Sharif Digital Repository

In this study Fe3O4/CMC magnetic nanoparticles were synthesized through co-precipitation method. Afterward, laccase from Trametes hirsuta was immobilized onto Carboxymethyl cellulose (CMC)-coated magnetic Fe3O4 nanoparticles by covalent bonding between carboxyl groups of carboxymethyl cellulose and amine group of laccases. Also, the resulted magnetic nanoparticles and immobilized laccase were characterized by Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and dynamic light scattering (DLS) analysis. Moreover, the vital factors in enzyme immobilization, such as contact time, amount of N-hydroxysuccinimide (NHS), and the amount of nanoparticles were... 

In order to determine the activity of C137s in soil resulting from nuclear accidents or fallouts, the best choice is to use HPGe detectors due to their best energy resolutions. In this regard, in order to enhance the detection efficiency, the Marinelli beakers have been used to increase the radiation interaction with the sensitive volume of the detector. In previous works, to optimize the dimension of Marinelli beakers, the assumption was that the emission rate of the source is homogeneous in beaker volume. In the present study, to investigate the effect of the inhomogeneous emission rate of the source on the optimum dimensions of the beaker, in a simple case, the beaker was divided into two... 

The electrocatalytic oxidation of cephalexin and cefazolin has been studied at a carbon paste electrode modified with cobalt salophen (CoSal) by cyclic voltammetry. The selectivity of the carbon paste modified with CoSal in detecting cephalexin and cefazolin was examined. To suggest the electrocatalytic mechanism for electro-oxidation of cefazolin, the electrochemical behavior of ceftriaxone was investigated which has a thiol group out of the beta lactam ring. The electrocatalytic oxidation of these antibiotics is shown to be irreversible at the CoSal modified electrode. Scan rate dependence of cefazolin, which is a sulfur-containing compound, has been examined. The results indicated that... 

Micro motion stages are one of the essential components in field of micro robotics and ultra fine positioning systems. This research presents the optimum design of a 3-DOF micro motion stage and its position control using FEM simulation. This stage to be studied uses a 3 RRR flexure hinge base compliant mechanism driven by three piezoelectric stack actuators to provide micro scale planar motion. First of all parametric modeling of the stage will be fulfilled in ANSYS environment utilizing a commercial piezostack and different types of flexure hinges. Hence the Jacobian matrix will be achieved for each case. The optimum selection of the hinge form will be achieved upon results of the previous... 

Marine industries have always been provided power and development for countries both militarily and economically. Due to the lack of essential economic, industrial, and technological infrastructure in developing countries, the development of marine industries has been facing serious obstacles. As a developing country, Iran has been tackling similar barriers. This paper aims at developing a conceptual model, to examine this complex problem, using a systems approach by which subsystems and casual loop diagrams have been created. Afterward, DEMATEL technique has been used, revealing the most effective variables. The research can remarkably help practitioners in appropriate recognition and... 

TiO2 and transition metal (Cr, Mn, Fe, Co, Ni, Cu, and Zn) doped TiO2 nanoparticles were synthesized by the sol–gel method using 2-hydroxylethylammonium formate as an ionic liquid. All the prepared samples were calcined at 500 °C and characterized by X-ray diffraction (XRD), BET surface area determination, energy dispersive X-ray (EDX) analysis, diffuse reflectance spectroscopy (DRS), and Fourier transformed infrared (FT-IR) techniques. The studies revealed that transition metal (TM) doped nanoparticles have smaller crystalline size and higher surface area than pure TiO2. Dopant ions in the TiO2 structure caused significant absorption shift into the visible region. The results of... 

The quasi-static and strain-controlled fatigue characteristics of ZK60 extrusion have been investigated along three different directions: the extrusion direction (ED), the radial direction (RD), and 45° to the extrusion direction (45°). The quasi-static response showed symmetric behavior for the samples tested along RD and 45° whereas the ED samples manifested completely asymmetric behavior. Although the ED samples exhibited longer fatigue lives than the RD and 45° in the high cycle fatigue, the fatigue lives in the low cycle fatigue regime were similar. The texture measurement indicated a sharp basal texture along ED, explaining its asymmetric behavior. Higher tensile mean stress and less... 

Contrast induced nephropathy (CIN) has been reported to be the third foremost cause of acute renal failure. Metabolomics is a robust technique that has been used to identify potential biomarkers for the prediction of renal damage. We aim to analyze the serum and urine metabolites changes, before and after using contrast for coronary angiography, to determine if metabolomics can predict early development of CIN. 66 patients undergoing elective coronary angiography were eligible for enrollment. Urine and serum samples were collected prior to administration of CM and 72 h post procedure and analyzed by nuclear magnetic resonance. The significant differential metabolites between patients who... 

Demand response (DR) is known as a key solution in modern power systems and electricity markets for mitigating wind power uncertainties. However, effective incorporation of DR into power system operation scheduling needs knowledge of the price–elastic demand curve that relies on several factors such as estimation of a customer’s elasticity as well as their participation level in DR programs. To overcome this challenge, this paper proposes a novel autonomous DR scheme without prediction of the price–elastic demand curve so that the DR providers apply their selected load profiles ranked in the high priority to the independent system operator (ISO). The energy and reserve markets clearing... 

Background: Numerous studies have described the neuroprotective effect of lithium in spinal cord injury in addition to its ameliorative impact on pain sensation. In the present study, we aim to examine the efficacy of 85 mg/kg as well as 50 mg/kg dosage of the lithium chloride (LiCl) through oral consumption in spinal cord injured rats and their effect on gene expression of three candidate genes, corresponding to the hyper-sensitization. Methods: Adult Wistar (male) rats were divided into four experimental groups: control; oral administration of LiCl with 85 mg/kg and 50 mg/kg dosage; and 10 % sucrose receiver as the vehicle. BBB and heat plantar tests were performed weekly throughout four... 

Trapping a single aerosol using optical tweezers could be of great importance for environmental sciences. Though a single nanoparticle as small as 10 nm is successfully trapped in aqueous media using optical tweezers, due to spherical aberration only large clusters of nanoparticles were stably trapped in air. In this paper we provide our theoretical and experimental results on optimized trapping of aerosols as small as 400 nm in radius by the introduction of an extra spherical aberration source in order to minimize the total spherical aberration of the system. Our method allows for trapping of high refractive index particles such as polystyrene beads in air. It also provides considerably... 

In this paper, modeling and control of a new cable-driven robot is presented. In this mechanism, the cable arrangement eliminates the rotational motions leaving the moving platform with three translational motion. The mechanism has potentials for large scale manipulation and robotics in harsh environments. In this article kinematics and dynamics models for the proposed cable-driven architecture are derived. Additionally, Feedback linearization under input constraints is used for the control of the robot. The control algorithm ensures the cable tensions are positive while minimizing the sum of all the torques exerted by the actuators. Finally, the implementation of the proposed method is... 

A multi-item multiperiod inventory control model is developed for known-deterministic variable demands under limited available budget. Assuming the order quantity is more than the shortage quantity in each period, the shortage in combination of backorder and lost sale is considered. The orders are placed in batch sizes and the decision variables are assumed integer. Moreover, all unit discounts for a number of products and incremental quantity discount for some other items are considered. While the objectives are to minimize both the total inventory cost and the required storage space, the model is formulated into a fuzzy multicriteria decision making (FMCDM) framework and is shown to be a... 

In this study, crosslinked and non-crosslinked carboxymethylcellulose (CMC) membranes were prepared with different concentrations of polymer. Then, the permeability of pure CO2, N2, and CH4 was measured through these membranes in dry state to investigate the influence of polymer concentration and applied feed pressure on permeability and permselectivity. The permeability of CO2 through membranes was higher than the other gases. A comparison of permeabilities revealed that the permeability of N2, CO2, and CH4 increased on an average of 33, 40 and 20 percent, respectivly, by increasing the feed pressure from 6 to 10... 

In this paper, the shear deformation behavior of A286 Iron-based superalloy was studied with an emphasis on the influence of η phase on shear strength. The η (Ni3Ti phase precipitates at high temperature heat treatment or during services at the expense of gamma prime phase. According to the microstructural features, no evidences of η phase were found at 650 and 720°C. η phase precipitated at 780 and 840°C and the amount of it increased with an increase the time and temperature. Because of using the alloy as fasteners, investigation of shear properties and the influence of η phase on it are indispensable. The shear strength of the alloy with different volume fractions of η was examined. It... 

People make decisions and express their opinions according to their communities. A natural idea for controlling the diffusion of a behavior is to find influential people, and employ them to spread a desired behavior. We investigate an influencing problem when individuals' behaviors are affected by their friends in an opinion formation process. Our goal is to design efficient algorithms for finding opinion leaders such that changing their opinions has a great impact on the overall external behaviors in the society. We study directed social networks and define a set of problems like maximizing the sum of individuals' behaviors or maximizing the number of individuals whose external behaviors... 

Optical tweezers have proven to be indispensable micromanipulation tools especially in aqueous solutions. Because of the significantly larger spherical aberration induced by the refractive index mismatch, trapping aerosols has always been cumbersome if not impossible. We introduce a simple but very efficient method for optimized aerosol trapping at a desired depth. We show that a wise selection of the immersion medium and the mechanical tube length not only enables trapping of objects that are known to be untrappable but also provides a way to tune the trappable depth range  

TiO2 and transition metal (Cr, Mn, Fe, Co, Ni, Cu, and Zn) doped TiO2 nanoparticles were synthesized by the sol-gel method using 2-hydroxylethylammonium formate as an ionic liquid. All the prepared samples were calcined at 500 °C and characterized by X-ray diffraction (XRD), BET surface area determination, energy dispersive X-ray (EDX) analysis, diffuse reflectance spectroscopy (DRS), and Fourier transformed infrared (FT-IR) techniques. The studies revealed that transition metal (TM) doped nanoparticles have smaller crystalline size and higher surface area than pure TiO2. Dopant ions in the TiO2 structure caused significant absorption shift into the visible region. The results of... 

This paper presents a new point-to-face contact algorithm for contacts between two polyhedrons with planar boundaries. A new discrete numerical method called three-dimensional discontinuous deformation analysis (3-D DDA) is used and formulations of normal contact submatrices based on the proposed algorithm are derived. The presented algorithm is a simple and efficient method and it can be easily coded into a computer program. This approach does not need to use an iterative algorithm in each time step to obtain the contact plane, unlike the ‘Common-Plane’ method applied in the existing 3-D DDA. In the present 3-D DDA method, block contact constraints are enforced using the penalty method.... 

Electrochemical potential noise analysis was used to investigate corrosion behavior of copper electrodes in presence of 0.001, 0.005, 0.01 and 0.02 M benzotriazole (BTA) inhibitor. Energy distribution of the potential noise was obtained from wavelet transformation using the 4th order Daubechies pattern. Two lowest frequencies were added-up and fitted to the impulse response of the first order circuit to achieve the time-constant vs. concentration (T-C) diagram. T-C diagram can be used either as a conventional diagram of inhibition efficiency or a tool for evaluation of the surface film dielectric constant. The assumptions made in this treatment were confirmed by EIS method. © 2009 Elsevier...