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Non-covalent sulfoxide⋯(nitrosyl group) interactions involving coordinated nitrosyl in a Ru(ii) nitrosyl complex with an α-diimine ligand: Structural and computational studies

Kia, R ; Sharif University of Technology | 2020

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  1. Type of Document: Article
  2. DOI: 10.1039/d0ce01063d
  3. Publisher: Royal Society of Chemistry , 2020
  4. Abstract:
  5. Investigation of the X-ray structure of the newly prepared [Ru(NO)(2,6isopPh2Aceq)Cl3] (2,6isopPh2Aceq = bis(2,6-diisopropylphenylimino)acenaphthenequinone) complex revealed for the first time the π-hole interaction involving the coordinated nitrosyl group with DMSO as the solvent of crystallization in the crystal lattice. Processing of CSD data showed only one reported structure. A significant feature of the structure is the presence of n → π∗, π → σ∗, and n → σ∗ interactions due to the coordinated nitrosyl and chloro groups and DMSO. © 2020 The Royal Society of Chemistry
  6. Keywords:
  7. Crystal structure ; Data handling ; Dimethyl sulfoxide ; Ruthenium compounds ; Acenaphthenequinone ; Computational studies ; Diimine ligand ; Hole interactions ; Nitrosyl complex ; Nitrosyl groups ; Non-covalent ; X-ray structure ; Coordination reactions
  8. Source: CrystEngComm ; Volume 22, Issue 44 , October , 2020 , Pages 7532-7537
  9. URL: https://pubs.rsc.org/en/content/articlelanding/2020/ce/d0ce01063d#!divAbstract