Sharif Digital Repository

Knock is an abnormal phenomena in combustion engines and one the main limiter elements in increasing engine efficiency. From years ago, recognition and elimination of this phenomenon had studied by investigators and various approaches to anticipation had presented. One of the newest methods is using of property variety in air and fuel mixture with using technologies like Variable Valve Timing (VVT) system.
The purpose of this work is development a simple model in basis physics of 3 zone, homogeneous, ignition combustion with a partial kinetics model that this model can predict the knock phenomenon onset with good precision for various qualities of mixture. This study survey effect of... 

The Moderate or Intense Low-oxygen Dilution (MILD) combustion of liquid fuels has attracted attention to use its advantages in industrial burners and gas turbines applications. Here numerical investigation has been conducted on a research experimental MILD turbulent spray burner (Deft Spray in Hot Co-flow, DSHC). RANS approach has been adopted for modeling of the reactive turbulent flow field of continues phase with the Lagrangian approach for droplet modeling of pressure-swirl atomizer fuel spray. The EDC combustion model is used which has the ability to take into account the detailed chemical mechanisms. The accuracy of different turbulence and droplet injection sub-models are examined and... 

Homogeneous Charge Compression Ignition (HCCI) engines are the new generation of internal combustion engines which have diesel-like thermal efficiency, while they have low nitrogen oxide and soot emission. One of the major problems of HCCI engines is combustion timing control due to its dependence on reactivity of the charge and chemical kinetics. Moreover, limiting operation range between knock and misfiring is the other drawback of using these kind of engines. In the present work, partially homogeneous HCCI combustion in a single cylinder diesel engine is modeled using Computational Fluid Dynamics (CFD) coupled with chemical kinetics. Simulation includes the engine cycle from exhaust valve... 

Experimental studies of regular cell structure of a weak detonation wave in a gaseous mixture of hydrogen and oxygen diluted with argon have shown that for a constant initial thermodynamic condition, the final cell size differs by repeating the tests. The question is that if these different final cell sizes for a constant initial condition are because of test errors, or the experiments would lead to a domain of solution in the form of different final cell sizes? Therefore, the aim of this study is to investigate, numerically, the evolution process and domain of variation of cellular structure of a weak detonation, and their dependency to unstable wavelengths obtained from linear instability... 

Real fuels contain hundreds of hydrocarbons such as linear and chain paraffins, naphthenes, olefins and aromatics.Behavior of this real fuels are represented by mixtures with simple compounds. Since engine with homogeneous charge compression ignition (HCCI) is a promising combustion concept able to provide very low NOx and PM diesel engine emissions while keeping good fuel economy, for use in vehicles requires kinetic reaction mechanism to simulate the hydrocarbons oxidation and it’s rules.combustion control is facing with basic problem in this engine.unlike conventional methods, . HCCI combustion is a kinetically controlled process and start of combustion will be controlled and dominanted... 

Emission control, especially Carbon Monoxides (CO) as one of the major by-products of combustion processes, is one of the most serious challenges in burning waste-gases with high amounts of humidity and Carbon Monoxide. We investigated an oil waste-gas incinerator serving to a bitumen production line located in Pasargad Oil Company, Shazand, Arak, Iran. The aforementioned incinerator was criticized seriously for its high CO emissions. We were requested to find a solution to reduce the undesirable CO emission from that. Following the environmental standards, there is an upper limit of 150 ppm for the CO produced by an industrial waste oil incinerator. To present an inclusive solution for such... 

The aim of this study is to find a formulation to investigate the catalytic effect of the electric field on the kinetic pathway of a chemical reaction. The catalytic effects of the electric field can be explained by the effect of the external electric field on the stability of the transition state relative to the reactants.The effect of the external electric field on the reaction rate for redox reactions have been proven, but this effect seemed unlikely for non redox reactions. Recently, the role of the electric field in the rate of such chemical reactions, as well as its catalytic activity,has been demonstrated experimentally and computationally. In previous studies, reactive components... 

In this project, metal oxides loaded on different supports were used in the heterogeneous electro-Fenton (EF) process for organic pollutants removal. At first, Fe3O4/AC was synthesized for catechol degradation as a phenolic compound. 98.2% removal of catechol was achieved by operational conditions optimization. The catalytic activity of Fe3O4/AC was remained constant after 6 cycles. In the other study, reduced graphene oxide was used as a support for the magnetite nanoparticle catalyst. The catalytic activity of Fe3O4/rGO in EF degradation of reactive red 195 (RR195) dye was studied and 93.34% removal was obtained. Response surface methodology (RSM) was used and a quadratic model with... 

The purpose of this dissertation is to experimentally and numerically investigate the effect of molecular structure, composition, and physical and chemical properties of fuel on HCCI combustion. A well-equipped laboratory was set up to perform the required tests, capable of performing HCCI tests with different fuels. All tests used a single-cylinder diesel engine modified to operate in HCCI mode. Also, for numerical simulation, a chemical kinetic multi-zone model was developed to predict HCCI combustion behavior with appropriate accuracy. To investigate the effect of fuel chemical structure on HCCI combustion, three fuels, toluene, iso-octane and normal heptane, with entirely different... 

In this thesis, reactivity controlled compression ignition (RCCI) combustion fueled by diesel and natural gas is experimentally and numerically investigated. Natural gas as a fuel with low reactivity is injected into the intake manifold, and diesel as a fuel with high reactivity is injected directly into the combustion chamber. One of the main goals of this thesis is to experimentally examine the effect of important parameters on combustion phasing control, operational range extension, and pollutants. Natural gas is one of the important sources of energy in Iran and the world. Using natural gas in internal combustion engines can cause methane to slip into the atmosphere and intensify the... 

Control and reduction of gas turbines pollutants emissions are increasingly of major concern. Here we introduce and apply new algorithms for derivation of accurate and low cost skeletal chemical kinetics, optimization of global multi-step chemical kinetics, and optimization of geometry of Lean Premixed (LPM) dry low emission (DLE) combustors.A new reduction algorithm called SA-GEIE, based on sensitivity analysis of reaction mechanisms respect to ignition delay, flame temperature and pollutants concentration (NO and CO), is introduced. This algorithm is implemented to GRI-3.0 to produce a low cost methane oxidation skeletal mechanism with 118 reactions and 39 specie. The accuracy is assessed...