Sharif Digital Repository

Flow through the pores of granular materials has many instances in practice. Therefore, it is interesting to realize how some parameters, such as the shape of the particles affect the passing flow. Following the recent mathematical theory proposed by the authors, this paper deals with the issue of how tortuosity and permeability are influenced by the particle shape. Comparison of the results with the experimental data reveals the competency of the theory in predicting the impact of particle geometry  

Tunnels constructed using New Austrian Tunnelling Method (NATM) are always based on certain round (unsupported) advance lengths, after which, the temporary lining is placed. The settlement of the ground surface resulting from such construction is of high significance in design and practice. The existing data in this respect, however, is scarce. It is the aim of this paper to propose a semi-analytical procedure based on three-dimensional finite element analyses to predict the maximum surface settlement of the ground in NATM tunnels under different combinations of tunnel diameter, overburden depth, round length and soil and lining properties. The comparison of the results with three case... 

Macroscopic properties of granular materials are important in modeling a variety of flow and transport phenomena in many fields of science. Determination of these parameters has always been an issue among both researchers and engineers, mainly in view of tortuosity and permeability. This paper presents analytical functions for the tortuosity and permeability of monosized sphere arrays based on a volume averaging approach and eliminates some ambiguities by modification of the original representative elementary volume model. Veracity of the proposed formulations has been illustrated through comparisons with the latest available results on the subject. Good agreement is found  

Analytical solution of shock wave propagation in pure gas in a shock tube is usually addressed in gas dynamics. However, such a solution for granular media is complex due to the inclusion of parameters relating to particles configuration within the medium, which affect the balance equations. In this article, an analytical solution for isothermal shock wave propagation in an isotropic homogenous rigid granular material is presented, and a closed-form solution is obtained for the case of weak shock waves. Fluid mass and momentum equations are first written in wave and (mathematical) non-conservation forms. Afterwards by redefining the sound speed of the gas flowing inside the pores, an... 

Gas-to-Liquid (GTL) is a multi-staged process in which natural gas is converted to liquid fuels. The stages of GTL process are discussed. A GTL plant with 10,000 bpd capacity and have similar specifications with the SASOL process was simulated using the Aspen-Plus software and the simulation results were compared with the SASOL process data. This is an abstract of a paper presented at the 18th International Congress of Chemical and Process Engineering (Prague, Czech Republic 8/24-28/2008)  

Using a combined hydrothermal and sol–gel route, TiO2-capped ZnO nanoparticles with an average size of 60 nm were prepared. The titania shell was amorphous with a thickness of ~10 nm. Formation of Zn2TiO4 phase at higher calcination temperature was noticed. Effects of Ti/Zn molar ratio and coating time on the thickness of TiO2 shell and the photoactivity of the particles for decolorization of Methylene Blue (MB) under UV lamp irradiation (3 mW/cm2) were investigated. The nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, fourier-transform infrared spectrometry (FTIR), diffuse reflectance spectroscopy (DLS), and atomic absorption spectroscopy. Analysis of... 

Using a combined hydrothermal and sol-gel route, TiO 2 -capped ZnO nanoparticles with an average size of 60 nm were prepared. The titania shell was amorphous with a thickness of ∼10 nm. Formation of Zn 2TiO 4 phase at higher calcination temperature was noticed. Effects of Ti/Zn molar ratio and coating time on the thickness of TiO 2 shell and the photoactivity of the particles for decolorization of Methylene Blue (MB) under UV lamp irradiation (3 mW/cm 2) were investigated. The nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, fourier-transform infrared spectrometry (FTIR), diffuse reflectance spectroscopy (DLS), and atomic absorption spectroscopy.... 

In this study, both CuO nanoparticles and ZnO nanorods were anchored on thermally-exfoliated g-C3N4 nanosheets (denoted as CZ@T-GCN) via isoelectric point-mediated annealing process as a novel nano-photocatalyst towards degradation of amoxicillin (AMOX). The features of prepared materials were characterized using BET, UV–vis DRS, XRD, FT-IR, XPS, FE-SEM, TEM, EIS and transient photocurrent techniques. These analyses demonstrated the successful formation of heterojunctions between components of CZ@T-GCN nanocomposite, which reflected in significantly increased electron-hole separation and enhanced degradation of AMOX as compared with pure substances. The investigation of influential operative... 

Herein, Kiwi peel activated carbon (AC), Materials Institute Lavoisier (MIL-88B (Fe), and AC/MIL-88B (Fe) composite were synthesized and used as catalysts to degrade Reactive Red 198. The material properties were analyzed by the FTIR, BET-BJH, XRD, FESEM, EDX, TGA, and UV–Vis/DRS. The BET surface area of AC, MIL-88B (Fe) and AC/MIL-88B (Fe) was 1113.3, 150.7, and 199.4 m2/g, respectively. The band gap values (Eg) estimated by Tauc plot method, were obtained 5.06, 4.19 and 3.79 eV for AC, MIL-88B (Fe) and AC/MIL-88B (Fe), respectively. The results indicated that the AC/MIL-88B (Fe) composite had higher photocatalytic activity (99%) than that of pure AC (79%) and MIL-88B (Fe) catalysts (87%).... 

Influence of two nano-size additives oSubject:A. Suspensions. Subject:C. Electrical conductivity. Subject:Castable. Subject:E. Refractories. Subject:Castables. Subject:Electrical conductivity. Subject:Electrical property. Subject:High alumina. Subject:matrix. Subject:Mechanical strength. Subject:Nano-size. Subject:Polycarboxylate ethers. Subject:Refractory castables. Subject:Working time. Subject:Alumina. Subject:Cement additives. Subject:Electric conductivity. Subject:Ethers. Subject:Suspensions (fluids) Subject:Refractory materials. n electrical properties of suspension matrix of self-flowing low-cement high alumina refractory castable is investigated. For this purpose, castament FS 10 and... 

Bi2O3 compositions were prepared to investigate the effect of rare earth metal oxides as co-dopants on phase stability of bismuth oxide. Compositions containing 9-14 mol% of Y2O3 and Er2O3 were synthesized by solid state reaction. The structural characterization was carried out using X-ray powder diffraction. The XRD results show that the samples containing 12 and 14 mol% total dopants had cubic structure, whereas the samples with lower dopant concentrations were tetragonal. Comparing the lattice parameters of the cubic phases of (Bi 2O3)0.88(Y2O3) 0.06(Er2O3)0.06 and (Bi 2O3)0.86(Y2O3) 0.07(Er2O3)0.07 revealed that lattice parameter decreases by increasing the dopant concentration. The XRD... 

SiC Ceramic was joined to itself using active brazing alloys, like Ti in shape of sheet filler of Ag-cu and Ti-6AI-4V. This operation occurred in an inert gas furnace. Interfacial microstructure was studied with scanning electron microscopy and X-Ray diffraction. Variation of Electrical Specific Resistance measured by 4 pin astute multimeter and strength of these joints was measured by fracture shear loading. This joint happened at 900°C and upper temperature with 90 minutes and upper time. Electrical specific resistance goes up with the joint in low temperature and time but this variation is very little. The microstructure showed excellent bonding at the interfaces. The data showed also... 

In this paper, design and analysis using analytical expressions for the inverse class-E power amplifier (PA) operating at the outside nominal operation, i.e., class- $ ext{E}-{mathrm{n}}$ PA, is presented. This operation is defined as nonzero current switch (n-ZCS) and nonzero-derivative-current switch (n-ZDCS) conditions. The generalized design equations as a function of design specifications, load resistance, and a given dc-supply voltage are derived. Two degrees of the design freedom achieved thanks to n-ZCS and n-ZDCS that are utilized for the simultaneous satisfaction of design specifications, such as peak-switch-voltage and peak-switch-current along with a given load resistance. The... 

In this paper, design and analysis using analytical expressions for the inverse class-E power amplifier (PA) operating at the outside nominal operation, i.e., class-En PA, is presented. This operation is defined as non-zero current switch (n-ZCS) and non-zero derivative current switch (n-ZDCS) conditions. The generalized design equations as a function of design specifications, load-resistance and a given dc-supply voltage are derived. Two degrees of the design freedom achieved thanks to n-ZCS and n-ZDCS that are utilized for the simultaneous satisfaction of design specifications, such as peakswitch- voltage and peak-switch-current along with a given loadresistance. The output power... 

In this study, different concentrations of ascorbic acid (50, 100 and 200 μg/mL) were added to the liquid phase of a calcium phosphate cement (CPC). The cements were immersed in simulated body fluid (SBF) for different intervals and physical, physicochemical and mechanical properties of them were evaluated. The release of added ascorbic acid from CPCs into the SBF solution was also studied. From the results, both setting time and injectability of CPC decreased by adding ascorbic acid, however the compressive strength was sharply increased before soaking in SBF solution. But, the compressive strength values of all cements (with or without ascorbic acid) soaked in SBF solution for more than 7...