Sharif Digital Repository

A carbon paste electrode, modified with 2, 2″-[1,7- hepthandiylbis(nitriloethylidyne)]-bis-hydroquinone and TiO 2 nanoparticles, was used for the simultaneous determination of dopamine (DA), uric acid (UA), and l-cysteine. The study was carried out by using cyclic voltammetry, chronoamperometry, and square wave voltammetry (SWV) techniques. Some kinetic parameters such as the electron transfer coefficient (α) and heterogeneous rate constant (k s) were also determined for the DA oxidation. A dynamic range of 8.0-1400 μM, with the detection limit of 8.4∈×∈10 -7 M for DA, was obtained using SWV (pH∈=∈7.0). The prepared electrode was successfully applied for the determination of DA, UA, and... 

In dye-sensitized solar cells recombination reactions at the TiO2 photoanode with the electrolyte interface plays a critical role in cell efficiency. Recombination of injected electrons in the TiO2 with acceptors in the electrolyte usually occurs on uncovered areas of TiO2 surfaces. In this work, we report electropolymerization of polymer films on nanoporous TiO2 electrode surfaces using an ionic liquid as the growth medium. The choice of ionic liquid as the growth medium for this study is based on the insolubility of dye N719 in this electrolyte, thus avoiding dye molecule detachment from the TiO2 photoanode surface over the entire potential range investigated during the... 

In the present paper, the use of a carbon paste electrode modified by 2,2′-[1,2 buthanediylbis (nitriloethylidyne)]-bis-hydroquinone (BH) and TiO2 nanoparticles prepared by a simple and rapid method was described. The modified electrode showed an excellent character for electrocatalytic oxidization of norepinephrine (NE), acetaminophene (AC) and folic acid (FA). Using differential pulse voltammetry (DPV), a highly selective and simultaneous determination of NE, AC and FA has been explored at the modified electrode. Differential pulse voltammetry (DPV) peak currents of NE, AC and FA increased linearly with their concentration at the ranges of 4.0-1100.0 μM, 12.5-500.0 μM and 200.0-3200.0 μM,... 

A carbon paste electrode (CPE), modified with novel hydroquinone/TiO2 nanoparticles, was designed and used for simultaneous determination of ascorbic acid (AA), uric acid (UA) and folic acid (FA). The magnitude of the peak current for modified TiO2-nanoparticle CPE (MTNCPE) increased sharply in the presence of ascorbic acid and was proportional to its concentration. A dynamic range of 1.0-1400.0 μM, with the detection limit of 6.4x10-7M for AA, was obtained using the DPV technique (pH=7.0). The prepared electrode was successfully applied for the determination of AA, UA, and FA in real samples  

A carbon paste electrode (CPE) chemically modified with TiO2 nanoparticles and quinizarine (QZ) was used as a selective electrochemical sensor for the simultaneous determination of minor amounts of d-penicillamine (D-PA) and tryptophan (Trp). This modified electrode showed very efficient electrocatalytic activity for anodic oxidation of both d-PA and Trp. Substantial decreases of anodic overpotentials for both compounds made this analysis possible. Results of square wave voltammetry (SWV) using this modified electrode showed two well-resolved anodic waves for the oxidation of d-PA and Trp, which makes the simultaneous determination of both compounds possible. The peak potential for the... 

A modified carbon paste electrode was prepared by incorporating TiO2 nanoparticles with bis[bis(salicylidene-1,4-phenylenediamine)molybdenum(VI)]. A mixture of fine graphite powder with 4 wt% of TiO2 nanoparticles was applied for the preparation of the carbon paste (by dispersing in paraffin) and finally modified with a molybdenum (VI) complex. The electrocatalytic oxidation of guanine (G) was investigated on the surface of the molybdenum (VI) complex-TiO2 nanoparticle modified carbon paste electrode (MCTNMCPE) using cyclic voltammetry (CV), differential pulse voltammetry (DPV), chronoamperometry (CHA) and chronocoloumetry (CHC). Using the modified electrode, the kinetics of G... 

A carbon paste electrode (CPE) modified with 2,2′-[1,2 butanediylbis(nitriloethylidyne)]-bis-hydroquinone (BBNBH) and TiO2 nanoparticles was used for the sensitive voltammetric determination of epinephrine (EP). The electrochemical response characteristics of the modified electrode toward EP and acetaminophen (AC) were investigated by cyclic and differential pulse voltammetry (CV and DPV). The results showed an efficient catalytic activity of the electrode for the electrooxidation of EP, which leads to a reduction in its overpotential by more than 270 mV. The effects of pH and potential sweep rate on the mechanism of the electrode process were investigated. The modified electrode exhibits an... 

In the present paper, the use of a novel carbon paste electrode modified by N,N'(2,3-dihydroxybenzylidene)-1,4-phenylenediamine (DHBPD) and TiO2 nanoparticles prepared by a simple and rapid method for the determination of dopamine (DA) was described. In the first part of the work, cyclic voltammetry was used to investigate the redox properties of this modified electrode at various solution pH values and at various scan rates. A linear segment was found with slope value of about 48 mV/pH in the pH range 2.0 -12.0. The apparent charge transfer rate constant (ks) and transfer coefficient (α) for electron transfer between DHBPD and TiO2 nanoparticles-carbon paste electrode were calculated. In... 

A new, simple, fast and reliable solid-phase extraction method has been developed for separation/preconcentration of trace amounts of Pb(II) using dithizone/sodium dodecyl sulfate-immobilized on alumina-coated magnetite nanoparticles, and its determination by flame atomic absorption spectrometry (FAAS) and graphite furnace atomic absorption spectrometry (GFAAS) after eluting with 4.0 mol L -1 HNO 3. Optimal experimental conditions including pH, sample volume, eluent concentration and volume, and co-existing ions have been studied and established. Under the optimal experimental conditions, the preconcentration factor, detection limit, linear range and relative standard deviation of Pb(II)... 

This paper proposes a straightforward control method for voltage control of a three-phase transformer-based inverter in uninterruptible power supplies or distributed generation systems. The approach offers a dual-loop design consisting inner current control loop and outer voltage loop. Sliding mode current controller provides desired bandwidth for voltage controller which consists of a state feedback term for stabilization and resonant term for harmonic damping. The proposed scheme provides fast dynamic response and low total harmonic distortion even for high power inverters with the limitations of switching frequency and LC filter components. Experimental studies for 2KVA linear and... 

Long term evolution (LTE)-advanced aims the peak data rates in excess of 3 Gbps for the next generation wireless communication systems. Turbo codes, the specified channel coding scheme in LTE, suffers from a low-decoding throughput due to its iterative decoding algorithm. One efficient approach to achieve a promising throughput is to use multiple Maximum a Posteriori (MAP) cores in parallel, resulting in a large area overhead, a big drawback. The scaled Max-log MAP algorithm is a common approach to implement the MAP algorithm due to its efficient architecture with its acceptable performance. Although many works have been reported to reduce the area of the MAP unit, an efficient VLSI... 

Long-term evolution (LTE) is aimed to achieve the peak data rates in excess of 300 Mb/s for the next-generation wireless communication systems. Turbo codes, the specified channel-coding scheme in LTE, suffer from a low-decoding throughput due to its iterative decoding algorithm. One efficient approach to achieve a promising throughput is to use multiple maximum a posteriori (MAP) cores in parallel, resulting in a large area overhead. The two computationally challenging units in an MAP core are α and β recursion units. Although several methods have been proposed to shorten the critical path of these recursion units, their area-efficient architecture with minimum silicon area is still missing.... 

5-th generation mobile networks aim the peak data rates in excess of few Gbs, which may appear to be challenging to achieve due to the existence of some blocks such as the turbo decoder. In fact, the interleaver is known to be a major challenging part of the turbo decoder due to its need to the parallel interleaved memory access. LTE uses Quadratic Permutation Polynomial (QPP) interleaver, which makes it suitable for the parallel decoding. In this paper, a new property of the QPP interleaver, called the correlated shifting property, is theoretically proved, leading to a fully scalable interleaver and a low-complexity address generator for an arbitrary order of parallelism. The proposed... 

Long Term Evolution (LTE) supports peak data rates in excess of 300 Mb/s. A good approach to achieve such rates is by parallelizing the required processing in turbo decoders. An interleaver is an important part of a turbo decoder. LTE uses the Quadratic Permutation Polynomial (QPP) interleaver, which makes it suitable for parallel decoding. In this paper, we propose an efficient architecture for the QPP interleaver, called the Add-Compare-Select (ACS) permuting network. A unique feature of the proposed architecture is that it can be used both as the interleaver and deinterleaver leading to a high-speed low-complexity hardware interleaver/deinterleaver for turbo decoding. The proposed design... 

The combination of traditional retail channel with direct channel adds a new dimension of competition to manufacturers' distribution system. In this paper, we consider a make-to-order manufacturer with two channels of sale, sale through retailers and online direct sale. The customers are classified into different classes, based on their sensitivity to price and due date. The orders of traditional retail channel customers are fulfilled in the same period of ordering. However, price and due date are quoted to the online customers based on the available capacity as well as the other orders in the pipeline. We develop two different structures of the supply chain: centralized and decentralized... 

The use of cell phone is a significant source of driver distraction. Phone use while driving can impair a number of factors critical for safe driving which can cause serious traffic safety problems. The objective of this paper was to investigate the frequency of using cell phones while driving in Iran's roads through an observational survey with a random sample of drivers, to recognize contributing factors to cell phone usage and to understand the magnitude of the problem. A total of 1794 observations were collected from 12 sites at controlled intersections, entrance and exit points of highways. The cell phone use rate among drivers (talking or texting) was estimated at 10% which is... 

Purpose: This work aims to study factors, such as driver characteristics, environmental conditions, and vehicle characteristics, that affect different crash types with a special focus on distraction parameters. For this purpose, distraction factors are divided into five groups: cellphone usage, cognitive distractions, passengers distracting the driver, outside events attracting the driver’s attention, and in-vehicle activities. Methods: Taking the crashes that occurred in the USA into account, the crash types are divided into two main groups, single-vehicle crashes and two-vehicle crashes. Since there were different crash types (alternatives) in the dataset and the probable correlation in... 

The use of cell phone is a significant source of driver distraction. Phone use while driving can impair a number of factors critical for safe driving which can cause serious traffic safety problems. The objective of this paper was to investigate the frequency of using cell phones while driving in Iran's roads through an observational survey with a random sample of drivers, to recognize contributing factors to cell phone usage and to understand the magnitude of the problem. A total of 1794 observations were collected from 12 sites at controlled intersections, entrance and exit points of highways. The cell phone use rate among drivers (talking or texting) was estimated at 10% which is... 

Performing maneuvers such as braking and lane changing can hinder the occurrence of a crash. The driver tends to escape from the crash occurrence or reduce its severity by doing the maneuver, so finding the factors affecting this type of maneuver can help the driver to react better. This work aims to discover the effect of distraction-related factors on the performance of a crash avoidance maneuver. In order to pave the way for a more thorough comprehension of this matter, variables related to the characteristics of the driver, road, crash, vehicle, and environmental properties are also considered in the analysis. The used data is based on General Estimate System 2010 dataset, a dataset... 

This study provides a comprehensive literature review to summarize all contributing factors and the logit-based models that were used to predict the severity of crashes. Using the General Estimates Systems (GES) dataset, as a subset and a branch of the National Automotive Sampling System in the US, a Generalized Ordered Logit (GLM) model is developed to predict the crash severity. The developed severity model detects the most important parameters based on characteristics of the driver, the environment, the vehicle, the road, and the type of crash. This study aims to take a more in-depth look into the distraction-related factors as one of the most important groups of contributing factors to...