Sharif Digital Repository

Different catalysts have been proposed for CO oxidation reaction and still many researches are performed to obtain a catalyst with high activity and stability. In this study, MOFs of CuBTC, MIL-101(Cr), and NH2-MIL-101(Cr) and active metal of Pd have been selected and their performances have been investigated in CO oxidation reaction. MOFs have been synthesized by hydrothermal method. Pd loading has been performed by impregnation method in various pH and in aqeous palladium nitrate solution and palladium nitrate solution in nitric acid. To reveal the effect of the nature of noble metal, activity of 1% Pt/MIL has been investigated. Amine-functionalized MIL-101(Cr) has been synthesized by... 

Slosh phenomenon is described as the motion of the fluid’s free surface in a tank or partially-filled container. This motion can induce undesired forces that can change the path of a vehicle. In some liquid carrying vehicles these undesired changes is sensed by the driver or control system and can lead to instability. Some examples of this phenomenon are aircrafts, rockets, ships and fuel carrier trucks.
In this project, a coupling between the dynamics of the vehicle and the contained fluid is implemented for in depth understanding of the interactions. This is done by Co-Simulation. With the help of Co-Simulation, corrective control actions can be taken and the design of more powerful... 

In recent decades, we have faced the enormous growth of data and graph volumes. This requires modern ways of computation and storage systems and algorithms. MapReduce is a known way of processing Big Data in a Parallel and primarily Distributed setting. Theoretical models (e.g., Massively Parallel Computation) for Algorithms using this paradigm commonly evaluate the number of rounds and needed communication. We study the Minimum Spanning Tree (MST) as a fundamental graph problem. This problem in MapReduce is harder for sparse graphs. We introduce an algorithm that performs well comparing previous studies, especially for sparse graphs.We present an empirical study by implementing some... 

In the current situation, kidney transplantation is the most appropriate and least costly treatment for patients with end-stage renal disease (ESRD). Related or altruistic living donors, as well as deceased donors, are considered as a supply source for donated kidneys. Researches have shown deceased donor kidney may not work as well as a living donor kidney because the deceased donor kidney is outside the donor's body for a longer time. If the donor has an incompatibility with the patient (in terms of the blood group, HLA, etc.), a kidney exchange between the pairs can be used to resolve the issue and make the transplantation possible. Pairs with blood group compatibility have also... 

In this piece of work, a gravity model is suggested as Iranian non-fuel export model to OIC countries. The most important results out of this model are the acquired coefficients of two variables, namely “ECO membership” and “Economic and Trade Freedom of Importer”. At first, we expected that for importer, being a member of ECO would increase the amount of trade with iran. Surprisingly, this is not what we see in a model. In fact, as ECO has not achieved any tangible success in increasing trade between its members, eastern Asian Muslim countries has become an important trade partner for iranians. This result is compatible with other pieces of researches about ECO. “Economic and Trade Freedom... 

Today’s growing interest to the underwater explorations and navigations demands to design appropriate underwater communication methods and systems. However, radio frequencies which are widely being used in free space communications, can’t be a good candidate for underwater wireless communications, due to their sever attenuation in water. On the other hand, underwater acoustic communication has been widely studied and implemented in the past decades, inspired by suitable propagation of acoustic waves through the underwater medium. Nevertheless, acoustic communication systems have limited bandwidth, lower propagation speed and lower security than optical counterparts, which suggests underwater... 

Visible light communication (VLC) uses huge license-free spectral bandwidth of visible light for high-speed wireless communication. Since each VLC access point covers a small area, handovers of mobile users are inevitable. In order to deal with these handovers, developing fast and effective resource allocation algorithms is a challenge. this paper introduces the problem of mobility-aware optimization of resources in hybrid VLC and 5G radio access technologies networks using the T-step look-ahead policy and employing the notion of handover efficiency. It is shown that the handover efficiency can correlate the overall performance of the network with future actions based on the mobility of... 

In present research, a cohesive based finite element model has been introduced to estimate median crack depth during mechanical machining on optical glasses. Development of the machining numerical model has been initiated by investigating the indentation process. Experimental results of this step have been calibrated primary numerical model which has been used in the scratch process. Due to differences between the scratch mechanism and indentation one, mathematical bases fracture formulas and cohesive relations have been developed. After extracting primary result, using them in the scratch model and developing the primary model, ultimately numerical model has been evolved to an abstract... 

Lithium has 9 isotopes which two isotopes are stable and remaining isotopes are unstable and have half-life. Lithium stable isotopes include 6Li and 7Li that their abundance is 7.53% and 92.47% respectively. Importance of lighter lithium isotope appears for its small cross section against thermal neutron and producing fusion reactors fuel in nuclear industries. Thermal neutron absorption cross section for 6Li and 7Li are 950 barn and 37 mbarn respectively. Interesting of these isotopes in nuclear industry is due to the large difference in the absorption cross section.6Li compounds implied for tritium producing in coat of nuclear fusion reactor with DT fuel. Following tritium is used in... 

Hydrothermal supercritical method is one of the most suitable methods for metal oxide nano powder, ceramics and mineral catalyst synthesis. Metal oxides nanopowder in its pure or mixed form has wide potential application as chemical industrial catalyst, hot Superconductors, magnetic material, gas sensors and car catalyst convertors. One of the most important metal oxides aspects of application is uranium oxide as nuclear reactor fuel is used. In addition, UO2 is selective catalyst for converting methane to methanol process and Decomposition of organic Chlorine material. In Supercritical hydrothermal method done in high pressure reactor with critical to fluid, is new method for the... 

Despite of significant developments of optical trapping in past decays, trapping of small nanometer-sized particle faces some difficulties. Optical force reduces rapidly by decreasing the size of the particle because of reducing the particle’s polarizability. So, it is necessary to increase the intensity of incident beam to attain a stable trap. However, it can lead to damage of particle before getting trapped. Self induced back-action(SIBA) is one of the proposed solutions to overcome this problem. In this phenomena particle plays an active role in trapping by changing the surrounding electromagnetics field. In this thesis, we show that SIBA is a phenomenon that appears when we extend the... 

Taking into account the fast and ever-increasing pace of data growth, clustering algorithms emerge as the key tools for data analysis in new researches. Clustering remain as a method for decomposing data into clusters, in such a way that similar data coalesce in the same group. Different algorithms conduct clustering according to a series of initial hypotheses, without being informed about the clusters’ form and aims. Hence, in case with no conformity between initial hypothesis and the clustering aim, one cannot expect adequate response from the clustering algorithm. Exploitation of side information in clustering can play an impactful role in introduction of real models into clustering... 

Considering the limited number of works on investigation of solidification characteristics of Al-Zn-Mg-Cu cast alloys as well as the applications of this alloy system in aerospace industries, the solidification conditions of Al 713 alloy were investigated in this study. In order to achieve this goal, a number of experiments were designed and conducted including quantometry, thermal analysis, metallography and hardness measurements. In this thesis, effects of cooling rate on secondary dendritic arms spacing as well as solidification parameters including nucleation temperature, solidification time and temperature range, dendrite coherency point and formation temperature of intermetallic... 

Thin film graphene oxide(GO) membranes have been promising potential for gas purification due to thin lamellar microstructure, stable a few atom thick layers and very short intersheet distances. In this research, the nanoporous graphene oxide membranes have been prepared by vacuum and pressurized ultrafiltration on the modified polyacrylonitryle(mPAN) sublayer for helium separation from Nitrogen and carbon dioxide gas mixture. The separation performance of synthesized GO membrane was controlled by varying parameters such as concentration of stabilized aqueous GO solution, pores size range of support and its surface properties, centrifuge time, applied pressure after synthesis, humidity,... 

Because of increasing usage of modified polymers and consequent necessity for investigation and modeling of mechanical behavior of these materials, it is important to get a yield criterion for these materials. For this purpose the Gurson yield criterion presented for porous metals, was modified with regard to mechanical properties of polymers. Indeed pressure sensitivity of polymers and their large elastic strain during deformation, makes using of Gurson yield criterion problematic for modified polymers.
For modification of Gurson criterion, macroscopic hydrostatic yield stress equation was derived for a thick-walled spherical shell of epoxy and then Gurson criterion was modified with... 

Foil gas bearings are compliant surface, self-acting hydrodynamic bearings that use ambient gas as their working fluid. They do not require external pressurization and are typically constructed from several layers of sheet metal foils. In high-speed, high-temperature applications the GFB’s have the advantage of developing higher load capacities than with fixed geometry gas bearings. Since GFB’s have a complex structure consisting of a spring-like substructure with an overlying flexible surface, there exists a great variety of permutations on any given design. At current work presents a 1D model for GFB with couple solving Reynolds and Euler-Bernoulli beam equation. This mean top foil assume to... 

Natural boron consists of two stable isotopes, mass 10 (19.3%) and mass 11 (80.7%). 10B isotope has a large thermal neutron capture cross-section and it therefore, used widely in such aspects as modern industry, military equipment, medical science and so on. specially the demand of atomic energy industry for the boron isotope is increased severely. So the separation of 10B from natural boron has received very wide attention at present. There are many kinds of methods on the boron isotopes separation, such as chemical exchange reaction and distillation in boron trifluoride method, ion exchange in boric acid solution method, counter current recycle membrane cascades in boron trifluoride... 

Lameness in dairy cattle is a crucial welfare issue in dairy industry, and over the years scientists are attempting to present a detection method. In recent years it is attracting more attention to make the identification and discrimination of sounds and lames systematic and automatic. Right now, the most hopeful results have been obtained through the measurement of Ground Reaction Forces (GRF) of hooves, and analysis of load distribution between four legs, which seems applicable for wide use in dairy industry. However, the accuracy, validity, and reliability of discrimination is still far from an acceptable point, that is because of a great lack in understanding quantitative effects of the... 

In this study the feasibility of xenon separation from xenon-krypton mixture was investigated by utilizing of the chromatographic column filled with nano and micron sized NaY zeolite. For this purpose the nano NaY with the yield of 100% related to Al2O3 and the average size of 98.6 nm was synthesized through the clear solution method with the mid-adding of NaOH. Furthermore, a novel method for granulation of nano zeolite was developed by utilizing sodium alginate as an external template. In this method the production of uniform spherical granules with the different sizes in the range of several milimiteres to 100 µm was easily performed. Moreover, the results showed that the adding of... 

Natural boron includes two stable isotopes 10B and 11B with 19.3 and 80.7 weight percent respectivley.10B isotope has a high thermal neutron absorption cross section. So isotope 10B material is suitable for making atomic reactor control rods. Other and even more important applications of 10B are in disclosing neutrons in order to measure neutron reactors fluxes and also are in nuclear physics laboratories and medical radiation. This isotope also is used in the pharmaceutical and the military industries. There are several methods for separating boron isotopes. Among the distillation methods, thermal diffusion of BF3, distillation of BF3, distillation of methyl borate, boric acid distillation...