Search for: wettability-alteration
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    Wettability alteration of reservoir rocks to gas wetting condition: a comparative study

    , Article Canadian Journal of Chemical Engineering ; Volume 96, Issue 4 , April , 2018 , Pages 997-1004 ; 00084034 (ISSN) Erfani Gahrooei, H. R ; Ghazanfari, M. H ; Karimi Malekabadi, F ; Sharif University of Technology
    Wiley-Liss Inc  2018
    Productivity of gas condensate reservoirs reduces significantly due to the near wellbore condensate/water blockage phenomenon. A novel, permanent solution to alleviate this problem is near wellbore wettability alteration of reservoir rocks to preferentially gas wetting conditions; industrial chemical materials are good candidates for this purpose, because of their eco-friendly characteristics, economical price, and mass production. In this paper, a comparative study is conducted on two industrial fluorinated chemicals, MariSeal 800 and SurfaPore M. Static and dynamic contact angle measurements, spontaneous imbibition, and core flooding tests were conducted to investigate the effect of... 

    Experimental study on enhanced oil recovery by low salinity water flooding on the fractured dolomite reservoir

    , Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 40, Issue 5 , 2021 , Pages 1703-1719 ; 10219986 (ISSN) Ebrahimzadeh Rajaee, S ; Gerami, S ; Safekordi, A. A ; Bahramian, A. R ; Ganjeh Ghazvini, M ; Sharif University of Technology
    Iranian Institute of Research and Development in Chemical Industries  2021
    Enhanced Oil Recovery from carbonate reservoirs is a major challenge especially in naturally fractured formations where spontaneous imbibition is a main driving force. The Low Salinity Water Injection (LSWI) method has been suggested as one of the promising methods for enhanced oil recovery. However, the literature suggests that LSWI method, due to high dependence on rock mineralogy, injected and formation water salt concentration, and complexity of reactions is not a well-established technology in oil recovery from carbonate reservoirs. The underlying mechanism of LSWI is still not fully understood. Due to lack of LSWI study in free clay dolomite fractured reservoir, and to investigate of... 

    The impact of surfactants on wettability change and level of water imbibition in relation to EOR in carbonate reservoirs

    , Article Petroleum Science and Technology ; Volume 31, Issue 20 , 2013 , Pages 2098-2109 ; 10916466 (ISSN) Zangeneh Var, A ; Bastani, D ; Badakhshan, A ; Sharif University of Technology

    Isolation and screening of Bacillus subtilis MJ01 for MEOR application: biosurfactant characterization, production optimization and wetting effect on carbonate surfaces

    , Article Journal of Petroleum Exploration and Production Technology ; Volume 9, Issue 1 , 2019 , Pages 233-245 ; 21900558 (ISSN) Jahanbani Veshareh, M ; Ganji Azad, E ; Deihimi, T ; Niazi, A ; Ayatollahi, S ; Sharif University of Technology
    Springer Verlag  2019
    The bacterial strain MJ01 was isolated from stock tank water of one of the Iranian south oil field production facilities. The 16S rRNA gene of isolate, MJ01, showed 99% similarity to Bacillus subtilis. The results revealed that biosurfactant produced by this strain was lipopeptide-like surfactin based on FTIR analysis. Critical micelle concentration of produced surfactin in distilled water was 0.06 g/l. Wettability study showed that at zero salinity surfactin can change original oil-wet state to water-wet state, but in seawater salinity it cannot modify the wettability significantly. To utilize this biosurfactant in ex situ MEOR process, economical and reservoir engineering technical... 

    Investigating Wettability Alteration During MEOR Process

    , M.Sc. Thesis Sharif University of Technology Soleymani, Fatemeh (Author) ; Ayatollahi, Shahab (Supervisor) ; Kariminia, Hamid Reza (Supervisor)
    Microbial enhanced oil recovery (MEOR) is a collection of techniques that utilize microorganisms and their metabolic products to improve the recovery of crude oil from reservoir rock. From the advantages of this method, independency to the oil price and environmental benign can be mentioned. Many mechanisms have been proposed to contribute on MEOR, but still there is no enough knowledge about the mechanisms that causes inabilities in manipulating the process to get more oil production.
    In the present study, the effect of a native type of bacteria, Enterobacter cloacae, on the glass surfaces wettability which were aged in expose of model oil with different asphaltene concentration was... 

    Mechanistic Investigation of Enhanced Oil Recovery by Engineered Water Using Computational Fluid Dynamics at Pore Scale

    , Ph.D. Dissertation Sharif University of Technology Namaee Ghasemi, Arman (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Mahani, Hassan (Supervisor)
    Despite the proven advantage of the engineered water flooding technique, a coherent and mechanistic understanding of the fundamental phenomena occurring at pore scale is lacking. Most of the available simulation models have a phenomenological approach and have limited predictive capability. One of the key questions is how to justify and relate large (Darcy) scale observations to effects and phenomena that essentially occur at much smaller scales (i.e. pore and molecular level). Furthermore, two-phase flow dynamics and the effect of complex interplay between wettability, capillary number, and ions dispersion in a heterogeneous porous medium on the trapping and mobilization of oil at pore... 

    Experimental Investigation of Heavy Oil Recovery by Natural Surfactant Injection in Heterogeneous Systems Using Micromodel Apparatus

    , M.Sc. Thesis Sharif University of Technology Aabloo, Milad (Author) ; Rashtchian, Davood (Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Advisor)
    Nowadays, due to limitation of production from conventional oil reservoirs, enhanced recovery from heavy oil reservoirs is of great concern. However, production from these energy resources is not a simple task and production using common technologies is not easily exploitable. Heterogeneous structure and also high surface tension between injected fluid and reservoir oil are of the main challenges during water flooding processes in heavy oil reservoirs. The high surface tension force causes a large part of the oil remains in the reservoir after the water flooding operation. One method for overcoming this problem is the use of surfactants that reduces capillary forces and consequently... 

    Wettability Altration Determination by Using Streaming Potential

    , M.Sc. Thesis Sharif University of Technology Esmaeili, Sajjad (Author) ; Massihi, Mohsen (Supervisor) ; Ayatollahi, Shahabodin (Supervisor)
    The assessment of fluid transport in porous media is the main subject in oil reservoirs to understand the oil recovery efficiency. The efficiency of Enhanced oil recovery (EOR) processes depends on the surface properties and wetting behavior of oil reservoir rocks which are also affected by the electrokinetic behavior of solid part of the porous rock. Streaming potential measurement is one of the techniques to determine the electrokinetic properties. The streaming potential measurements using electrodes have recently been introduced in oil field applications and there are still significant uncertainties during the measurements and interpretation of streaming potential results. The Primarily... 

    Experimental and Modeling Study of Controlled Salinity Water Injection for Enhanced Oil Recovery from one of Iranial Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Shojaei, Mohammad Javad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Masihi, Mohsen (Co-Advisor)
    From previous years, water injection was considered as one of the most common methods for enhanced oil recovery. But recently much attention has been paid on the use of low salinity water (LSW) as an enhanced oil recovery fluid. The main mechanism that causes improve oil recovery is wettability alteration to a more water wet state. The change observed in recovery factor during LSW flooding induced from changes in relative permeability and capillary pressure when different levels of salinity are used. However, a few researchers tried to evaluate how macroscopic flow functions depend on the salinity of injected water. To this end, a series oil displacements by water performed on sandstone rock... 

    Investigating the Role of Nanoparticles and Chemicals on Wettability Alteration of Carbonate Rocks to Gas-Weting Condition and Analysis of Hystertic Behavior

    , M.Sc. Thesis Sharif University of Technology Azadi Tabar, Mohammad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor)
    The purpose of this study was to investigate the experimental and modeling of the drop formation process on calcite rock and calcite aged in nano fluid surfaces in order to analyze size dependent contact angle and wettability modification. To do this, the calcite surfaces were prepared by cutting to an approximately size of 3*3*0.4 cm and grinded and polished to achieve different roughnesses. The purity and roughness of the samples were determined by X-ray diffraction and atomic force microscopy, respectively. In order to conduct the dynamic and static contact angle measurements on the calcite surface in vapor saturated condition, a small laboratory device was designed. The advanced contact... 

    Janus Silica Nanoparticles and Their Application for Enhanced Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Behzadi, Abed (Author) ; Mohammadi, Ali Asghar (Supervisor)
    Nanoparticles can be applied as chemical agent in enhnaced oil recovery like surfactants and polymers. One of nanoparticles usefull capabilities is modification of their surface. This research investigates this capabilty of nanoparticles in enhanced oil recovery. Surface modification of nanoparticles with both agents can bring new abilities to these materials. Here surface of silica nanoparticles is modified by hydrophilic agent comprising PEG groups, hydrophobic agent comprising propyl group and both agents. FT-IR tests showed that grafting of modifiyng agents on surface of nanoparticles is well done. To investigate effect of nanoparticles surface modification on nanoparticles capability in... 

    Experimental and Modeling Study of Enhanced Oil Recovery Improvement during Nanosilica Particle Flooding to Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Nejatinezhad, Atefe (Author) ; Vosoughi, Manuchehr (Supervisor) ; Ghazanfari, Mohammad Hassan (Supervisor) ; Masihi, Mohsen (Supervisor)
    Recent studies in nanotechnology field have shown this technology could solve many challenges and needs in oil and gas industry. As yet, many applications of nanoparticles in enhanced oil recovery have been reported. One of the most important applications is wettability alteration due to presence of nanoparticles in injecting fluid, which has recently been studied by several research groups. These studies indicate that, presence of nanoparticles in injecting water would improve oil recovery. However, there is no adequate information about the mechanisms affecting fluid flow in reservoir rock and its mathematical modeling.The aim of this project is to evaluate the effect of injection of... 

    Experimental Study of Nano-bio Material Injection for Heavy Oil Recovery in Shaly Systems Using Micro-model Apparatus

    , M.Sc. Thesis Sharif University of Technology Mohebbifar, Mahdi (Author) ; Vossoughi, Manouchehr (Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Advisor)
    In this research we aim to find enhance oil recovery mechanisms involved in nano-bio material injection by micro model apparatus which has not been studied before. Especially for injection in heavy oil and shaly porous media that forms most of heavy oil reservoirs. To this end, microscopic images from injection of nano-bio materials to shaly patterns have been taken and analyzed to find the process mechanism. Also amount of enhance oil recovery in different conditions like type of microbe forming bio material, nano-bio material concentration and type of flow pattern (shale characteristics including length, direction and distance from injection and production wells) will be studied.Three... 

    Modeling of Wettability Alteration During Enhanced Oil Recovery by Surfactants

    , M.Sc. Thesis Sharif University of Technology Aliabadian, Ehsan (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Ayatollahi, Shahaboddin (Supervisor)
    There are considerable investigations on wettability alteration in carbonate reservoirs in recent years. The presence of ions including Ca, Si, Al etc in natural carbonate rocks and also the presence of various fatty acids, resins, asphaltenes etc in crude oil makes it difficult to understand the complex mechanism of wettability alteration by using surfactants. Furthermore there is still a conspicuous lack of dynamic wettability alteration model to demonstrate the dynamic behavior of cationic surfactants during wettability alteration. It is also widely accepted that cationic surfactants have substantial impact on changing the wettability of strongly oil-wet matrixes to a more water-wet... 

    Experimental Investigation of Surface Properties and Wettability Using Super Gas Wetting Surface Modified Multi-Nano-Composites

    , M.Sc. Thesis Sharif University of Technology Shayesteh, Mohammad (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Fakhroueian, Zahra (Supervisor)
    Recently, the researchers try to identify the application of nanofluids for wettability alteration. Changing the wettability of reservoirs, which gas injects to them, to gas wet can lead to enhanced oil recovery. Although several studies have been conducted to introduce proper nanofluids for altering the wettability of reservoirs to gas wet, there is not enough study to investigate the application of nanocomposites for wettability alteration of carbonate reservoirs. In this study, 20 nanoparticles with different compositional structures were synthesized, and then various nanofluids were prepared for the experimental survey. Also, the potential of these nanofluids for wettability alteration... 

    Pore-scale Simulation of Trapping Phenomena and Hysteresis Effect in Porous Media

    , M.Sc. Thesis Sharif University of Technology Tabibnejad Azizi, Mehdi (Author) ; Fatemi, Mobeen (Supervisor)
    So far, many studies have been carried out on the core-scale regarding the effects of hysteresis on the macro-scale properties of systems including fluids and porous rock, however, many issues related to the physics of the problem (especially regarding the way fluids are distributed and the trapping of the non-wetting phase) at the pore-scale need further investigation. In the process of multiphase fluid flow in porous media, hysteresis refers to the dependence of the results of the fluids’ displacements on the history of fluid saturation and the direction of saturation changes (increasing or decreasing). The first step to investigate the hysteresis effect is to determine the amount of fluid... 

    Wettability Alteration and its Effect on Oil Recovery by using Colloidal Nano-Silica in Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Sadatshojaie, Ali (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Goodarznia, Iraj (Supervisor) ; Badakhshan, Amir (Co-Supervisor)
    As many oil fields are reaching their final stage of production, new technologies are required in order to maintain production and increase recovery of hydrocarbons. Among these techniques of enhanced oil recovery (EOR), chemical injection method focuses on increasing the effectiveness of waterflooding. Due to the relatively high costs and considerable adsorption on the rock formations, this method is no longer used. In Recent years nanofluids (nanoparticles dispersed in brine) have been used as a cheap, efficient and environmentally friendly alternative more than any other chemicals. It has been stated that the Smart Water method and enhanced oil recovery by SiO2 nanoparticles are effective... 

    Experimental investigation of nano-biomaterial applications for heavy oil recovery in shaly porous models: A pore-level study

    , Article Journal of Energy Resources Technology, Transactions of the ASME ; Volume 137, Issue 1 , August , 2014 ; 01950738 (ISSN) Mohebbifar, M ; Ghazanfari, M. H ; Vossoughi, M ; Sharif University of Technology
    American Society of Mechanical Engineers (ASME)  2014
    Application of nano or biomaterials for enhanced oil recovery (EOR) has been recently much attended by petroleum engineering researchers. However, how would be the displacement mechanisms and how would change the recovery efficiency while nano and biomaterials are used simultaneously is still an open question. To this end, a series of injection tests performed on micromodel containing shale strikes. Three types of biomaterials including biosurfactant, bioemulsifier, and biopolymer beside two types of nanoparticles including SiO2 and TiO2 at different concentrations were used as injection fluids. The microscopic as well as macroscopic efficiency of displacements were observed from analysis of... 

    Wettability alteration modeling for oil-wet calcite/silica nanoparticle system using surface forces analysis: contribution of DLVO versus non-DLVO interactions

    , Article Industrial and Engineering Chemistry Research ; Volume 57, Issue 43 , 2018 , Pages 14482-14492 ; 08885885 (ISSN) Dehghan Monfared, A ; Ghazanfari, M. H ; Kazemeini, M ; Jamialahmadi, M ; Helalizadeh, A ; Sharif University of Technology
    American Chemical Society  2018
    In this work, application of silica nanoparticles for wettability alteration of initially oil-wet calcite was investigated through analysis of surface forces and DLVO theory. Doing so, the wettability and zeta potential of calcite surfaces were measured through the sessile drop method and an in-house experimental setup, respectively. Primary evaluation indicated that incorporating DLVO terms in the Frumkin-Derjaguin model was not sufficient to describe the wettability in an oil-wet calcite/nanofluid system. Sensitivity analysis showed that calculating the double-layer interaction using constant potential-constant potential boundaries along with structural hydrophobic forces (non-DLVO... 

    Impact of rock morphology on the dominating enhanced oil recovery mechanisms by low salinity water flooding in carbonate rocks

    , Article Fuel ; Volume 324 , 2022 ; 00162361 (ISSN) Farhadi, H ; Ayatollahi, S ; Fatemi, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Because of the complex nature of carbonate reservoirs, the required conditions for effective Low Salinity Water Flooding (LSWF) in these reservoirs need further and in depth investigation. In the present study, three calcite cores, i.e. Cal-1, Cal-2, and IL, with the same chemical composition are subjected to tertiary low salinity water flooding (LSWF), while the crude oil and composition of flooding brine kept the same. The experimental results show significant difference in the amount of enhanced oil recovery, as IL had the most additional oil recovery (20.8 % of IOIP), followed by Cal-2 (10.5 % of IOIP) and Cal-1 (3.9 % of IOIP). The results of contact angle, zeta potential, and effluent...