Sharif Digital Repository

In this research we focus on study and fabrication of ZnO composite nanofibers by electrospinning method for photocatalytic application. The most important challenges in the field of photocatalyst are photocatalytic activity under the visible light and efficiency enhancement. ZnO is a wide band gap semiconductor and it is not active under the visible light. In Iran, we have more than 300 sunny days in a year. Therefore fabrication and application of photocatalytic material with activity under the sun light that contained 40% of visible light is so vital in our country. In the first part of this project, ZnO-CNT nanofibers were fabricated and carbon doped in the crystal lattice of the ZnO.... 

In this study, the micro and nano particles of substituted strontium hexaferrites with nominal composition of SrFe12-xTix/2Znx/2O19 (x=0, 0.5, 1, 1.5, 2 and 2.5) were prepared by a co-precipitaion method. Ferrite-PVA composites (70:30) with thickness of 1.8mm were prepared at 220°C and 50Mpa. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), energy dispersive spectrometer (EDS), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) were employed for characterization of synthesized powders and composites. XRD and FTIR results showed that single phase hexaferrite were obtained for almost all of the... 

Rehabilitation usually involves physical therapy, occupational therapy and counseling for the patient's morale to help to restore his power and performance. Considering the economic outlook and the costs of rehabilitation methods and due to the increasing prevalence of stroke and the need to recover the patients in a short period, only the use of robotic systems opens the door to the medical community. Since a large rehabilitation robots designed and built and each been used according to their advantages and shortcomings. In this project, the major shortcomings examined and exoskeleton designed on two major features including portability and covering shoulder workspace. Shoulder movement was... 

Water treatment from industrial and domestic pollutants is one of the most important issues in recent decades. In the present research, simulation of water purification using single-layer graphene membrane were studied. The effects of nanopores diameter, applied pressure, concentration of contaminant ions, and functional groups on the amount of filtered water and ion rejection through the membrane were quantified. Contaminant ions including Na+, K+, Mg2+, Ca2+, and Cl- were dissolved in water. Based on the results, by increasing the pore diameter and applied pressure, more water would pass through the membrane. Also it was concluded that pores with functional groups have better performance... 

The present study deals with the development of development of fragility curves for confined masonry buildings with the emphasis on masonry school buildings by means of numerical simulation. In doing so and based on the results of several previously-performed tests in Iran, simple analytical models for confined masonry walls capable of predicting various failure modes and also simulating different behavioral characteristics of these walls in the form of cyclic force-displacement curves were presented. In order to endure the ability of the proposed analytical models in simulation of seismic response of existing confined masonry buildings, a static-cyclic in-situ test on a real typical... 

In this thesis, three novel geothermal-based ORC systems are proposed to enhance efficiency and to recover the waste heat recovery. The proposed systems are modeled based on basic ORC system (concept 1), ORC system with internal heat exchanger (concept 2), and regenerative ORC system (concept 3). Accordingly, two thermoelectric generators are introduced into the systems to exploit the waste heat of the system. For this purpose, the condenser is replaced by a TEG unit, while the other TEG unit is employed to recover the waste heat of the reinjected geothermal fluid. A comprehensive numerical investigation is conducted to compare the proposed systems from thermodynamic and thermo-economic... 

In communications systems, coding is used to combat channel errors. The redundancy introduced by coding enables the detection and/or correction of errors occurring in the channel. In addition to communications systems, coding is also beneficial in various other systems such as distributed storage systems and blockchain systems to cope with node failures, data erasures, and adversarial behaviors attempting to modify information. In existing applications of coding, it is generally assumed that the encoding operation is performed correctly and without errors, and errors are applied to the encoded data. In recent years, applications have emerged where the assumption of error-free encoding is not... 

In this work hydrometallurgical route for processing spent commercial catalysts (Co/Al2O3) are investigated for leaching the Cobalt component. The used catalysts were initially pre-oxidized at 500 °C and 5 h in order to eliminate coke and other volatile species present. Pre-oxidized catalysts were dissolved in solvents such as H2SO4, HNO3, HCl and H2O at 80-90 °C, and the remaining residues separated from the solution. These experiments were performed at different concentrations, presence and absence H2O2 solution. Also effect of reflux on leaching process investigated. The result show the yield of the pre-oxidized catalysts extracted with highly concentration of extractant is higher than... 

Iran is a country with bright cultural and historical background, and rich natural resources. It is also one of the important oil and gas exporters with a special geographical situation. The world energy needs are increasing rapidly and that requires higher oil production. On the other hand, oil is Iran’s most important source of revenue and the country is highly dependent on oil export. Islamic republic of Iran’s (I.R.I) 1404 program is visioning the country to be the first producer of material in the region, the second producer of oil in OPEC, and the third producer of gas in the world. Although critical conditions can slow down the process to achieve the vision, implementing this vision... 

Adobe structures are considered as masonry structures which are out of scope of 2800 Iranian code. Due to this code, since these structures are made of weak materials, they do not have a considerable resistance to earthquakes. Since these structures can be found all around Iran; therefore, seismic study of walls as an important component of these structures, is, indeed, necessary. During this study, cyclic tests on three types of adobe walls, without opening, with window-opening, and with door-and-window-opening with a scale of 2:3 were done to study their in-plane behavior and also their failure modes. Based on our observations, in these walls, because of small ratio of height to length,... 

Thermodynamic analysis of a system is a method for recognizing the type of energy transmission between system and surrounding environment. It also helps to find how macroscopic properties of the system change during this process. This analysis is based on first and second laws of thermodynamic. The first law expresses conservation of energy and inspects quantity of energy transmission but doesn’t evaluate quality of energy. The second law expresses quality of energy and the ability of doing work. The analysis that uses both of the laws is named exergy analysis. By exergy analysis the place of useful energy losses in the system can be determined. In this research the exergy analysis of... 

In the first part of the thesis, we introduce the structure of a Nano-Newton CMOS-MEMS capacitive force sensor. This force sensor has been utilized out-of-plane sensing mechanism with high accuracy and reliability. Also, we discuss about sensitivity analysis of this force sensor. The largest change of capacitance (increased capacitance + decreased capacitance) occurs in ℓ=2/3. Sensitivity for increased capacitance grows by 8.33% and for decreased capacitance grows by 2.27%. The proposed method provides useful guidelines to increase the sensitivity of the sensor up to 250%. In the second part, a fixed structure controller, PID type, is proposed to control and suppress the in-plane vibration... 

Superhydrophobic surfaces have attracted so mucha attenetions in recent years. High contact angle, Low adhesion and low friction drag are the most important features of these surfaces. Two main parameters of these surfaces are hydrophobicity and micro-( or nano) scale roughness. In this Project a 2-D simulation of flow on superhydrophobic surfaces have been considered. Shan-Chen multiphase Lattice Boltzmann Model has been used for the simulation and carnahan-starling equation of state have been used or a higher density ratio. In the first step flow in a channel with smooth walls with different hydrophobicity have been simulated and effects of hydrophobicity on pressure drop have been... 

Interconnects in SOFC’s has oxidation problems which is Because of high temperature operation. Also Cr migration to cathode make chroumiom poisoning problems and all of this affects SOFC’s efficiency. To solve this problem researchers decided to use some protective coating on interconnect. The best group of coatings is Mn-Co Spinels. In this thesis (Mn,Co)3O4 spinels was synthesized via solid state reaction. MC reffered to Mn1.5Co1.5O4 was calcined at 850°C and then sintered at 1200°C. It’s electrical conductivity measured by 4-point probe DC method. It had the lowest ASR (17mΩ.cm2) among other stochiometries. To reduce the sintering temperature, Cu and Y was added as dopants. Among the... 

Supersonic separators with neither rotating parts nor chemical process, physically separate particles in a multi-phase flow. In comparison with general separation techniques, which are utilized in industries, specifically this equipment is cheaper, smaller and lighter. Condensation and separation at supersonic velocity is the key to achieve a significant reduction in both capital and operating costs. In this study, a two dimensional de Laval nozzle and few three-dimensional supersonic separator have been modeled. The 3D models modified in shape and dimensions. Impellers were created to form swirl flow. The models were simulated by the use of CFD software ANSYS FLUENT. Diverse inlet pressures... 

In this thesis, a dynamic model of the biomimetic robotic fish with a flexible tail is developed. In this model, the oscillating frequency of the tail controls the forward velocity, and the body spline offset parameter controls the heading angle. The robotic fish were divided to two parts: a rigid body, and a flexible tail. The rigid body includes the head and the electrical and mechanical equipment. The bond graph model was developed and the numerical values were extracted from constructed robotic fish have also been hydrodynamically analyzed. Simulation results were quantitatively compared and verified with Matlab Simmechanics simulations. These simulations described the lateral movement...