Sharif Digital Repository

Thermodynamic modeling is a useful method for predicting of asphaltene precipitation due to various reasons, such as CO2 injection, mixing of different oils in oil storage and pressure changes. However, the application of solid model and thermodynamic micellization model, for prediction of asphaltene precipitation under gas injection condition, hasnot been improved. In this work, two computer codes which are based on two different asphaltene precipitation thermodynamic models, 1-Thermodynamic Micellization Model and 2- Solid Model, have been developed, and, used for predicting of asphaltene precipitation data reported in the literature as well as the experimental data obtained from high... 

It is widely accepted that under reservoir conditions there exists some degree of block-to-block interaction that may lead to capillary continuity. The formation of liquid bridges causing capillary continuity between blocks will significantly affect the ultimate oil recovery. However, accurate modeling of the growth and detachment of traveling liquid bridges which causes capillary continuity between blocks remains a controversial topic. In this work the generalized continuity and momentum equations along with fracture capillary pressure are combined to develop a mechanistic model for formation of traveling liquid bridges between blocks. Firoozabadi and Ishimoto (1994) model is considered for... 

Increasing the global demand for energy and decreasing the production rate of oil reservoirs have forced the oil companies to focus on enhanced oil recovery (EOR) extensively. This paper summarizes the design, reservoir simulation, and results of different gas injection scenarios in one of the Iranian complex oil reservoirs. This complex reservoir is located in the south west of Iran and is made up of sandstone, limestone, and dolomite layers. It is an under saturated reservoir with no gas cap but with a strong aquifer. Oil production has started in 1977, but due to strong aquifer the production is still in the plateau period. In this study, by simulation, it is estimated that natural... 

Iranian Power industry has undergone fundamental changes since deregulation started in 2003. Currently, bulk trade of electricity in the industry is mainly conducted through a day ahead wholesale market, representing over 98 percent of the exchange of electricity within the grid. Although the current market regime is under operation for over 4 years, several political, cultural and operational obstacles have hindered effective evolution of the restructuring process. Low political support from privatization of the industry assets backed by lack of confidence and trust in market economies in general, and low economic incentive of the market players has slowed down formation of an effective... 

The most fundamental concept in considering electrical properties of reservoir rocks are formation Resistivity factor and Resistivity index which are defined by Archie and are useful in interpretation of well logging, evaluation of porosity and saturation. A theory on the relationship between formation resistivity factor and porosity, also resistivity index and saturation are presented by use of parameters Cementation factor and Saturation exponent. The Archie equation is valid only when the rock is strongly water-wet and clay free, which is not the case in carbonate rocks. Therefore the Archie equation cannot be generalized over the entire carbonate reservoirs. On the other hand influence... 

The advent and proliferation of computer networks have dramatically changed computing, communications and more importantly, our daily lives. The global network of computer networks, the Internet, has enabled novel ways of distributed information sharing that were unthinkable just a short decade ago. With invaluable opportunities comes the grand challenge of developing methodologies for collaborative capturing, processing, storage, dissemination and sharing of information. The present work takes an important step toward addressing this grand challenge. In particular, we study and evaluate a novel programming paradigm, referred to as “Distributed Semantic Programming”, in which semantical... 

The optimum wave functions and calculation method were obtained using a 24 factorial design. Based on preliminary experiences, the following four factors at two level was selected: electron correlation, triple-ξ valence shell, diffuse function and polarization function.
The wave functions for calculating gas phase 1H chemical shifts of primary and secondary alcohols were optimized using factorial design as multivariate technique. Gas-phase experimental 1H chemical shifts of 18 alcohols were used to establish the best levels of theory for obtaining 1H chemical shift, among them the new experimental values of 1H chemical shifts of 10 alcohols were obtained in our laboratory. HF/6-31G(d,p)... 

Disturbance rejection is one of the most important criteria that should be considered when designing control systems. The problem has been widely investigated and studied when the parameters of disturbance signal is known. However, there are still ongoing researches in the field when the parameters of disturbance signals are uncertain and/or varying with time. In some applications the disturbance signal can be modelled by special dynamics, e.g., step type disturbances with unknown magnitude, sinusoidal disturbances with unknown magnitude and frequency, and damped sinusoidal disturbances with unknown magnitude, frequency and damping factor. In such cases, an adaptive scheme for estimating the... 

The effects of combined task demands on the way muscles are recruited to balance external loads during posture and movement is of great importance in quantitative analysis of upper arm function. Pain and disability of shoulder joint is becoming more important as population spends more often interacting with computers in seated position and carrying repetitive tasks using upper extremities. Shoulder joint that is more dependent on the muscles for its normal function than other joints such as hip due to its small articular surface and large range motion has been used here to study its coordination during isometric exertions. Since, the numbers of tasks that could be performed are enormous. In... 

In this project rotational barrier around the C-N bond in 4-ethyle-morpholine- carboxylate has been studied using DNMR spectroscopy. Spectra were taken at variable temperature, and then with simulation of bandshape broadening pattern at coalescence region, rate constants of exchange were obtained for all temperatures. For simulation of line-shape broadening Spinworks software was used, that with two interfaces made possible simulation with two bandshape simulator programs, DNMR and MEXICO. The rate constants obtained from simulations, were used for calculation of thermodynamic activation parameters (∆G#, ∆H#, ∆S# and Ea). ∆G# 298 value of 13.66 Kcal/mol for 4-ethyle-morpholine- carboxylate... 

Soil liquefaction is a phenomenon in which soil loses much of its strength or stiffness for a generally short time but nevertheless long enough for liquefaction to be the cause of many losses. Thus, many researchers have worked on the factors which affect this phenomenon. Effects of initial static shear stress on liquefaction strength of loose and medium dense Babolsar sand specimens were investigated in this study. Babolsar sand is fine to medium uniform sand classified as SP in USCS. Tests were performed with cyclic simple shear and static triaxial devices. All tests were performed under consolidated undrained conditions. Cyclic simple shear tests were performed under constant vertical... 

The development of effective models for classification problems, such as the problem of selecting which credit applicants to accept, has been the subject of intense research for decades. Many static and dynamic methods, ranging from statistical classifiers to decision trees, nearest-neighbor methods, and neural networks, have already been proposed to tackle this problem and to assist decision making in the area of consumer and commercial credit. Given the profusion of modeling and data management techniques, it is often the case that which model has the more appropriate outputs in classification of the same problem. Among the stated methods although the latter, Neural Networks, is powerful... 

Nowadays, in our contemporary societies the social networks and online communities have carved for themselves a crucial niche and unique status. Maintaining and enhancing a core relation between their communities, thus have proven to be a worthy challenge to IT professionals. We have proposed a model for developing and maintaining a cohesive relation between members in social networks and improved their interaction and cooperation via collaboration of different social networks .We focus on the definition and properties of transitivity and semantic attributes ,which explains the relationship between members’ attributes and their membership level in social networks and leading us to provide... 

Accurate prediction of relative permeability for various reservoir rocks at various saturation conditions has been of concern for a long time in petroleum industry. Relative permeability is known as one of the most significant parameters in simulation of actual multi-phase flow through porous media during life-time of a hydrocarbon reservoir. In addition, it plays important role in oil production and well completion. Direct experimental measurement in order to determine relative permeability of porous rock has long been recorded in petroleum related literature. However, empirical methods for determining relative permeability are becoming more widely used, particularly with the advent of... 

We extend the non-relativistic AdS/CFT correspondence to the fermionic fields. In particular we study the two point function of a fermionic perator in non-relativistic CFTs by making use of a massive fermion propagating in geometries with Schrodinger group isometry. Although the boundary of the geometries with Schrodinger group isometry differ from that in AdS geometries where the dictionary of AdS/CFT is established، using the general procedure of AdS/CFT correspondence، we see that the resultant two point function has the expected form for fermionic operators in non-relativistic CFTs، though a non-trivial regularization may be needed. Also we study Weyl symmetry for non-relativistic... 

Members of Centaurea species are common traditional medicines throughout the world. For this reason medicinal plants are the targets of intense Phytochemical studies. In this research we have investigated Centautea Golestanica which are members of this genus and endemic of Iran. In this research, One Flavonoid, two Sesquiterpenelactones and two triterpenoides were elucidated by advanced spectroscopic techniques such as IR, MS, 1H NMR, 13C NMR and 2D NMR. In continuation of this research, we have reported new and efficient methods for the synthesis of hitherto unknown indole-annulated pentacyclic indolylhydroisoquino lines and naphthooxazocines via tandem dinucleophilic addition of... 

Pile foundations suffered severe damages during the past earthquakes in all around the world. These damages were more severe in laterally spreading grounds and they mostly have been observed in gently sloping grounds and coastal areas. In these cases, Pile foundations not only are subjected to structures inertial loads and kinematic loads of liquefied soil but also lateral spreading intensifies damages. Thus, in the recent decade, several researches have been conducted to investigate the behavior of pile foundations in liquefiable and laterally spreading grounds, however, some uncertainties still remain in modeling of soil-pile interaction. In this study, the effects of liquefaction- induced... 

A critical property in designing drilling fluids is the concerns for environmental damages and cost efficiency of mud additives used to complete a well safely and economically. Designing drilling fluids for harsh environments such as high temperature, high salinity formation water, lime and cement contamination demands proper selection of deflocculant (thinner) materials to achieve a successful drilling operation. This study presents a novel thinner material that satisfies the goal of an environmentally and economically acceptable mud in drilling lime contamination areas where drilling carbonate formations with high concentration of calcium ions tends to flocculate clay particles in... 

The Barrier of the internal rotation around C-N bond in O-ethyle morpholine-4-carbotioate were calculated using dynamic NMR spectroscopy (DNMR) in DMSO solvent. 1H and 13C NMR spectra were recorded at different temperatures (295-350K). Band shape broadening patterns at coalescence regions were simulated to extract rate constants of NMR spectera. Transition state thermodynamic properties of internal rotation around C-N bond in O- ethyle morpholine -4- carbotioate are estimated: , , , . To assay reliability of the estimated values, transition state thermodynamic properties were calculated using PCM model at method and basis set B3LYP/6-311++G(d,p). Theoretical values of thermodynamic... 

Aqueous phase trapping (APT) in many of the oil and gas reservoirs is a significant mechanism of formation damage during drilling, completion, work over, and stimulation operation. APT can limit the productivity of the well to a high extent, especially in low permeable gas reservoirs. Experimental investigation of factors affecting APT is vital to recognize extends of associated damage and contribution of each factor. Albeit many experimental studies have been conducted as regards factors affecting removal of phase traps in understudy mechanism of formation damage, but up to date no experimental data has been published regarding effect of different factors on reservoir’s potential for APT....