Sharif Digital Repository

Heterogeneity is the major cause of the uneven acid distribution in carbonate acidizing. Traditional acidizing involves the injection of mineral acids, such as hydrochloric acid into the formation, which the bulk of the acidic solution permeates into the high-permeable layers and the low-permeability layers remain unreacted. So far, many chemical and mechanical techniques have been used to avoid the uneven distribution of acid. Using surfactant-based viscoelastic acids is one of the effective chemical method to divert acid to low-permeable zones. The unique feature of these acids is increasing viscosity of acidic solution as the pH increases. In this study, a two-scale continuum model... 

In literature, substantial works have been done on supply chain coordination. The majority of these works looking for a mechanism that enforces the supply chain members to follow strategies that produce the equilibria of an integrated supply chain, and most of this literature ignores competition between supply chains. In this thesis, we consider two distinct supply chains which compete to each other on the price. We present a method to calculate the equilibria for three structural forms. In the first form, two supply chains are integrated and in the second form, one of the supply chains is integrated and the other one is decentralized. Finally in the third form, both supply chains are... 

Necessity of a public transport network, environmental protection and a highly land cost in urban areas have increased the desire for underground transportation systems. On the other hand, ventilation system design should be done precisely specially for longer tunnels, large undergrounds spaces and crowded places. Rate of energy reduction for vent systems operation is dependent on their proper implementation. Tunnel design efficiently is influenced by ventilation system. The tunnel mid shaft is complementary part of the underground railway systems that is required for exchange air between the tunnel and the railway station with ambient fresh air. An important application of the tunnel mid... 

Over the past few decades, brachytherapy has been used as one of the leading methods in the treatment of a wide range of cancers, including breast cancer. Due to the high dose gradient of brachytherapy radiation sources, this method is used to treat such tumors that are grown at the vicinity of sensitive points or tissues of the body. Therefore, as irradiation get started by implanting radiation sources in the desired position, at the same time healthy tissue are also receiving the same dose as tumor tissues do Reducing healthy tissue dose along with increasing the dose of tumor tissue is one of the challenging topics that researchers are always looking for a solution. In the left breast... 

In present work, we fabricated novel heterojunction magnetic composite and the goo visible-light-harvesting photocatalysts through integration of ZnFe2O4 and MIL-53 by facile solvothermal method. To understand physical and chemical structure prepared material and morphology of samples, The XRD,FTIR, FESEM, DRS and VSM analysis were carried out. The ZFO/M53Fe/vis-light system reveled 92.3% dye degradation which enhanced photo catalyst reactivity for the decolorization of Direct red 23 as anionic dye under irraditation of LED lamp through AOP environment friendly technology, which are significantly higher than those of pure ZFO and M53Fe semiconductors. more ever ,aforementioned composite... 

Adobe structures are considered as masonry structures which are out of scope of 2800 Iranian code. Due to this code, since these structures are made of weak materials, they do not have a considerable resistance to earthquakes. Since these structures can be found all around Iran; therefore, seismic study of walls as an important component of these structures, is, indeed, necessary. During this study, cyclic tests on three types of adobe walls, without opening, with window-opening, and with door-and-window-opening with a scale of 2:3 were done to study their in-plane behavior and also their failure modes. Based on our observations, in these walls, because of small ratio of height to length,... 

Dental implants should be biocompatible. This ability cause bone growth beside implant and increases stability of implant. Manufactoring method and materials used in implants are main parameters affectig biocompatibility of implants. Fabrication of functionally graded structures is a novel method to increase biocompatibility. Stress shielding is one of the main causes of failures in current dental implants. This phenomenon takes place due to different young modulus of dental implants and host bone. Pouros structures remedial this problem and implant’s young modulus comes closer to host bone. The aim of this project is to study feasibily of fabrication of functionally graded titanium dental... 

Natural Boron consists of two stable isotopes, 10B (19.3%) and 11B (80.7%). 10B isotope has a large thermal neutron absorption and therefore, use widely in such aspects as modern industry, atomic energy industry (as control rods, chemical shim and etc.), Medical science and applications in disclosing neutrons to measure neutron reactors fluxes. Boron trifluoride is most importantly used as a reagent in organic synthesis, typically as a Lewis acid. In this study, we designed and built the related setup for preparation of high purity BF3 gas. And then we tried to optimize the efficiency with process design tools such as response surface methodology (RSM). At the end of this study, we were able... 

Hydrogen gas is considered as a clean fuel and energy carrier that its storage for future uses is a challenging issue. One of the methods to store it, is adsorption on a group of adsorbents called metal-organic frameworks. In this research, one of these frameworks called ZIF-8, has been selected to study hydrogen storage capability. To evaluate the effect of having two metals, a mixture of two metals was used in the synthesis process. To characterize the structure of the synthesized adsorbents, X-ray powder diffraction (XRD),adsorption and desorption of nitrogen at temperature of 77 K, Field Emission Scanning Electron Microscopy (FESEM), energy-dispersive X-ray Spectroscopy (EDS) and... 

This project investigates on synthesis of β-amino carbonyl compounds with new approach to become closer to green chemistry principals.In this project, we investigated the synthesis of β-amino carbonyl compounds with aromatic amines and electron deficient alkenes in the Michael reaction using boric acid and glycerol in water as a green media. High yields of the products and easy handling are some advantages of this procedure. Also, we investigated the Michael reaction in different solvents and temperatures but gave better results in the aqueous media. Moreover, thiomorpholine derivatives were synthesized using this method to give excellent yield.
 

It is the main idea of present thesis to provide a micromechanical method as a general treatment for several fundamental problems of the piezoelectric inhomogeneities. For initial demonstration of pertinent methodology, a single piezoelectric inhomogeneity of ellipsoidal geometry, under non-uniform far-field loading is considered. Accordingly, it is taken equivalent to elastic and dielectric inclusion problems connected by proper eigenstrain-electric field. This approach is named the electro-mechanical equivalent inclusion method (EMEIM) and requires that the electroelastic fields of the inhomogeneity to be equal to fields of the equivalent inclusions. Afterwards, the complex problem of... 

Dithiocarbamates are a group of compounds that nowadays have been used extensively in pharmaceutical agents, organicsynthesis and as fungicides in agriculture.We haveshown, an efficient. regiospecific method for the synthesis of cyclic dithiocarbamates by one-pot three-component cascade reaction of an amine, CS2 and α,β-unsaturated aldehyde via Michael addition/hemiamination reaction in watre under a mild and green procedure with excellent yields and complete regioselectivity  

Emission of CO2 and its diffusion into atmosphere is associated with negative effects on the environmental such as Green House Gases effect. Various techniques of CO2 Capture in energy conversion and processing plant are investigated. A method of CO2 Capture could be based on utilization of solar energy for producing methanol. Basic design of such a system and feasibility analysis of developing that system has been considered on the subject of the present research work. Basic design and commercial feasibility of the system producing methanol through capturing CO2 from exhaust gases of a power plant and hydrogen produced by using solar energy have done such an integrated system. The main... 

Nowadays using traditional hollow clay brick in buildings to make walls and partitionsisvery common. Non-load-bearing walls in buildings are used as architectural elements for design purposes and protecting the people that are inside the building from cold , heat and sound pollution .Due to the new technologies and developing building codes interms of structure , non-load-bearing walls behaviour that is always neglected seems necessary to be considered. In this research we have investigated the static and dynamic behaviour of a patented non-load-bearing wall made up of a claybrick system with specially-designed-precision grooved faces that eliminates conventional cement mortar and results...