Michael Addition of Anthrone to Nitroolefines in Water and Oxidation of Alkenes Using a Supported Iron Oxide Nanocatalyst<br/>

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Michael Addition of Anthrone to Nitroolefines in Water and Oxidation of Alkenes Using a Supported Iron Oxide Nanocatalyst

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Type of Document: M.Sc. Thesis
Language: Farsi
Document No: 42395 (03)
University: Sharif University of Technology
Department: Chemistry
Advisor(s): Saeedi, Mohammad Reza; Ziyaei Halimehjani, Azim; Rajabi, Fatemeh
Abstract:
This projct includes the following sections: In the first section, Michael addition reaction of anthrone to nitroolefins is described in water without using any catalyst to prepare 9-(2-nitro-1-arylethyl)anthracene-10(9H)-ones. This method is green, efficient and gives high yields of products. The solvent effect is also investigated. In the second section, Considerable efforts have been directed in recent years towards the transition metal complex catalyzed oxidation of organic compounds such as olefins, sulfides, benzylics alcohols and phenolics. And due to the various advantages of supported heterogeneous catalysts and in our aim to develop a simple, more efficient and eco-friendly catalytic processes, in this section, we have reported the application of a simple Fe(III) complex supported on mesoporous SBA-15 in the aqueous selective catalytic oxidation of styrene and its derivatives under mild conditions. The reactions proceeded within reasonable time frames and lead to remarkably high yields
Keywords:
Michael Addition ; Catalytic Oxidation ; Immobilized Catalyst ; Nanoporous Materials ; Anthrone ; Nitroolefine

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