Sharif Digital Repository

An analytical expression for the fugacity coefficient of supercritical fluids has been derived from the equation of state. Here, the equation of state known as the linear isotherm regularity, LIR, is used to obtain this expression. We have inverted the LIR equation of state to obtain an appropriate expression for fugacity calculation. The inverted LIR (ILIR) works well at high pressures; but at high temperatures, Tr = T/Tc ≥2, ILIR is valid for the entire pressure range. ILIR is valid over a wide temperature range. Unlike LIR, ILIR is also valid at temperatures above twice the Boyle temperature. Like LIR, the inverted equation is a general equation of state which is valid for all types of... 

Generally, there are different enhanced oil recovery (EOR) methods. One of the most promising EOR method is the gas injection especially carbon dioxide (CO2) injection since it introduce several unique characteristic desired for higher tertiary oil recovery. In this study, the performance and feasibility of supercritical carbon dioxide (SC-CO2) and supercritical nitrogen (SC-N2) injection to enhanced oil recovery was investigated. In this regard, swelling tests and core flooding experiments were performed to find out whether the injections of these gases are efficient to recover trapped oil in the reservoir. Based on the experimental results, the possible active mechanisms were discussed on... 

In this paper, a new correlation to calculate the thermal conductivity of supercritical carbon dioxide based on 668 data points from the literature is introduced. The proposed correlation is valid in temperature range from 310 to 960 K, and pressures range between 7.4 and 210 MPa. The average absolute error of the model was found to be 2.7 and 2.4% in the comparison with the literature and NIST data respectively, which demonstrates superiority of the model over other methods  

The effective parameters such as particle size, temperature, pressure and extraction time on supercritical carbon dioxide extraction of cocoa butter form cocoa seed were studied in order to find the optimum conditions for extraction. Particle size from whole cocoa nibs to one millimeter diameter, extraction temperature from 35°C to 55°C, extraction time from 2 to 8 hours and extraction pressure from 5 to 20 MPa were investigated and optimized. The optimum results (according to the limitation of the apparatus) of 5.2% extraction efficiency, suggests that pure CO2 is not a suitable solvent for extraction of cocoa butter in the investigated range of parameters and therefore the use of a... 

Dissolution pressure and nozzle temperature effects on particle size and distribution were investigated for RESS (Rapid Expansion of Supercritical Solution) process. Supercritical CO2 was used as solvent and Ibuprofen was applied as the model component in all runs. The resulting Ibuprofen nano-particles (about 50 nm in optimized runs) were analyzed by SEM and laser diffraction particle size analyzer systems. Results show that in low supercritical pressure ranges, depending on the solvent and solid component properties (Lower than 105 bar for Ibuprofen-CO2 system), nozzle temperature should be as low as possible (80-90 °C for Ibuprofen-CO2 system). In the other hand in high supercritical... 

In this study, the essential oil of aerial parts species of a plant called Spearmint was extracted by CO 2 to optimize the results of the supercritical extraction process. In order to achieve maximum total yield extraction and SF-CO 2 concentration, tests were done in a laboratorial pilot considering the Taguchi method under following condition: pressure. 90,100,140,170 bar, temperature. of 35, 40, 45, 50 °C, mean particles size: 250,500,710,1000 μm, flow rate 1,3,5,8 ml/s and dynamic time 30,50,90,120 min. The optimizing conditions for SCE and SF-CO 2 concentration are: 90 bar, 45 °C, 500 μm, 5 ml/s, 120 min and 90 bar, 35 °C, 250 μm, 1 ml/s, 30 min. SCE total yield and CO 2 concentration... 

The effect of porosity in oscillating situations (to the authors' knowledge, for the first time) on a supercritical airfoil (SC0410) has been experimentally investigated. Tests have been carried out in an open circuit suction-type wind tunnel at a free stream Mach number of M = 0:80. Both static and dynamic (pitching) tests have been carried out on the mentioned airfoil. The oscillation frequency for the unsteady tests has been set to 3 and 6 Hz. The amplitude of frequency is ±1 deg. The effect of porosity has been surveyed on the magnitude of pressure fluctuations, phase shift, and lift coefficient loop. The investigations show that increasing porosity in the test section of transonic... 

A new flow model of high performance light water reactor (HPLWR) is discussed in the present study. HPLWR involves a negative density reactivity coefficient with high time delay. This factor decreases the stability of such reactors when transient and abnormal accidents happen. A new design for enhancing safety and efficiency in such reactors is presented. In the new design, the fluid passing through the moderator channels and the assembly gaps (known as a moderator) flows in channels detached from coolants. It is possible to control the moderator mass flux. Increasing or decreasing the moderator mass flux will modify the moderation capacity, which results in a change in the reactor power.... 

Conventional buffet onset methods for a 2D supercritical airfoil, SC0410, in transonic regime for various Mach number and various angles of attack have been surveyed. The existing methods give good results for high subsonic and transonic regimes, but demand a computational procedure to detect the buffet onset. One of these methods, trailing edge pressure divergence, that have been recognized inappropriate in other studies for supercritical airfoils, shows acceptable result at least for the present supercritical airfoil. A new method has been proposed by the authors for transonic regime that is based on the physical definition of the buffet onset from the surface pressure distribution... 

Side weirs are widely used for level control and flow regulation in hydraulic engineering applications such as irrigation, land drainage, and sewer systems. These hydraulic structures allow a part of the flow to spill laterally when the surface of the flow in the main channel rises above the weir crest. The supercritical flow over a side-weir is a typical case of spatially varied flow with decreasing discharge. This study is aimed at investigating the variations of specific energy along the side-weir using experimental results. Some diagrams have been presented in terms of dimensionless ratio of diverted discharge to total discharge. These diagrams which can be used in the design of side... 

In this article, the conjugate heat transfer of the methane coolant inside a rectangular channel is studied and the related Nusselt correlations are improved. The compressible methane flow enters the cooling channel at supercritical pressure and subcritical temperature. The coolant flow absorbs heat from the heated walls and exits the channel with a supercritical temperature. An in-house solver is developed employing Semi-Implicit Method for Pressure-Linked Equations-Consistent (SIMPLEC) algorithm accompanied by the appropriate thermodynamic and transport property relations for the supercritical conditions of the methane coolant. The solver is validated with the experimental data found in... 

The absolute free energy of solvation of methane (CH4) and its fluorinated forms (CH3F, CH2F2, CHF3 and CF4) have been computed via statistical perturbation theory (SPT) in the NPT ensemble at four thermodynamical states (whitin liquid and supercritical regions), in the context of Monte Carlo Simulations. Thermodynamical interpretation of the observed trend in the absolute free energy of solvation in different states reveals an exothermic solvation with ΔSslv < 0 (entropically unfavorable solvation) that the intermolecular interactions play an important role in the solvation process. The fluorinated methanes are confirmed to control the mutual arrangement of neighboring CO2 molecules and the... 

New treatment technologies are currently being investigated for the treatment of contaminated drilling waste mud with oil. Supercritical fluid extraction is a promising technology that could be effectively used to extract this contaminated drilling waste mud. In this work, one step extraction efficiency of supercritical carbon dioxide to drilling waste mud of South Pars gas field has been investigated at a range of temperatures (55 to 79.5 °C), and over a pressure range of 160 to 220 bar. Extraction efficiencies were calculated based on cuttings weight loss. Results show that approximately 28.45% of cuttings weight loss in one step extraction at a pressure of 200 bar and temperature of 60 °C... 

An experimental flow-type apparatus has been tested for the separation of phenanthrene from a mixture of solids (phenanthrene, anthracene, and carbazole) and also from anthracene oil of the Isfahan Coal Tar Refining Company based on retrograde crystallization phenomena in supercritical carbon dioxide. The results show that by exploiting the crossover effect it is possible to obtain (82 and 24) mass % of phenanthrene from the solid mixture and anthracene oil, respectively, with a single temperature cycle  

Supercritical fluid extraction (SFE) is a relatively new separation technique that has received much attention in recent years. This process is an alternative to distillation or liquid extraction. Its main advantage over the conventional ones is that the dissolved extract may be completely separated from the supercritical fluid simply by decreasing the pressure. In recent years considerable effort has been devoted to the measurement of equilibrium solubility data for solids in supercritical fluids. A coal tar distillate, anthracene oil, which contains 34.46 mass-% phenanthrene, 33.8 mass-% anthracene, 13.89 mass-% carbazole and other impurities, was used as the model mixture. In this study,... 

Both the equation of state-excess Gibbs energy (EoS/GE) model and the cubic plus association (CPA) equation of state (EoS) are compared in this study with respect to their accuracy in the correlation of PVTx for systems such as water/methanol, water/ethanol, water/benzene, water/toluene, water/methane, water/n-butane, water/n-pentane, water/n-hexane, water/heptane, and water/octane, in supercritical conditions within temperature and pressure ranges of (573-698 K) and (7. 0-276. 0 MPa), respectively. In the proposed EoS/GE model, Peng-Robinson (PR) equation of state, linear combination Vidal-Michelsen (LCVM) and Wong-Sandler (WS) mixing rules in conjunction with UNIQUAC activity coefficient...