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Novel and efficient method for the silylation of hydroxyl groups with hexamethyldisilazane (hmds) under solvent-free and neutral conditions

Azizi, N ; Sharif University of Technology | 2004

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  1. Type of Document: Article
  2. DOI: 10.1021/om0341505
  3. Publisher: 2004
  4. Abstract:
  5. Various alcohols and phenols were silylated to trimethylsilyl ethers with hexamethyldisilazane in the presence of solid lithium perchlorate under very mild, neutral, and solvent-free conditions in good to excellent yields
  6. Keywords:
  7. Ammonia ; Stoichiometry ; Solvents ; Phenols ; Lithium compounds ; Hydroxylation ; Ethers ; Catalysts
  8. Source: Organometallics ; Volume 23, Issue 6 , 2004 , Pages 1457-1458 ; 02767333 (ISSN)
  9. URL: https://pubs.acs.org/doi/10.1021/om0341505