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    Sol–gel preparation and corrosion properties of Zn–SiO2 nanocomposite thin film

    , Article Journal of Sol-Gel Science and Technology ; Volume 79, Issue 1 , 2016 , Pages 133-143 ; 09280707 (ISSN) Razavizadeh, O ; Ghorbani, M ; Sharif University of Technology
    Springer New York LLC  2016
    Abstract
    In this study, a novel nanocomposite thin film of Zn–SiO2 is considered. The thin film is a viable alternative for higher abrasion-resistant coatings. DLS technique revealed that the nanoparticle size is to be below 10 nm, and FE-SEM showed particle size to be below 17 nm in the obtained coating. The coating was found to be highly adhesive with an amorphous structure and hardness value above 1000HV. Corrosion resistance studies using linear polarization technique revealed that this unique nanocomposite has a lower corrosion rate than hot-dip galvanized steel at higher positive potentials. A conclusive mechanism for corrosion and erosion improvement has been proposed. Graphical Abstract:... 

    Surface modification of carbon steel by ZnO-graphene nano-hybrid thin film

    , Article Surface and Coatings Technology ; Volume 363 , 2019 , Pages 1-11 ; 02578972 (ISSN) Razavizadeh, O ; Ghorbani, M ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Application of corrosion resistant coatings is one of the most widely used means of protecting steel. Zinc coated (galvanize) steel, is well known for galvanic protection of steel substrates and nowadays, particular attention has been paid to the coupling of graphene oxide (GO) with metallic materials, in order to lessen corrosion rate. In this research, an isopropanol supercritical reducing environment prepared to make zinc ions bond directly with graphene oxides, to form a button shape hybrids of ZnO-Graphene (ZnOG). The hybridized bonding between zinc and graphene oxide is confirmed by Fourier Transform Infra-Red analysis. And the morphology revealed, using a Field Emission Scanning... 

    The Structure and Corrosion Behavior of Synthesized Zn-SiO2 Nano-composite Coating by Sol-Gel Method

    , M.Sc. Thesis Sharif University of Technology Razavizadeh, Omid (Author) ; Ghorbani, Mohammad (Supervisor)
    Abstract
    Zinc–silicanano-composite coatings were produced by successive dip coatand sintering procedure from different sol-gel solutions. The surface and cross-sectional morphologies of Zn-SiO2 nano-particles (NPs) were examined using field emission scanning electron microscopy (FE-SEM). Corrosion resistance evaluated by means of polarization and electrochemical impedance spectroscopy showed that even thin films of Zn-SiO2 in orders of 200 nm can have corrosion rates as low as conventional hot dip galvanized steels. Multi-layers coatings have been studied and showed that 10 layers coating with the thickness of 2m has the lowest corrosion rate with the passive region in anodic branch. Corrosion... 

    Enhanced hardness and corrosion resistance of Zn/SiO2 films by electrodeposition

    , Article Journal of the Electrochemical Society ; Volume 162, Issue 9 , 2015 , Pages D480-D485 ; 00134651 (ISSN) Ghorbani, M ; Salehi, F ; Razavizadeh, O ; Sharif University of Technology
    Electrochemical Society Inc  2015
    Abstract
    The electrodeposition of Zn-SiO2 nanocomposites has been investigated with different electrolytes: triethanolamine as a dispersing agent, and cetyl trimethylammonium bromide and dodecyl dimethylamine oxide as ionic (cationic) and non-ionic surfactants. Appropriate electrophoretic potentials for each solution were obtained using cyclic voltammetry. The results show that the most stable SiO2 nanoparticles with zeta potential range of 25 to 41 mV, along with highest SiO2 mobility of 0.4 to 0.7 m2/V.s were dispersed by triethanolamine in ethanol and the resulting coating adhesion improved up to 5.87 MPa in the standard pull off test, with the enhanced hardness of... 

    Photo-Electrochemical application of ZnOG thin film for in situ monitoring of steel sour corrosion

    , Article Surface Engineering and Applied Electrochemistry ; Volume 56, Issue 2 , 2020 , Pages 242-247 Razavizadeh, O ; Ghorbani, M ; Shafiekhani, A ; Sharif University of Technology
    Pleiades Publishing  2020
    Abstract
    Abstract: Further to traditional corrosion monitoring techniques for rated deteriorations, nowadays modern electrochemical monitoring methods are promising for the control of non-rated damage mechanisms. Considering carbon steel as the most commonly used alloy in the oil and gas industry, there are special grades under NACE MR0175 standard which are immune to sour corrosion. However, according to the industry reports, their immunity can be terminated by upset conditions or on site repairs. This issue will impose either a high operational risk or exorbitant maintenance and inspection costs. Hence, in this paper, a new monitoring technology framework is discussed to lessen a catastrophic... 

    Dynamic relay selection and resource allocation in cooperative networks based on OFDM

    , Article 17th European Wireless Conference 2011, EW 2011 ; 2011 , Pages 328-332 ; (Print ISBN): 978-3-8007-3343-9 Javidbakht, O ; Alizadeh, N. N ; Razavizadeh, S. M ; Sharif University of Technology
    2011
    Abstract
    In this paper, we are planning to introduce a new method for relay selection and resource allocation in OFDM-based cooperative networks. Up to now, there have been relatively few works clearly concentrating on the combination of relay selection and resource allocation in such networks. In our work, a network with a single transmitter, a single receiver and a group of relays is considered. Relays work on Amplify and Forward (AF) method and there is no direct link between the transmitter and the receiver. The optimization problem is to maximize the throughput of the receiver with constraints on the amounts of the power of the transmitter and relays, and subcarriers. We will introduce an... 

    Effect of photoelectrochemical activity of ZnO-graphene thin film on the corrosion of carbon steel and 304 stainless steel

    , Article Journal of Materials Engineering and Performance ; Volume 29, Issue 1 , 2020 , Pages 497-505 Razavizadeh, O ; Bahadormanesh, B ; Ghorbani, M ; Simchi, A ; Sharif University of Technology
    Springer  2020
    Abstract
    In this research, the ZnOG hybrid thin film was produced via solgel method. The surface morphology, band gap and photoactive properties of the films were studied by means of SEM, UV–Vis and photoluminescence analysis. In addition, the ability of the thin film in photocathodic protection of carbon steel (CS) and 304 stainless steel in 3.5 wt.% NaCl and Na2S solutions under dark and UV illumination was investigated by polarization test as well as OCP and current measurements during coupling of steels with ZnOG photoanode. The mix band gap is reduced to the orders of 1.17 eV through hybridization of ZnO with graphene oxide. In both NaCl and Na2S solutions, the ZnOG thin film could effectively... 

    ECG Denoising by Deterministic Approaches

    , M.Sc. Thesis Sharif University of Technology Taghavi Razavizadeh, Marjaneh (Author) ; Shamsollahi, Mohammad Bagher (Supervisor)
    Abstract
    The goal of the research presented in this thesis is removing noise from electrocardiogram (ECG) signals. The electrocardiogram is a test that measures the electrical activity of the heart. The information obtained from an electrocardiogram can be used to diagnose different types of heart disease. It may be useful for seeing how well the patient is responding to treatment. The extraction of high resolution ECG signals from noisy measurements is among the most tempting open problems of biomedical signal processing. Extracting useful clinical information from the real (noisy) ECG requires reliable signal processing techniques. Numerous methods have been reported to denoise ECG signals based on... 

    Fabrication of Graphene-WO3 Nanocomposites as Photocatalyst in the Visible Light Region

    , M.Sc. Thesis Sharif University of Technology Choobtashani, Mohammad (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    WO3 is known as a photocatalyst in the visible light region, but with lower efficiency compared to more interesting semiconductor photocatalysts such as TiO2 and ZnO. Many attempts have been done to increase the efficiency of this photocatalyst by incorporating metal and metal oxide nanoparticles or recently carbon nanotubes.On the other hand, application of graphene, as an unrolled carbon nanotube, for increasing the photocatalytic activity of TiO2 and ZnO has shown positive results. Furthermore, it was reported that such semiconductor photocatalysts (and very recently WO3) can photocatalytically reduce the chemically exfoliated graphene oxide sheets under UV-vis irradiation.
    In this... 

    Synthesize of Graphene Nanoribbons with a Non-Zero Energy Band Gap for Inactivation of Alive Cells Using Infrared Irradiation

    , M.Sc. Thesis Sharif University of Technology Emamy, Hamed (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    Graphene is a one layer atom thickness and zero energy gap so for using it in nano electronic and transistors baised on graphene it's energy gap should be opened.one of the methods for opening graphene band gap is creating nano scale boundaries or synthesize graphene nanoribbons. One of the new methods for graphene nanoribbon synthesize is longitudinal opening of carbon nanotube. In this thesis graphene nanoribbons synthesize with this method and analyze with AFM and Raman spectroscopy. Carbon nanotubes also have energy gap and IR absorption recently they used for living cell destruction. In this thesis we synthesize graphene nanoribbons and analyzing their optical absorption and use it for... 

    Fabrication of Graphene/TiO2 Nanowalls as Visible Lights Photocatalysts

    , M.Sc. Thesis Sharif University of Technology Rahimi, Kourosh (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    TiO2 is known as a photocatalyst in near UV-Visible light region with better efficiency compared to other semiconductor photocatalysts. Many attempts have been done to increase the efficiency of this photocatalyst. also, application of 2D carbon nanostructures namely graphene for increasing the photocatalytic activity of TiO2 has shown positive results.
    In this research, we first synthesized Graphene Oxide (GO) suspension by exfolation of graphite oxide suspension. then we fabricated TiO2 thin films on glass substrates by so-called sol-gel method. finally we fabricate Graphene Oxide/TiO2 nanowalls composite films as a photocatalyst in visible light. X-ray photoelectron spectroscopy... 

    Synthesis of Graphene Nanosheets for Stem Cells Applications

    , M.Sc. Thesis Sharif University of Technology Shahsavar, Mahla (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    Graphene nanogrids fabricated by graphene nanoribbons obtained through oxidative unzipping of multi-walled carbon nanotubes, used as two-dimensional selective templates for accelerated differentiation of human mesenchymal stem cells (hMSCs), isolated from umbilical cord blood, into osteogenic lineage. The biocompatible and hydrophilic graphene nanogrids showed high actin cytoskeleton proliferations that coinciding with patterns of the nanogrids. The amounts of proliferations found are slightly better than proliferation on hydrophilic graphene oxide (GO) sheets, and significantly higher than non-uniform proliferations on hydrophobic reduced graphene oxide (rGO) sheets and polydimethylsiloxane... 

    Synthesis of Graphene from Waste by Chemical Exfoliation and Study of It’s Physical Characteristics

    , M.Sc. Thesis Sharif University of Technology Mirsepah, Ali (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    One atom thick layer of pure carbon in bonded and hexagonal lattice is named graphene. graphene has unique mechanical, optical, thermal and electrical properties and because of these properties has grabbed attention. graphene has been made from high pure graphite by different methods such as CVD(chemical vapor deposition) , chemical exfoliation , micromechanical cleavage and colloidal suspension. through these methods, green methods for synthesis of graphene, using eco-friendly reductants during synthesis of graphene instead of hydrazine and recently using waste(not graphite) are attractive for synthesis of graphene. Following this idea , a group has produced graphene from wastes such as... 

    Synthesis of Graphene Oxide and Study of its Fluorescence Properties

    , M.Sc. Thesis Sharif University of Technology Akbari, Ebrahim (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    Graphene oxide is a single sheet of Carbon atoms which has been arranged on a two-dimensional honeycomb lattice. Functional groups such as epoxy, carboxyl and carbonyl are located on basal plane and at the edges of graphene oxide and they localize electrons on the surface of graphene oxide and open band gap in its band structure. Pure graphene has zero band gap, so existence of fluorescence properties is unlikely; but graphene oxide has fluorescence properties due to band gap in its band structure. Fluorescence properties of graphene have been used in live cell imaging and drug delivery, so study and increasing of fluorescence properties is significantly important. The purpose of this... 

    The Use of Hydrogen Rich Water for Synthesis of Hydrogenized Graphene and Investigation of Its Properties

    , M.Sc. Thesis Sharif University of Technology Ghorbani, Fatemeh (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    Graphene is a two dimensional lattice which is created from carbon atoms. Having special feature, it has such various medical usage, for example in diagnosing and treating cancer. Adding a particular factor to graphene could improve their efficiency. In comparis on with graphene itself, graphene oxide and reduced graphene oxide are much more successful in diagnosing and treating than others because of their higher hygroscopic. Recent studies state that hydrogenized combinations including hydrogenized graphene show desired results. Due to its higher hygroscopic and the possibility of adherence to the cells, hydrogenized graphene could be very effective in diagnosing and treating the sarcomas.... 

    A Meta Heuristic Approach for Design of a Network System in Mass Customization

    , M.Sc. Thesis Sharif University of Technology Puresmaili, Ehsan (Author) ; Fattahi, Omid (Supervisor)
    Abstract
    This study discusses about mass customization and optimization of supply network in which both goal considering to set the flow of raw material and final product to satisfy the customer demand. The mass customization is more important concept in this study, so that this goal is placed to the first objective. In this research, the model which contained both goal is presented. The model focus on mass customization and try to satisfy various products demand, which constitute 3 kind of speed demands. Each product can satisfy in 3 way: fast, normal, slow.In the first model the new approach present in which the speed affects all of supplying, manufacturing and distributing system. The system try... 

    Identifying the risks of Iranian Knowledge BasedFirms Using Fault Tree Analysis (FTA)

    , M.Sc. Thesis Sharif University of Technology Sarhadi, Maryam (Author) ; Fattahi, Omid (Supervisor)
    Abstract
    Knowledge Based Firms are considered to be important for the economic development of a country in regards to both employment growth and innovative activity. The latter is believed to contribute significantly to the increase in productivity and therefore the competitiveness of Iran’s economy. This study contributes to the above literature by investigating the factors that are believed to treat the growth of such firms in Iran. The purpose of this study is to identify functional risks of vital signs monitors via Fault Tree Analysis (FTA) method to use as a guide for manufacturers to identify and control hazards. Therefore, 30 knowledge based firms were selected as sample. Then, based on a... 

    A Novel Reliability Model for Information Technology Web services

    , M.Sc. Thesis Sharif University of Technology (Author) ; Fatahi Valilai, Omid (Supervisor)
    Abstract
    The Internet is often used for communication-based applications such as online banking, stock trading, and shopping where service interruption is unacceptable. Thus, analysis of the impact of the failures of hardware, software, and related services’ performance quality of the service provided to users is of importance to designers and managers in these functions. In this study, we developed a strategy to the design of a dynamic combination of file servers with the aim of providing reliability and SLA. At first, we examine the reasons for the violation of service level in file host services and datacenters, and then we introduce the criteria to measure the violation of service level on the... 

    Fabricating Graphene Paper and Determining Its Electrical and Mechanical Properties and Using It for Proliferation and Differentiation of Neural Stem Cells

    , M.Sc. Thesis Sharif University of Technology Akbar Shirazian, Soheil (Author) ; Akhavan, Omid (Supervisor)
    Abstract
    Nowadays, tissue engineering and stem cells-based therapies have outlined a promising prospect in neural networks regeneration. But it usually requires biocompatible and conductive scaffolds for culturing neural stem cells and directing their differentiation toward the neurons. Graphene due to its unique physical and chemical properties has attracted much interest in tissue engineering. For this purpose, in this study biocompatible graphene oxide foams have been used for neural stem cell culturing. For the first time, graphene oxide foam were fabricated by precipitation of chemically exfoliated graphene oxide sheets in an aqueous suspension onto the PET substrate at ~80 oC under UV... 

    Product Portfolio Management Using Life Cycle Considerations

    , M.Sc. Thesis Sharif University of Technology Ebrahimian, Mahsa (Author) ; Fattahi, Omid (Supervisor)
    Abstract
    Today’s organizations always encounter limitations on the way of achieving their goals. Budget constraint, inventory constraints, capital constraints are issues which complicates management decision making.
    Global market has enabled manufacturers compete globally. Even position their factories in other countries and use of competitive advantages and other markets demand. This is why decision making in production and manufacturing domain has been complicated. Decision making in production and manufacturing should become faster and more precise in order to keep market competitiveness. Organization should make long term or strategic decisions and short term decisions about keeping the...