Sharif Digital Repository

The reactions of different dithiocarbamate anions with epoxides were investigated in water. With this method, β-hydroxy dithiocarbamate derivatives were synthesized in high yields. The reaction was also carried out in DMF in the presence of lithium perchlorate with a simple work-up procedure, and the results are compared  

A simple, rapid, and highly regioselective green protocols for the synthesis of β-hydroxylnitriles by the direct reaction of epoxides with trimethylsilyl cyanide in the presence of catalytic amount of lithium perchlorate under solvent free conditions in high to quantitative yield is reported  

Treatment of aliphatic and aromatic aldehydes with chiral amines and trimethylsilyl cyanide in the absence or in the presence of Lewis acids (including lithium perchlorate) under solvent-free conditions afforded the corresponding α-aminonitriles in good yields and with a diastereoselectivity of 68 to 86%  

Norouzak oil seeds that are the source of bio-diesel (Norouzak) fuel grow mostly in Gonabad and Kashmar located in Khorasan, north east of Iran. Spray characteristics of Norouzak bio-diesel have been experimentally and theoretically studied in this work. Norouzak fuel is added to the conventional diesel fuel, and mixture formations of several blends have been investigated and compared with each other. Moreover, by varying ambient and injection conditions, behaviors of spray of different blends have been explored. Microscopic and macroscopic properties of spray such as Sauter Mean Diameter (SMD), Ohnesorge number, spray tip penetration, spray cone angle, spray projected area and volume have... 

Norouzak oil seeds that are the source of bio-diesel (Norouzak) fuel grow mostly in Gonabad and Kashmar located in Khorasan, north east of Iran. Spray characteristics of Norouzak bio-diesel have been experimentally and theoretically studied in this work. Norouzak fuel is added to the conventional diesel fuel, and mixture formations of several blends have been investigated and compared with each other. Moreover, by varying ambient and injection conditions, behaviors of spray of different blends have been explored. Microscopic and macroscopic properties of spray such as Sauter Mean Diameter (SMD), Ohnesorge number, spray tip penetration, spray cone angle, spray projected area and volume have... 

In the present work, the spray characteristics of bio-ethanol and its blends have been experimentally and theoretically investigated. To have a comprehensive study, the effects of ambient condition and injection pressure on the spray of different blends have been considered. Macroscopic and microscopic characteristics of spray such as tip penetration length, cone angle, projected area, volume, Sauter Mean Diameter (SMD), and Ohnesorge number are investigated precisely. Besides, air entrainment and atomization analyses have been carried out to improve mixture formation process. Using curve fitting and least squares method, theoretical correlations have been suggested in such a way to predict... 

In this study, the gas turbine power plant with preheater is modeled and the simulation results are compared with one of the gas turbine power plants in Iran namely Yazd Gas Turbine. Moreover, multiobjective optimization has been performed to find the best design variables. The design parameters of the present study are selected as: air compressor pressure ratio (rAC), compressor isentropic efficiency (ηAC), gas turbine isentropic efficiency (ηGT), combustion chamber inlet temperature (T3) and gas turbine inlet temperature. In the optimization approach, the exergetic, economic and environmental aspects have been considered. In multiobjective optimization, the three objective functions,... 

this research chamber effective length, which is the minimum chamber length required for complete combustion, for a dilute monopropellant spray, constant area, one dimensional and fixed volume engine is analytically predicted. A new evaporation rate in the form of dk +1 relation, instead of d 2 law, is introduced. In case of controlling the vaporization by radiative heat transfer, k is equal to zero, and when molecular processes control the vaporization, k will be equal to unity and in some cases the vaporization data need the value of k greater than one to fit properly to related equation. Development of this approach can be used in design of combustion chambers with optimum length and with... 

In this research, effective length of one-dimensional combustion in a dilute monopropellant spray, constant area and fixed volume chamber is analytically predicted. A new evaporation rate in the form of d k+1 relation is introduced. In the case of controlling vaporization by radiative heat transfer, k is equal to zero, and when molecular processes control the vaporization, k will be equal to one and in some cases vaporization data need the value of k greater than one to fit properly to related equation. Development of this approach can be used in the design of combustion chambers with optimum length and with using vaporization rate of R = R0〈r〉 0 k/〈r〉k. Spray equation and distribution... 

A new experimental facility was designed, fabricated and tested to model and study the possibility of applying the bidirectional swirl flow on the combustion chamber of airbreathing subsonic ramjet engine. Appropriate intake was designed to convert axial external air to tangential swirl flow inside the combustion chamber. Inlets with appropriate angles conduct the swirl flow into the chamber and create bidirectional swirl flow field in the combustion chamber. This flow field has been modeled theoretically to determine the velocity field characteristics by previous researchers. Bidirectional swirl flow in liquid fuel ramjet engines has the proven advantage of keeping the combustion chamber... 

An experimental investigation has been performed to realize thorough behavior of a vortex tube system. In this work attention has been focussed on the classification of the parameters affecting vortex tube operation. The effective parameters are divided into two different types, namely geometrical and thermo-physical ones. A reliable test rig has been designed and constructed to investigate the effect of geometrical parameters i.e. diameter and length of main tube, diameter of outlet orifice, shape of entrance nozzle. Thermo-physical parameters which have been designated and studied are inlet gas pressure, type of gas, cold gas mass ratio and moisture of inlet gas. The effects of these... 

The Fontan surgery is performed on patients with a single ventricle heart defect to prevent the combination of highlyoxygenated and poorly-oxygenated blood. Blood flow in total cavopulmonary connection (TCPC) which culminates an ordinary Fontan operation is practically steady-state but this flow is not appropriate for respiratory systems. This article investigates an approach in Fontan surgery that has been recently proposed in order to make the pulmonary blood flow pulsating. Moreover, for investigating the compliance of vessels and its effects on blood flow in TCPC, we have used the FSI (Fluid Structure Interaction) method as well as rigid wall assumption for comparison purposes. Our TCPC... 

In this paper the analytical and simulation modelling of the combined heat and mass transfer processes that occur in a solid desiccant wheel is carried out. Using the numerical method, the performance of an adiabatic rotary dehumidifier is parametrically studied, and the optimal rotational speed is determined by examining the outlet adsorption-side humidity profiles. An approach to compare the solutions for different conditions used in air dehumidifier has been investigated according to the previous published studies. Comparing the simulated results with the published actual values of an experimental work substantiates the validity of model. The model accuracy with respect to the key... 

An operationally simple and entirely green protocol for heteropoly acid catalyst conjugate addition of indoles and pyrrole to unsaturated carbonyl compounds and nitro-alkene in water was investigated. It is important that the products arising from 1,2-addition were not observed under the reaction conditions. Pyrroles also readily underwent Michael addition at Α-positions under the same reaction conditions. Indole and many of its derivatives are present in many substances commonly found in nature. Micheal addition reactions are performed in organic solvents with the reactions in water are relatively scarce. The Michael addition between indole and methyl vinyl ketone in the presence of... 

A highly efficient and simple synthesis of dithiocarbamates is possible based on the one-pot reaction of amines, CS2, and alkyl halides without using a catalyst under solvent-free conditions. The mild reaction conditions, high yields, and broad scope of the reaction illustrate the good synthetic utility of this method. The reaction is a highly atom-economic process for production of S-alkyl thiocarbamates and successfully can be used in high quantities in the pharmaceutical or agrochemical industries  

A very efficient and mild procedure for the trimethylsilylation of a wide variety of alcohols, including primary, allylic, benzylic, secondary, hindered secondary, tertiary, and phenols with hexamethyldisilazane on the surface of silica gel dispersed with LiClO4 in room temperature at few minutes in excellent yields under neutral conditions is reported. This procedure also allows the excellent selectivity under LP-SiO2 system for silylation of alcohols in the presence of amine and phenolic hydroxy groups  

Heteropoly acids efficiently catalyzed the one-pot, three-component Mannich reaction of ketones with aromatic aldehydes and different amines in water at ambient temperature and afforded the corresponding β-amino carbonyl compounds in good to excellent yields and with moderate diastereoselectivity. This method provides a novel and improved modification of the three-component Mannich reaction in terms of mild reaction conditions and clean reaction profiles, using very a small quantity of catalyst and a simple workup procedure  

The present investigation considers the fully developed electro-osmotic flow of power-law fluids in a planar microchannel subject to constant wall heat fluxes. Using an approximate velocity distribution, closed form expressions are obtained for the transverse distribution of temperature and Nusselt number. The approximate solution is found to be quite accurate, especially for the values of higher than ten for the dimensionless Debye-Huckel parameter where the exact values of Nusselt number are predicted. The results demonstrate that a higher value of the dimensionless Debye-Huckel parameter is accompanied by a higher Nusselt number for wall cooling, whereas the opposite is true for wall... 

In this study, effect of desiccant wheel, heat exchanger and cooling coil will be evaluated on decreasing the wet bulb temperature of entering air to cooling tower and decreasing the outlet cold water temperature. For this purpose, change effect of desiccant wheel parameters will be investigated on wet bulb temperature of outlet air from heat exchanger. After that, optimum parameters and minimum wet bulb temperature will be selected. Then, outlet cold water temperature will be achieved for various cooling coil surface temperature with definition of by pass factor and also by using optimum desiccant wheel parameters and entrance air wet bulb temperature to tower related to cooling coil... 

Investigation of radiation heat transfer In vortex engine is an important and new phenomenon in combustion for scientists and combustion researchers. In this research some parts of the combustion chamber wall are insulated using Blanket as a high insulating material. The rate of radiative heat transfer to the chamber wall is calculated using temperature difference between inner and outer surface of chamber. In the experiments this parts are protected from direct contact with hot combustion media using quartz window. The luminous radiative transfer per volume of chamber and also volume of flame in a vortex engine are compared with that in a similar axial flow type engine. A detector sensitive...