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    Some investigations on bioflocculant producing bacteria

    , Article Biochemical Engineering Journal ; Volume 5, Issue 1 , 2000 , Pages 39-44 ; 1369703X (ISSN) Salehizadeh, H ; Vossoughi, M ; Alemzadeh, I ; Sharif University of Technology
    2000
    Abstract
    Bacillus sp. As-101 which produces flocculating substances was isolated from activated sludge, using a proteolytic enzyme. Bioflocculant As-101 was partially purified by cold ethanol and cetylpyridinium chloride. The partially purified flocculating substance was an acidic polysaccharide including uronic, pyruvic and acetic acids, respectively, in an approximate ratio of 11.4%, 6.1%, 0.4%. The biopolymer is also a sugar-protein derivative consisting of glucose, mannose and galactose. The protein, the sugar contents ratio is about 83-17%. Bioflocculant As-101 acted under acidic condition and the maximum activity was observed at optimum pH ˜ 3.7 and optimum concentration of 30 ppm in kaolin... 

    Comparison of adsorption process by GAC with novel formulation of coagulation - Flocculation for color removal of textile wastewater

    , Article International Journal of Environmental Research ; Volume 2, Issue 3 , 2008 , Pages 239-248 ; 17356865 (ISSN) Hassani, A. H ; Seif, S ; Javid, A. H ; Borghei, M ; Sharif University of Technology
    2008
    Abstract
    This study evaluates the effectiveness of adsorption process by Granular Activated Carbon (GAC) compared with a novel formulation of coagulation - flocculation process for dye removal from textile wastewater. In this regard, acidic, reactive, disperse and direct red dye are used to prepare the synthetic dye. Dominant wave length for each dye is determined by spectrophotometeric method. Using GAC as adsorbent, equilibrium time and adsorption isotherm of each dye are determined with aid of spectrophotometric method. The results show that GAC can not remove dispersed red dye. Acidic red, direct red and reactive red of 5 mg/L concentration are removed by GAC up to %90, %88 and %43 in 30, 60 and... 

    Novel cationic-modified salep as an efficient flocculating agent for settling of cement slurries

    , Article Carbohydrate Polymers ; Volume 93, Issue 2 , April , 2013 , Pages 506-511 ; 01448617 (ISSN) Pourjavadi, A ; Fakoorpoor, S. M ; Hosseini, S. H ; Sharif University of Technology
    2013
    Abstract
    A new cationic flocculant was synthesized by graft copolymerization of acrylamide (AM) and 3-(methacryloylamino)propyl]trimethylammonium chloride (MAPTAC) onto salep using free radical polymerization initiated by ammonium persulfate (APS) to produce cationic salep [S-g-P(AM-co-MAPTAC)]. Reaction parameters (monomers/salep ratio, concentration of reactants, MAPTAC/AM ratio, and APS) were optimized using a full factorial experimental design to obtain the highest settling rate for cement suspensions. The best performing product was characterized by gel permeation chromatography (GPC), FTIR, 1H NMR spectroscopy, and thermogravimetric analysis (TGA). The resulted cationic flocculant may be... 

    Synthesis, characterization and comparison of PAM, cationic PDMC and P(AM-co-DMC) based on solution polymerization

    , Article Journal of Industrial and Engineering Chemistry ; Volume 17, Issue 3 , 2011 , Pages 580-586 ; 1226086X (ISSN) Abdollahi, Z ; Frounchi, M ; Dadbin, S ; Sharif University of Technology
    2011
    Abstract
    High molecular weight homopolymers of acrylamide (PAM) and (2-methacryloyloxyethyl) trimethyl ammonium chloride (PDMC) and copolymer of DMC with acrylamide (P(AM-co-DMC)) were synthesized using solution polymerization technique. The synthesized polymers were characterized by Fourier transform infrared (FTIR), 1HNMR, 13CNMR spectroscopy and differential scanning calorimetry (DSC) and viscometery. 1HNMR and 13CNMR studies confirmed the structure of the synthesized polymers. The behavior of the synthesized polymers was investigated in water-acetone and water-methanol mixtures. The plot of intrinsic viscosity of either PAM or P(AM-co-DMC) with respect to acetone (methanol)/water ratio in... 

    The combination of KMnO4 oxidation and polymeric flocculation for the mitigation of membrane fouling in a membrane bioreactor

    , Article Separation and Purification Technology ; Volume 159 , 2016 , Pages 124-134 ; 13835866 (ISSN) Zarei baygi, A ; Moslemi, M ; Mirzaei, S. H ; Sharif University of Technology
    Elsevier 
    Abstract
    KMnO4 oxidation combined with polyelectrolyte (K530CF) flocculation was investigated to mitigate membrane fouling in a membrane bioreactor. The optimum dosages of chemical additives in order to enhance the removal of soluble microbial products (SMPs) were determined. This method was able to reduce the concentration of COD in the effluent to 57.1% and 51.1% lower than those in the experiments in the absence of chemical flocculants and in the presence of polyelectrolyte, respectively. NH3-N removal was improved by combining KMnO4 and K530CF. When KMnO4 was used along with polyelectrolyte, the zeta potential was neutralized to a greater extent which resulted in an improvement in the... 

    Experimental Studies on Recovery Process of Microalgae using Electric Current and Membrane

    , M.Sc. Thesis Sharif University of Technology Sabermanesh, Mohammad Hossein (Author) ; Vosughi, Manoochehr (Supervisor) ; Moslemi, Mohammad Reza (Supervisor)
    Abstract
    Microalgae is a major problem in water resources due to its adverse influence on water treatment process and water quality like color, odor and taste. In addition microalgae removal is an important process in food and pharmacy industry. Electrocoagulation is a potential method for microalgae removal. Another method for microalgae recovery is membrane treatment. This study is focusing on using both methods separately and simultaneously. To achieve this, the removal of Chlorella Vulgaris, a fresh water microalgae, was used in experiments. In first phase the experiments were solely on electrocoagulation and the effect of several parameters including current density, electrocoagulation duration,... 

    Experimental Investigation of Henna powder as an Additive to Drilling Fluid

    , M.Sc. Thesis Sharif University of Technology Mahmoodi, Masoud (Author) ; Masihi, Mohsen (Supervisor) ; Shadizadeh, Reza (Supervisor)
    Abstract
    A critical property in designing drilling fluids is the concerns for environmental damages and cost efficiency of mud additives used to complete a well safely and economically. Designing drilling fluids for harsh environments such as high temperature, high salinity formation water, lime and cement contamination demands proper selection of deflocculant (thinner) materials to achieve a successful drilling operation. This study presents a novel thinner material that satisfies the goal of an environmentally and economically acceptable mud in drilling lime contamination areas where drilling carbonate formations with high concentration of calcium ions tends to flocculate clay particles in... 

    Effect of ultrasonic irradiation on rheological properties of asphaltenic crude oils

    , Article Petroleum Science ; Volume 9, Issue 1 , March , 2012 , Pages 82-88 ; 16725107 (ISSN) Mousavi, S. M ; Ramazani, A ; Najafi, I ; Davachi, S. M ; Sharif University of Technology
    2012
    Abstract
    In this work, the rheological changes of several crude oil samples exposed to ultrasonic waves for different time intervals in addition to the effect of temperature on viscosity behavior of heavy crude oils were investigated using a series of steady shear flow and oscillatory tests. The colloidal structural evolutions of flocs in oil samples were illustrated by analysis of the size distribution of flocculated asphaltene particles (confocal microscopy tests). The rheological investigations indicate that the ultrasonic irradiation dissolved heavy components in crude oil. After ultrasonic treatment, the Kouh-e-Mond crude oil was found to be pseudoplastic. In addition, confocal microscopy... 

    Application of ultrasonic wave technology as an asphaltene flocculation inhibition method

    , Article Saint Petersburg 2012 - Geosciences: Making the Most of the Earth's Resources ; 2012 Najafi, I ; Amani, M ; Mousavi, M. R ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Based on series of crude oil rheological properties and asphaltene flocculation confocal microscopy analysis, Najafi et al., (2011) reported the existence of an optimum radiation time at which asphaltenic crude oils reach the minimum kinematic viscosity. Accordingly, they proposed the idea of asphaltene flocculation inhibition due to wave radiation.The present investigation is a continuous effort to provide more information about the process of flocculation inhibition. Confocal microscopy and rheological analyses are performed on different crude oils to prove the repeatability of the observed phenomena. The asphaltene content analysis was done based on IP143 procedure, which provides more... 

    Quantitative analysis of ultrasonic wave radiation on reversibility and kinetics of asphaltene flocculation

    , Article 4th International Conference and Exhibition: New Discoveries through Integration of Geosciences, Saint Petersburg, 5 April 2010 through 8 April 2010 ; 2010 Mousavi, S. M. R ; Najafi, I ; Ghazanfari, M. H ; Kharrat, R ; Ghotbi, C ; Sharif University of Technology
    European Association of Geoscientists and Engineers, EAGE  2010
    Abstract
    Recently, it was found that ultrasonic wave technology can be used as a method for asphaltene deposits removal from the near wellbore region. However, ultrasounds can affect asphaltene resolution.In this work, asphaltene resolution in several crude oil samples exposed to ultrasonic waves for different time intervals is studied by confocal microscopy. The colloidal structure of flocks is described by analysis of asphaltene particle size distribution to investigate ultrasonic application in solving asphaltene deposition problems.. The results show that for the first 90 minutes of flocculation time, the size of aggregates increases rapidly, and reaction limited aggregation model matches well... 

    Application of ANFIS-GA algorithm for forecasting oil flocculated asphaltene weight percentage in different operation conditions

    , Article Petroleum Science and Technology ; Volume 36, Issue 12 , 2018 , Pages 862-868 ; 10916466 (ISSN) Keybondorian, E ; Soltani Soulgani, B ; Bemani, A ; Sharif University of Technology
    Taylor and Francis Inc  2018
    Abstract
    Asphaltene which cover range of 1% to over 10% of oil by weight, is well-known as most problematic part of oil that can deposit during production in reservoir, well tubing, and surface production lines, and consequently impose a serious restriction on production which in turn increases total cost of entire operation. Through decades an extensive research has been performed in order to identify asphaltene molecular structure, its behavior at different condition, and its separation mechanism from oil. One of most critical parameter associated with asphaltene precipitation modeling is flocculated asphaltene weight percentage in oil at given operation condition. In this study, to eliminate cost... 

    Mechanistic study to investigate the effects of different gas injection scenarios on the rate of asphaltene deposition: An experimental approach

    , Article Fuel ; Volume 262 , 2020 Dashti, H ; Zanganeh, P ; Kord, S ; Ayatollahi, S ; Amiri, A ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Asphaltene deposition during enhanced oil recovery (EOR) processes is one of the most problematic challenges in the petroleum industry, potentially resulting in flow blockage. Our understanding of the deposition mechanism with emphasis on the rate of the asphaltene deposition is still in its infancy and must be developed through a range of experiments and modelling studies. This study aims to investigate the rate of asphaltene deposition through a visual study under different gas injection scenarios. To visualise the asphaltene deposition, a high-pressure setup was designed and constructed, which enables us to record high-quality images of the deposition process over time. Present research... 

    Gold Nanowaste Reduction and Recycling Using Chemical Methods

    , M.Sc. Thesis Sharif University of Technology Sotudeh, Ali (Author) ; Hormozi-Nezhad, Mohammad Reza (Supervisor) ; Alamolhoda, Ali Asghar (Supervisor)
    Abstract
    The growing use of nanomaterials leads to causing harm to the aquatic environment resulting in a demand for effective methods to remove these nanomaterials from aquatic environment. On the other hand, the high cost of raw materials used for the production of noble metal nanomaterial limits their use or requires the development of recycling and recovery methods. In this study, we found that citrate capped gold nanoparticles (cit-AuNPs) could be removed effectively from waste water using aluminum chloride (AlCl3) coagulant. The effect of pH, of coagulant concentration, and alkalinity on the performance of this coagulant was investigated. It has... 

    Effect of the Chemical Coagulant and Oxidizer on the Membrane Fouling During the Treatment of Wastewater Using a Membrane Bioreactor

    , M.Sc. Thesis Sharif University of Technology Zarei Baygi, Ali (Author) ; Moslemi, Mohammad Reza (Supervisor)
    Abstract
    Membrane bioreactor (MBR) is a combination of conventional activated sludge (CAS) and membrane filtration which owing to its advantages such as high quality effluent and low excess sludge production, has gained increasing application in wastewater treatment. The major drawback of a MBR is the membrane fouling that reduces the permeate flux, which in turn increases the overall operational costs due to high energy requirements. In existing study, the combination of sludge oxidation and coagulation/flocculation addition was investigated for mitigation of membrane fouling in a membrane bioreactor. Oxidation can facilitate sludge flocculation and hence improve the properties of mixed liquor. The... 

    Quantifying the role of ultrasonic wave radiation on kinetics of asphaltene aggregation in a toluene-pentane mixture

    , Article Petroleum Science and Technology ; Volume 29, Issue 9 , 2011 , Pages 966-974 ; 10916466 (ISSN) Najafi, I ; Mousavi, S. M. R ; Ghazanfari, M.H ; Ghotbi, C ; Ramazani, A ; Kharrat, R ; Amani, M ; Sharif University of Technology
    Abstract
    Recently, ultrasonic wave technology has received much attention as a method for removal of asphaltene deposits from the near wellbore region. However, very little is known about another feature of this technology on the kinetics of asphaltene molecules aggregation. In this work, the kinetics of asphaltene flocculation in several crude oil samples exposed to ultrasonic waves for different time intervals is studied by confocal microscopy. The colloidal structural evolutions of flocks are described by analysis of size distribution of flocculated asphaltene particles. The results show that for the first 90 min of flocculation time, the size of aggregates increases rapidly, and a... 

    Comparison of ultrasonic wave radiation effects on asphaltene aggregation in toluene-pentane mixture between heavy and extra heavy crude oils

    , Article Journal of Energy Resources Technology, Transactions of the ASME ; Volume 134, Issue 2 , 2012 ; 01950738 (ISSN) Mousavi, S. M. R ; Najafi, I ; Ghazanfari, M. H ; Amani, M ; Sharif University of Technology
    2012
    Abstract
    In this study, it is aimed to compare the efficiency of ultrasonic wave technology on asphaltene flocculation inhibition of crude oils with different American Petroleum Institute (API) gravities. A set of confocal microscopy test is performed and a series of statistical analysis is done. According to the results of this study, there is an optimum radiation time for both crudes at which the viscosity and the flocculation rate of asphaltenic crude oils reduces to its minimum. This optimum appears at later times of radiation for extra heavy oil. Also, it is shown that the rate of changes in the properties measured in this study is sharper for extra heavy crude oil. It could be concluded that... 

    Synthesis and Characterization of High Molecular Weight Polyacrylamide and Cationic Polyacrylamide

    , M.Sc. Thesis Sharif University of Technology Abdollahi Banouei, Zohreh (Author) ; Frounchi, Masoud (Supervisor) ; Dadbin, Susan (Supervisor)
    Abstract
    In many industrial processes there is an urgent need for flocculation of suspensions that can’t flocculate easily through the time so flocculants are wildly used in these industries. Polymeric flocculants because of less needed dose are economically used. Polymeric flocculants divided to three categories: nonionic, anionic and cationic those are almost from polyacrylamide group. Studying mechanisms of flocculation, one of the main factors that enhance flocculation is molecular weight of polymer. Hence one of the goals of this work is to improve molecular weights of synthesized polymers as much as possible that is followed by viscometery, NMR, DSC and FTIR studies and ended with jar test.... 

    Investigating the Effects of Different Parameters on Asphaltene Deposition Using Electrodeposition Technique

    , M.Sc. Thesis Sharif University of Technology Hosseini, Ali (Author) ; Ayatollahi, Shahabeddin (Supervisor) ; Taghikhani, Vahid (Supervisor)
    Abstract
    Additional to Temperature, Pressure and Compositional changes of crude oils, Electro-kinetics and Electrical potential effects are also known as the most influencing parameters on Asphaltene deposition during oil production and processing.Mechanisms of electro-kinetics and asphaltene charge generation are very complex and unclear. In the previous studies on asphaltene precipitation and deposition, mostly electro-kinetics effects are ignored.While, recent studies show the great effects of electrical filed on asphaltene deposition during production and processing phase of crude oils.At reservoir porous medium and crude flow line, an electrical field can be developed along the length of the... 

    Upgrading "Qaed Basir"Petrochemical Wastewater Treatment Plant

    , M.Sc. Thesis Sharif University of Technology Maqsudi, Matin (Author) ; Borghei, Mehdi (Supervisor) ; Shayegan Salek, Jalaledin (Supervisor)
    Abstract
    Golpayegan Qaed Basir Petrochemical Company is one of the lucrative and entrepreneurial companies in Iran. Every day in this complex, a large amount of wastewater is being generated and transferred to the evaporative lag after the primary and secondary purification outside the complex and it is not restored. Considering the growing importance of surface and underground water resources, reuse of wastewater is a valuable production. In this research, the optimization of the sewage treatment system of the complex was evaluated by replacing the chemicals in the primary purification unit and also by using chloride-ferric and trickling filter for tertiary purification(treating) of the... 

    Modeling of asphaltene deposition during miscible CO2 Flooding

    , Article Petroleum Science and Technology ; Vol. 32, Issue. 18 , 2014 , Pages 2183-2194 ; ISSN: 10916466 Tahami, S. A ; Dabir, B ; Asghari, K ; Shahvaranfard, A ; Sharif University of Technology
    Abstract
    The authors present the results of numerical tests and simulations to investigate and analyze the likelihood of asphaltene precipitation and deposition during CO2 flooding in a reservoir. The effects of asphaltene precipitation on oil properties such as oil viscosity and density during miscible CO2 flooding process were elaborated by using Winprop software of Computer Modeling Group. Also oil properties change during CO 2 miscible flooding by numerical slim tube were investigated by a compositional simulator (GEM). A fluid sample of Saskatchewan Reservoir that had been flooded miscibly with CO2 was chosen for performing the sensitivity analyses. The results showed that asphaltene...