Coatings ; Volume 99 , 2016 , Pages 197-209 ; 03009440 (ISSN) Pirhady Tavandashti, N ; Ghorbani, M ; Shojaei, A ; Gonzalez Garcia, Y ; Terryn, H ; Mol, J. M. C ; Sharif University of Technology
    Elsevier  2016
    Abstract
    Cerium nitrate loaded polyaniline (PANI) nanofibers were synthesized in this work via a chemical route. PANI nanofibers act as a host structure for the corrosion inhibitor, forming a Ce(III)-PANI complex. This complex is pH sensitive, and a change of pH can cause breaking of the complex and releasing of Ce(III). The Ce(III) loaded PANI nanofibers were embedded into epoxy ester coating and the self-healing corrosion protection ability was investigated by Scanning Vibrating Electrode Technique (SVET) and Electrochemical Impedance Spectroscopy (EIS). The results showed that by embedding of Ce(III) loaded PANI nanofibers into the coatings a superior corrosion protection and self-healing...