Sharif Digital Repository

Archaeological excavations in western Iran have recently revealed a significant Luristan Bronzes collection from Sangtarashan archaeological site. The site and its bronze collection are dated to Iron Age II/III of western Iran (10th-7th century BC) according to archaeological research. Alloy composition, microstructure and manufacturing technique of some sheet metal vessels are determined to reveal metallurgical processes in western Iran in the first millennium BC. Experimental analyses were carried out using Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy and Optical Microscopy/Metallography methods. The results allowed reconstructing the manufacturing process of bronze... 

NiZn nanoferrites doped with rare-earth cations having stoichiometric composition such as Ni0.5Zn0.5R0.02Fe1.98O4 (R = Tb, Pr, Ce, Gd, Y) were prepared by sol–gel technique. The same amount of Ni and Zn with constant ratio of different rare-earths ions were doped to investigate the variations in the properties. X-ray diffraction (XRD), Field emission electron microscope (FESEM), and vibrating sample magnetometer (VSM) were used to investigate the structure, morphology, and magnetic properties of rare-earth doped NiZn nanoferrites, respectively. X-ray density, bulk density, and porosity were also calculated. Phase, crystallite size, structure, d-spacing, lattice parameter, micro strain, and... 

NiZn nanoferrites doped with rare-earth cations having stoichiometric composition such as Ni0.5Zn0.5R0.02Fe1.98O4 (R = Tb, Pr, Ce, Gd, Y) were prepared by sol–gel technique. The same amount of Ni and Zn with constant ratio of different rare-earths ions were doped to investigate the variations in the properties. X-ray diffraction (XRD), Field emission electron microscope (FESEM), and vibrating sample magnetometer (VSM) were used to investigate the structure, morphology, and magnetic properties of rare-earth doped NiZn nanoferrites, respectively. X-ray density, bulk density, and porosity were also calculated. Phase, crystallite size, structure, d-spacing, lattice parameter, micro strain, and... 

The mixed nano-ferrites materials Cu0.6Zn0.4HoxFe2−xO4 (0.00 ≤ x ≤ 0.12) were prepared via the sol–gel auto combustion technique. The TGA curve established the annealing temperature (500 °C) for phase formation. The single exothermic peak on the DSC plot occurred at 341 °C temperature. XRD patterns of these nano ferrites verified single phase formation of the FCC cubic structure. The lattice constant a was increased from 8.4244 to 8.4419 Å and then its value decreased to 8.4319 Å. Crystallite size was found in the range of 7 to 16 nm. The surface morphology of the samples was observed from the scanning electron microscope (SEM) images. The grain size was found within the range of 90 nm to... 

The mixed nano-ferrites materials Cu0.6Zn0.4HoxFe2−xO4 (0.00 ≤ x ≤ 0.12) were prepared via the sol–gel auto combustion technique. The TGA curve established the annealing temperature (500 °C) for phase formation. The single exothermic peak on the DSC plot occurred at 341 °C temperature. XRD patterns of these nano ferrites verified single phase formation of the FCC cubic structure. The lattice constant a was increased from 8.4244 to 8.4419 Å and then its value decreased to 8.4319 Å. Crystallite size was found in the range of 7 to 16 nm. The surface morphology of the samples was observed from the scanning electron microscope (SEM) images. The grain size was found within the range of 90 nm to... 

We have investigated the surface-enhanced resonance Raman spectroscopy (SERRS) for 4,4′-diaminotolane absorbed on silver experimentally and theoretically. Experimental observation shows greatly enhanced bg symmetric modes ν26 and ν27, which are silent in normal Raman spectroscopy and SERS on gold. The dependence of the surface-enhanced Raman spectroscopy (SERS) spectra on five excitation lines has also been registered and classified for single bands into three profiles referring to the different contributions of resonant transitions. Theoretical calculations based on the time-dependent path integral formalism by including the Herzberg-Teller correction reproduce the experimental spectra with... 

This paper presents the results obtained and the deductions made from a series of microstructural studies and mechanical tests involving gray cast iron which was sand cast using a variety of modules. The effect of cooling rate on the primary dendrite arm spacing (DAS), secondary dendrite arm spacing (SDAS), thickness of ferrite-cementite layer (λe) and the hardness (HB) were evaluated. Results show that the both DAS and SDAS and also λe are highly dependent on the cooling rate, and they decreases as the cooling rate increases. More attempts were also done to correlate the HB with DAS, SDAS and λe. It was found that HB increases as DAS, SDAS and λe decreases  

Effort was made to characterise segregation tendency of mechanically stirred ZA27 alloy with back extrusion as a thixoforming process. At sufficiently high ram speeds, at which liquid phase flows forcefully, pooling of the heavy liquid phase owing to gravitational segregation contributes to homogeneity of back extruded products in terms of solid phase distribution, The amount of this contribution depends on the contact time of this liquid with solid skeleton during liquid exertion to the clearance. Hence, at high ram speeds, small rams which demand taller initial slugs are more efficient in minimising the segregation. However, in the case of low speed back extrusion tests, liquid impotency... 

It is known that the thermomechanical processing is one of the most important techniques for improving quality and mechanical properties of microalloyed steels. In this paper, the main parameters of hot forging (preheat temperature, strain and post-forging cooling rate) on the primary austenite grain size of vanadium microalloyed steel (30MSV6) were studied. From this investigation, it was found that increasing preheat temperature from 1150 °C to 1300 °C will result in a decrease in grain size number. Furthermore, it has shown that as the strain increases, the austenite grain size number increases, as is evident for the two cooling rates of 2.5 °C/s and 1.5 °C/s for primary austenite.... 

In this research, the mechanical properties of various glass fibre reinforced polymer (GFRP) pultruded profiles exposed to seawater sea sand concrete (SWSSC) and its combination with UV radiation and water vapour condensation were studied. The effect of different conditions, duration of conditioning, and the profile cross-section configuration on the mechanical properties were investigated. Three-point bending, tension, and compression tests were carried out to obtain the mechanical properties, including flexural, tensile and compressive strengths and tensile elastic modulus. Furthermore, in order to scrutiny the mechanisms and extent of damage, scanning electron microscopy (SEM) was carried... 

The heterogeneous environmentally friendly catalyst and photocatalyst based on Ag, Pt, Ag–Pt nanoparticles (NPs) loading on the γ-Fe2O3/CuO nanocomposite which was derived from Fe-metal organic framework (Fe-MIL-88B) and Cu-metal organic framework (Cu (tpa)) was introduced. The catalytic and photocatalytic activities of Ag–Pt loading on the γ-Fe2O3/CuO nanocomposite were performed for a reduction process (4-nitrophenol (4-Nip) to 4-aminophenol (4-Amp)), and decomposition organic dyes (AB92, MB) in the LED light. Metal-organic framework (MOFs) composed with inorganic and organic linker which used as suitable precursors to obtain different type of nanostructures for environmental applications.... 

In this paper, the effect of molybdenum on the grain boundary segregation of other elements was studied in Incoloy 901 superalloy. Initially, five alloys were prepared with different percentages of Mo by using a vacuum induction furnace. Then, these alloys were remelted by Electro-slag remelting (ESR) process and after homogenizing at 1160 °C for 2. h followed by air cooling, were rolled. The effect of Mo on segregation of elements was evaluated with Scanning Electron Microscopy, Linear Analysis, and the mechanical tests. The results showed that the grain boundary segregations of elements in Incoloy 901 superalloy were decreased by increasing of molybdenum content up to 6.7% and the... 

In this study, the permeability for interdendritic liquid flow through equiaxial mushy zone has been modeled and experimentally measured. In the present work, by applying a virtual dendrite in a micro-domain and solving Navier-Stokes equation, flow pattern around the dendrite has been obtained and then by applying Darcy's law to this 3D domain the permeability has been determined. In this micro-model the influence of solid fraction and geometry of dendrites have been assessed. Numerically determined values of permeabilities have been analyzed by the use of SPSS statistical software. Then an experimental method is used to measure the permeability for flow through equiaxial mushy zone of Pb-Sn... 

In the present work, diffusion bonding of Fe-5%Cu powder compact to wrought carbon steels was studied. Effects of iron particle size and carbon content of the solid component on the bond strength, which is the maximum shear stress required to obtain separation at the interface, were investigated. Atomized iron powders with the mean particle size of 36, 56, 90, 106, and 148 μm and wrought steels with 0.22, 0.33, and 0.47 wt% carbon content were used. To evaluate the bonding zone, "ring shear" test, standard metallography technique, and micro-hardness test were employed. The results showed a profound effect of carbon content of the solid steel on the diffusion bonding process. It is suggested... 

A numerical model has been developed for the determination of liquid flow permeability through columnar dendrite during growth and segregation in Al-Si mushy alloys. The model is inclusive of two stages, first numerical evolution of the dendrite shape during growth, and second numerical determination of the permeability. Simulation results shown which Si concentration by transform of dendrite shape dendrite could reduce of the interdendritic liquid permeability. © 2005 Elsevier Ltd. All rights reserved  

In this paper, in order to investigate the creation of macroscopic shear bands, due to material flow tracks in the cross section of a wire after flat rolling, the combined Finite and Slab Element Method (FSEM) is used. The effective strain field is predicted for different reductions in height. The validity of the method is assessed by performing the Vickers microhardness measurements on the cross section of the flattened wire. It is found that the FSEM and microhardness results show the minimum and the maximum effective strains at the round edge and the center of the flattened wire, respectively. Also, the results indicate two bands of maximum effective strain in the cross section of the... 

Rene-80, as an alloy for production of the jet turbine blades, shows high mechanical properties as well as microstructure stability during the high temperature engine operation. In this study we tried to have a deep insight on the microstructure of the cast Rene-80 and the evolution of microstructure during the different stages of the relatively complex GE class-A heat treatment. Although the solution heat treatment homogenized the chemical alloy segregation resulted from the casting to some extent, it did not cause all the casting γ′ particles to dissolve completely in the matrix. Primary aging caused growth in the residue particles as well as growth of the new precipitated particles, which... 

In this work, cavitation during creep in AA7075-T76 was simulated employing a probabilistic cellular automata scheme. Two-dimensional cellular automata coupled with the governing equations for cavity growth were utilized to define the size and distribution of cavities during creep. Both diffusion and strain-controlled mechanisms were taken into account while the first and second neighboring cells were considered for determination of the cavity growth as well as to generate the initial microstructure. Moreover, uni-axial creep experiments on AA7075-T76 were carried out under different temperatures and applied stresses including 170 MPa at 150 °C and 150 MPa at 160 °C. The microstructural... 

Controlled graphitization has become known as a practical method for improvement of wear resistance and machining properties in steels. In this paper, the effect of heat treatment on microstructure of CK45 steel has been investigated. Austenitising was carried out at 920 °C for 5 h. Besides, isothermal transformation was conducted at 750 °C in the time range of 1-20 h. In this work, full potential carbon resource was tried to be used around samples as a factor to prevent the burning of the limited carbon in steel and also to increase the percentage of sample surface carbon in order to improve wear capability and machining. The microstructure of the steel considerably changes by this heat... 

In this study the influences of predeformation and heat treatment conditions on stress-induced melt activating process (SIMA) of A319 aluminum alloy were investigated. At 30% of predeformation a dominant globular structure of grains was obtained. However, further increasing of the predeformation rate considerably reduced the shape factor. The holding time of 10-15 min at semi-solid temperature of 580 °C was suggested in order to prevent grain growth. Coarsening of the grains by excess time or temperature of heat treatment reduced the tensile strength of the alloy. © 2008 Elsevier B.V. All rights reserved