Sharif Digital Repository

In this study, using the B3LYP/6-3111++g(d,p) computational level, we have explored the possibility of formation of some organic and bioorganic cation-cation clusters (CCC) in the absence of any anionic stabilizing species. Furthermore, we have shown the existence of a barrier energy for exothermic dissociation of these clusters. Herein, we have selected some biomolecules such as the chloroquine (CQ) antimalarial drug . The selected molecules possess the basic sites and can function as both hydrogen bond donors and acceptors. Also, a facile and direct synthetic route toward the rhodanine derivatives and thiazolidine-2,4-diones via a three-component coupling of carbon disulfide, primary... 

Designers consider formation of slug flow in pressurized pipes because of hazardous effects of this flow pattern. Therefore, researchers, using different methods, attempt to study formation of slug flow and its effects. For numerical simulation of this phenomenon, In spite of existence of commercial 2D or 3D two-phase models, numerical models used for the slug flow modeling are 1D. In this thesis, a 2D model has been developed to simulate the initiation and formation of slug flow and estimation of the effects in pressurized pipes. Most important assumptions used in this model are existence of turbulence, surface tension and air compressibility. Isothermal condition has been supposed for... 

One strategy for increasing efficiency and decreasing brake specific fuel consumption in spark ignition engines is using variable valve timing mechanism which is proportional to engine speed and load. Variable timing refers to the opening and closing time of inlet and outlet valves and their duration and overlap. In conventional SI engines the performance of valves is designed on a fixed point at special engine load and speed. While investigations show that if performance time of valves is changed according to engine load and speed, performance parameters of engine will improve.
In reviewing articles related to variable valve timing, their effect was considered on volumetric efficiency.... 

First studies in internal combustion engines have focused on increasing engine power and efficiency, reducing engine volume and improving fuel quality. However, nowadays most studies are concentrated on decreasing exhaust emissions and usage of regenerative fuels while maintaining engine size, efficiency and power. Surveying fuel type in direct injection engines, requires investigation of microscopic and macroscopic spray characteristics including spray tip penetration, spray cone angle, spray area and sauter mean diameter, since these parameters determine air-fuel mixture quality. In this study, spray of ethanol as a regenerative fuel that reduces emissions such as NOx and CO is... 

Considerable increase in speed and decrease in size of electronic devices results in increase of heat flux, so there is a need to enhance efficiency of cooling electronic devices. In the present research two sets of OLPHPs with five turns for two different magnetic nano-fluids were fabricated and the effects of working fluid (water, and two types of magnetic nano-fluids), working pressure, concentration, magnetic field, magnets location, and inclination angle on the thermal performance of OLPHPs have been considered in both startup and steady thermal conditions.
Experimental results show that magnetic nano-fluids can improve thermal performance of the OLPHPs. Application of magnetic... 

Improving efficiency of heat exchangers has always been an important concern for the industry. Pulsating heat pipes are novel and efficient technology in the field of heat transfer. Pulsating heat pipes are widely used in solar water heaters, solar desalination systems, air conditioning systems, cooling of electronical boards, etc. these applications explain the necessity of performing this study in our country. In this research, thermal performance of open loop pulsating heat pipes using two operating fluids (ferrofluid with surfactant and aluminum microfluid) is experimentally investigated. Start-up and steady thermal performance of pulsating heat pipes charged with these two operating... 

Micro combined heat and power (MCHP) system is one of the most worldwide considered energy saving with high total efficiency systems. This research presents the application of MCHP to small scale users such as residential or light commercial buildings. Initially, the available technology in micro scale that can be used as an energy generator has been specified and categorized. Since then, by using the overall energy purchased cost by households assuming the energy carriers are kerosene, gas and electricity, total demand has been determined considering that the electricity expenses showing the use of electric appliances and the gas expenses expressing the cost of domestic hot water and... 

Cardiovascular diseases are most common causes of deaths in the whole world. Nowadays, engineers and scientists in various fields become intent on finding solutions for prevention and recovery of these diseases. In this way, it is very important to know about the blood flow in arterial systems and its changes in various diseases. Numerical simulation of the blood flow beside of experimental studies could be very useful in this way. One dimensional simulation among various methods of numerical simulation was chosen to simulate a cardiovascular system since it has smaller computational cost and ability to modeling of whole arterial systems. It also is useful in extraction of medical indexes.... 

The aim of this research has been to modeling and optimization of steam injected gas turbine with inlet air cooling using absorption chiller. The whole system consists of compressor, combustion chamber, turbine, heat recovery steam generator, absorption chiller and cooling coil. The tasks carried out in this research include four points of view. The thermodynamic, exergetic, thermo-economic and environmental points of view are considered along modeling and optimization process. Design variables including temperature of combustion chamber exhausted gas, pinch point temperature of heat recovery steam generator and steam injection flow rate. Finally this modeling and optimization process is... 

Modern microelectronic systems generate a large amount of heat which must be transferred out of the system without excessive temperature rise. Conventional forced air convection and microchannel cooling plates have reached their performance limits Nanofiuids are proposed as an innovative way to solve the problem. A nanofiuid is nanoscale solid particles dispersed in a traditional heat transfer liquid. Some studies show an anomalous increase in the thermal conductivity for stationary nanofiuids. However, there are only few previous studies on the convection heat transfer rate and viscosity of nanofiuids. Both convection and stationary measurements of the thermal conductivity are widely... 

Recent stringent HC and CO emission regulations are because of increasing consciousness of the perilous influences of exhaust emissions. The chief attempt to pass the standards is to decrease the emissions during cold-start, due to catalytic converters are not efficient until they arrive a light-off temperature. It has been discovered that 50% to 80% of the controlled HC and CO emissions are sent out from tailpipe of automotive during the cold-start. Therefore, in order to minimize the cold-start emissions and fast light-off of catalytic converters, it is important to understand the catalytic converter characteristics and techniques for rapid warm-up catalyst. This thesis describes a... 

Many of industrial processes include suspension in their middle section of production, final product or residue. Majority of these two-phase mixtures are unstable due to their large particle size (larger than one micrometer). Therefore, Study of particle distribution in suspensions for generation of stabilized suspension becomes significant. In this study a new mechanism in stabilization of microparticle suspension known as nanoparticle halo mechanism has been assessed. Experiments have been conducted in dilute suspension and two-way coupling range. The effect of the presence of silica nanoparticle on zirconia microparticle suspension has been investigated. The effect of zeta potential of... 

Investigation of flow field and vortex structures in swirl flows and their velocity components, have received widespread interest among the researchers in the field of fluid mechanics. Due to the importance of vortex structures and their applications in combustion chambers, a special type of combustion chamber which is called “bidirectional swirl combustor” has been investigated in this work. Accurate identification of vortex phenomenon and flow structure in vortex engine leads to better design and control of the engine in the field of stability, geometry, cooling and combustion efficiency. Eperimnetal methods in this area are difficult but very valuable and efficient. Numerical methods are... 

Nowadays, cooling towers are widely used in power plants, refineries, petrochemicals and ventilation industries, but the water consumption of these towers is high and because of water crisis in Middle East and Iran, it is necessary to devise in order to reduce the water consumption of these towers. In this study separated hybrid cooling tower are used to investigate the water consumption at power plants. The rigorous Poppe method are used in order to estimate the exact amount of water loss due to evaporation in wet cooling towers. First, the effect of ambient condition, wet cooling tower cells and dry cooling tower size on the performance of hybrid cooling tower are investigated, then the... 

Due to increasing of internal combustion engine applications in metropolitan, reduction of emission is one of the challenging issues for engine companies. Natural gas is a promising fuel for the strict legislation of emission in many countries. Vast variety of natural gas sources in Iran and also lower carbon to hydrogen content of natural gas motivates us to use this fuel for engine application. Using natural gas also helps to increase the variety of fuel basket in Iran. Present research has focused on mixture formation and injection characteristics of natural gas direct injection engine. Injection and mixture formation in direct injection engines is very important for good combustion and... 

Helium gas is the working fluid in common Pulse Tube Refrigerators (PTRs) due to its brilliant properties in reaching cryogenics temperature as low as 4 K. Generally ideal gas equation of state has been used to evaluate thermodynamic performance of He. However using ideal gas equation of state for He in 10 bar and 5 K causes considerable error on estimation of density. The objective is to use real gas equation of state for temperatures near zero Kelvin. This approach makes an accurate prediction of PT cooling capacity and COP. In this thesis the objective is to realize the most relevant equations of state describing the proper behavior of He in the regions of operating point of PTR. Later on... 

In order to promote the efficiency of fossil fuel power stations, rotary air preheaters are used to warm the air entering the boiler. So, knowing the essential parameters of such exchangers and their effect on the efficiency is the primary objective and choosing the appropriate parameters and the dimensions reducing the liquid pressure, weight of exchangers and subsequently the maintenance expenses would be the secondary objective.
In this research we tried to know the principles of regenerative convertors introducing the tentative air preheaters and their functional characteristics .We also assessed the factors in designing the ideal tentative air preheaters including the type of... 

In this study, a catalyst-free Mannich reaction is applied for synthesis of 1,3-oxazines as an important class of biologically active compounds. In order to consider environmental application a mixture of water and ethanol is selected as a solvent for the reaction of 2,7-dihydroxynaphthalene with formaldehyde and an amine. Primary consideration of substitution effect on the reaction revealed that aniline and its derivatives with electron-donating substituent and halogens, cause higher yield. Aliphatic amines are not good substrate for this reaction with the exception of benzyl amine  

In the recent decades, cleanrooms have found growing applications in broad range of industries such as pharmacy and microelectronics. Concerns about negative effects of the contaminant exposure on the human health and product quality motivate many researchers towards understanding of the airflow and contaminant distribution through these environments. With an improvement in computational capacity of the computers, computational fluid dynamics (CFD) technique has become a powerful tool to study the engineering problems including indoor air quality (IAQ). In this research, indoor airflow in a full-scale cleanroom is investigated numerically using Eulerian–Eulerian approachand the results are...