Synthesis and Characterization of Dithiocarbamate Complex Derivatives of 3-((Pyridin-2-yl)Methyl Amino)Propannitril

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Torabi, Saeedeh | 2013

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Type of Document: M.Sc. Thesis
Language: Farsi
Document No: 45125 (03)
University: Sharif University of Technology
Department: Chemistry
Advisor(s): Saeedi, Mohammad Reza; Ziyaei Halimehjani, Azim
Abstract:
Dithiocabamates are valuable compounds due to their wide application as herbicides, fungicides, antitumor and etc. Another aspect of dithiocarbamates is their application in coordination chemistry. In this project, 3-((pyridin-2-yl) methyl amino) propane nitrile was prepared via Michael addition reaction of 1-methyl¬amino¬pyridine and acrylonitrile in water. Then this compound was converted to its potassium dithiocarbamate salt via treatment with carbon disulfide in the presence of potassium hydroxide in tetrahydrofuran. The prepared ligand was used in complexation with metal salts of Zn, Hg, Ni and Sn to prepare their dithiocarbamate complexes. The structure of complexes was elucidated by 1HNMR, 13CNMR, IR, X-ray, TGA and UV-Vis analyses
Keywords:
Dithiocarbamate ; Michael Addition ; COMPLEXES ; 1-Methylamino Pyridin

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