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An efficient one-pot Michael addition of dithiocarbamate anion to α,β-unsaturated olefins mediated by lithium perchlorate

Ziyaei-Halimjani, A ; Sharif University of Technology | 2005

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  1. Type of Document: Article
  2. DOI: 10.1080/17415990500088997
  3. Publisher: Taylor and Francis Ltd , 2005
  4. Abstract:
  5. The reaction of substituted dithiocarbamates with electrophilic alkenes in the presence of LiClO4 was investigated in an attempt to prepare numerous ethyl dithiocarbamates bearing β-electron-withdrawing-group substituents. The reaction conditions are mild, neutral, with extremely simple work-up procedures, and offer high yield. © 2005 Taylor & Francis Group Ltd
  6. Keywords:
  7. Michael addition ; α,β-Unsaturated olefins ; Lithium perchlorate ; Carbon disulfide
  8. Source: Journal of Sulfur Chemistry ; Volume 26, Issue 2 , 2005 , Pages 149-153 ; 17415993 (ISSN)
  9. URL: https://www.tandfonline.com/doi/abs/10.1080/17415990500088997