Sharif Digital Repository

Proton exchange membrane fuel cell (PEM-FC) aggregation pressure causes extensive strains in cell segments. The compression of each segment takes place through the cell modeling method. In addition, a very heterogeneous compressive load is produced because of the recurrent channel rib design of the dipole plates, so that while high strains are provided below the rib, the domain continues in its initial uncompressed case under the ducts approximate to it. This leads to significant spatial variations in thermal and electrical connections and contact resistances (both in rib–GDL and membrane–GDL interfaces). Variations in heat, charge, and mass transfer rates within the GDL can affect the... 

Proton exchange membrane fuel cell (PEM-FC) aggregation pressure causes extensive strains in cell segments. The compression of each segment takes place through the cell modeling method. In addition, a very heterogeneous compressive load is produced because of the recurrent channel rib design of the dipole plates, so that while high strains are provided below the rib, the domain continues in its initial uncompressed case under the ducts approximate to it. This leads to significant spatial variations in thermal and electrical connections and contact resistances (both in rib–GDL and membrane–GDL interfaces). Variations in heat, charge, and mass transfer rates within the GDL can affect the... 

In recent years, the need to reduce environmental impacts and increase flexibility in the energy sector has led to increased penetration of renewable energy sources and the shift from concentrated to decentralized generation. A fuel cell is an instrument that produces electricity by chemical reaction. Fuel cells are a promising technology for ultimate energy conversion and energy generation. We see that this system is integrated, where we find that the wind and photovoltaic energy system is complementary between them, because not all days are sunny, windy, or night, so we see that this system has higher reliability to provide continuous generation. At low load hours, PV and electrolysis... 

In recent years, the need to reduce environmental impacts and increase flexibility in the energy sector has led to increased penetration of renewable energy sources and the shift from concentrated to decentralized generation. A fuel cell is an instrument that produces electricity by chemical reaction. Fuel cells are a promising technology for ultimate energy conversion and energy generation. We see that this system is integrated, where we find that the wind and photovoltaic energy system is complementary between them, because not all days are sunny, windy, or night, so we see that this system has higher reliability to provide continuous generation. At low load hours, PV and electrolysis... 

In this study, UV‐Vis-NIR photodetectors based on decorated ZnO nanofibers (NFs) with optimized coverage of Au nanoparticles (NPs) fabricated via combined simple electrospinning and sputtering techniques are introduced. The effect of different coverages of Au NPs resulted from different Au nominal layer thicknesses on the morphology and optical properties of the ZnO fibers are investigated through various characterization methods. It is discovered that 4 nm Au nominal thickness provides the highest UV on/off ratio (~460), responsivity (~332 A/W), detectivity (~2.93×10 11 Jones) as well as faster rise and decay times as compared to pure ZnO nanofibers. A broad spectral response from UV to NIR... 

Communication networks with highly mobile users are emerging rapidly. Autonomous vehicular communication is an interesting example of such systems. High mobility speed causes drastic change in channel states, and consequently a doubly selective fading scenario is a proper model for such channels. In this paper, by considering this proper model, we introduce a multiuser system based on orthogonal signal division multiplexing in a cognitive radio scenario. Carrier interferometry codes are also utilized in this system. By designing the transmitter and receiver, the performance of such system is investigated. We show that this system works properly when users are moving rapidly, and moreover the... 

Ionic liquids (ILs) have been considered as a good candidate to be replaced by the conventional solvent in recent years due to their potential consumptions and unique properties. In the present study, artificial neural network was used to predict the ternary viscosity of mixtures containing ILs. A collection of 729 experimental data points were gathered from the previously public shed literatures. Different topologies of a multilayer feed forward artificial neural network (MFFANN) were examined and optimum architecture was determined. Ternary viscosity data from the literature for 5 ILs with 547 data points have been used to train the network. In addition, to differentiate dissimilar... 

This paper develops a model for estimating unsignalized intersection delays which can be applied to traffic assignment (TA) models. Current unsignalized intersection delay models have been developed mostly for operational purposes, and demand detailed geometric data and complicated procedures to estimate delay. These difficulties result in unsignalized intersection delays being ignored or assumed as a constant in TA models. Video and vehicle license plate number recognition methods are used to collect traffic volume data and to measure delays during peak and off-peak traffic periods at four unsignalized intersections in the city of Tehran, Iran. Data on geometric design elements are measured... 

To the best knowledge of us, survivability for WSN has never been studied considering failure affects on network. We perceive the network survivability as a composite measure consisting of both network failure duration and failure impact on the network. In this paper we will study network survivability in unstably state: in this state, network is affected by the failures that occur temporarily and instantly also may occur several times. In other words, the main characteristics of these failures are their frequency and being temporary. In this paper we will propose a survivability model for network in unstable state that is based on network availability. This availability model, presents... 

Traffic assignment problem (TAP) is traditionally defined without side constraints. Although introducing the side constraints into the TAP is used as a way of refining the applied assignment models, it brings some computational difficulties preventing the refined model to be applicable in the real-case problems. In this paper an iterative solution algorithm is developed for TAP with linear side constraints. This method is based on implicitly considering the side constraints by means of adding a dynamic penalty function (DPF) to the link travel times. Each of the iterations of the algorithm is reduced to an unconstrained assignment followed by updating the penalty functions. The unconstraint... 

Novel ZnO-carbon and ZnO nanofibers were fabricated by electrospinning of polymer precursor followed by subsequent annealing in nitrogen and air, respectively. Field emission scanning electron microscopy (FESEM) and X-ray diffraction (XRD) indicated the smooth and beadless nanofibers with wurtzite crystal structure. X-ray photoelectron spectroscopy (XPS) showed the presence of oxygen vacancies (VO) and chemisorbed O2 on the surface of the samples. Band gap narrowing of the ZnO-carbon nanofibers in comparison to ZnO were measured by diffuse reflectance spectroscopy (DRS). Photo-degradation of azo dye under the UV and visible light was evaluated and ZnO-carbon showed an enhancement in... 

Network survivability is one of the main design challenges in wireless sensor networks (WSN). Survivability is the ability of the network to provide essential services in the presence of attacks and/or failures, and recover full service in a timely manner. To the best knowledge of us, survivability for WSN has never been studied considering failure effects on network. We consider the network survivability as a composite measure consisting of both network failure duration and failure impact on the network. In this paper we model network survivability in steady state. In this state, network is affected by predicted failures. This modeling is based on network connectivity and coverage, when an... 

Aluminium alloys are lightweight materials relatively used in automotive industries. However, welding using the conventional welding methods is known to be difficult. In this study, the friction stir welding (FSW) known as the solid state joining process was extensively used for joining similar and dissimilar 5 mm aluminium alloy plates. The butt-joint type of similar joints (AA5083-AA5083) and dissimilar joints (AA5083-AA6061) were carried out under the same welding parameters; 1000 rpm (rotational speed) and 100 mm/min (transverse speed). Macro- and microstructural observations were acquired at the cross-section of the weld regions by stereo and optical microscopes. The microstructural... 

CuSO4/SiO2 is found to be an efficient and selective medium for the acetalization of aldehydes in the presence of ketones in solvent-free conditions under microwave irradiation. © 2005 Bentham Science Publishers Ltd  

Not only should dams be evaluated for seismic shaking, but their capability to survive potential fault displacement in their foundations should also be assessed. Safety reviews of existing dams suggest that geological-seismic evaluation of some dam sites has failed to recognize the existence of possibly active faults. In this study, the nonlinear seismic behavior of concrete gravity dams, due to relative fault dislocation occurring in foundations, has been investigated. Two types of fault movement, including normal-slip and reverse-slip, have been considered. These two types, combined with the location of fault lines, with respect to the toe, middle, and heel of the dam base, angle of fault,... 

Etheno-damaged DNA adducts such as 3,N4- ethenocytosine, N 2,3-ethenoguanine, and 1,N2-ethenoguanine are associated with carcinogenesis and cell death. These inevitable damages are counteracted by glycosylase enzymes, which cleave damaged nucleobases from DNA. Escherichia coli alkyl purine DNA glycosylase is the enzyme responsible for excising damaged etheno adducts from DNA in humans. In an effort to understand the intrinsic properties of these molecules, we examined gasphase acidity values and proton affinities (PA) of multiple sites of these molecules as well as equilibrium tautomerization and base pairing properties by quantum mechanical calculations. We also used calculations to compare... 

Interactions of α-D-glucose with gold, silver, and copper metal clusters are studied theoretically at the density functional theory (CAM-B3LYP) and MP2 levels of theory, using trimer clusters as simple catalytic models for metal particles as well as investigating the effect of cluster charge by studying the interactions of cationic and anionic gold clusters with glucose. The bonding between α-D-glucose and metal clusters occurs by two major bonding factors; the anchoring of M atoms (M = Cu, Ag, and Au) to the O atoms, and the unconventional M.H-O hydrogen bond. Depending on the charge of metal clusters, each of these bonds contributes significantly to the complexation. Binding energy... 

In the present work, mesoporous nitrogen-doped carbon nanotubes (N-CNTs) were synthesized by using a low-cost and unique set of precursors (camphor and urea). The CVD method at 1000 °C was used with different camphor/urea ratios, and Co-Mo/MgO nanocatalyst was utilized as growth catalyst. Application of mesoporous N-CNTs in selective oxidation of H2S was studied experimentally and N-CNTs interactions with H2S was also investigated using DFT calculations. The as-synthesized N-CNTs were characterized using FTIR, FE-SEM, elemental analysis, X-ray diffraction (XRD), XPS and nitrogen adsorption/desorption. The N-CNT2 sample with urea to camphor ratio (U/C) of 1 showed the highest sulfur yield at... 

Active edge sites of MoS2 nanosheets exhibit promising futures for hydrogen evolution reaction (HER), comparable with remarkable performances of highly cost platinum. However, 3D structures of MoS2 suffer from a lack of high mobility and unexposed active sites which lower the electrocatalytic activity. In this study, we show that there is a balance between increasing the active sites on the one hand and managing the charge transfer to facilitate the reaction on the other hand, and achieving this balance increases the efficiency of the electrocatalyst tremendously. For this purpose, we directly attached exfoliated MoS2 nanosheets onto carbon cloth (CC) substrate as a 3D network of conductive... 

Active edge sites of MoS2 nanosheets exhibit promising futures for hydrogen evolution reaction (HER), comparable with remarkable performances of highly cost platinum. However, 3D structures of MoS2 suffer from a lack of high mobility and unexposed active sites which lower the electrocatalytic activity. In this study, we show that there is a balance between increasing the active sites on the one hand and managing the charge transfer to facilitate the reaction on the other hand, and achieving this balance increases the efficiency of the electrocatalyst tremendously. For this purpose, we directly attached exfoliated MoS2 nanosheets onto carbon cloth (CC) substrate as a 3D network of conductive...