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Magnetic nanofluidic electrolyte for enhancing the performance of polysulfide/iodide redox flow batteries

Rahimi, M ; Sharif University of Technology | 2021

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  1. Type of Document: Article
  2. DOI: 10.1016/j.electacta.2020.137687
  3. Publisher: Elsevier Ltd , 2021
  4. Abstract:
  5. In this article, the novel concept of using magnetic nanofluidic electrolyte for redox flow batteries is demonstrated for the first time. In this regard, the stable magnetic nanofluidic electrolytes are prepared by dispersing magnetic modified multiwalled carbon nanotubes (MMWCNTs) in the positive electrolyte of a polysulfide-iodide redox flow battery at mass concentrations of less than 0.3 g L−1. The electrochemical behavior of magnetic nanofluidic electrolyte was examined using cyclic voltammetry at different mass concentrations of MMWCNTs with a carbon felt electrode. Higher and stable peak current densities were observed at larger mass concentrations of MMWCNTs. A polysulfide-iodide redox flow battery was employed to evaluate the influence of magnetic nanofluidic electrolyte on the battery performance for various mass concentrations, velocities of flowing electrolyte, and current densities using electrochemical impedance spectroscopy, polarization, and galvanostatic charge-discharge experiments. A decrease in ohmic resistance as well as reductions in the charge-transfer and mass-transfer resistances were observed for the magnetic nanofluidic electrolyte compared to those obtained in the absence of MMWCNTs. Adding MMWCNTs to the positive electrolyte at the mass concentration of 0.3 g L−1 results in enhanced performance of the polysulfide-iodide redox flow battery, whereby the peak power density increases by 45% and an energy efficiency of 79.91% was obtained at a current density of 20 mA cm−2. Moreover, high coulombic efficiency close to 100% and stable cycling performance over 200 cycles were achieved using magnetic nanofluidic electrolyte. After 50 cycles, at a current density of 30 mA cm−2, the energy efficiency of the battery operated with magnetic nanofluidic electrolyte remains 10% greater than that obtained in the absence of MMWCNTs. Besides improving the battery performance, MMWCNTs can be separated and recovered using magnetic decantation during electrolyte replacement for redox flow batteries involving high capacity fade and precipitation, which preserves system cost-benefits. The magnetic nanofluidic electrolyte could be applied for different redox solutions using appropriate magnetic nanoscale conductors. This innovative concept opens up a new opportunity to develop the next generation of high-performance and low-cost flow batteries. © 2020 Elsevier Ltd
  6. Keywords:
  7. Charge transfer ; Current density ; Cyclic voltammetry ; Electric discharges ; Electrochemical electrodes ; Electrochemical impedance spectroscopy ; Electrolytes ; Energy efficiency ; Mass transfer ; Multiwalled carbon nanotubes (MWCN) ; Nanofluidics ; Nanomagnetics ; Ohmic contacts ; Polysulfides ; Coulombic efficiency ; Electrochemical behaviors ; Flowing electrolytes ; Galvanostatic charge discharges ; Mass transfer resistances ; Modified multi-walled carbon nanotubes ; Nanoscale conductors ; Peak current density ; Flow batteries
  8. Source: Electrochimica Acta ; Volume 369 , 2021 ; 00134686 (ISSN)
  9. URL: https://www.sciencedirect.com/science/article/pii/S0013468620320806?via%3Dihub