Sharif Digital Repository

The main objective of all managers of the economic organizations, manufacturing and industrial companies and service providers is to take steps toward improvement and effective use of different resources like workforce, capital, materials, energy and information. To attain the desired productivity, managers have to observe requirements such as establishment of a working organizational structure, effective implementation methods, safe equipment and tools, balanced working atmosphere and qualified human force as the most important factor. Therefore productivity culture should be publicized throughout the organization, and human force should be considered as the main component of this process.... 

This projct includes the following sections: In the first section, Michael addition reaction of anthrone to nitroolefins is described in water without using any catalyst to prepare 9-(2-nitro-1-arylethyl)anthracene-10(9H)-ones. This method is green, efficient and gives high yields of products. The solvent effect is also investigated. In the second section, Considerable efforts have been directed in recent years towards the transition metal complex catalyzed oxidation of organic compounds such as olefins, sulfides, benzylics alcohols and phenolics. And due to the various advantages of supported heterogeneous catalysts and in our aim to develop a simple, more efficient and eco-friendly... 

Gray Cast Irons are the most important engineering Cast Irons. Gray color of fracture surface and morphology of graphite flakes are the reasons of this naming. Gray iron is relatively cheap with easy production; because of wide chemical composition range rather other cast irons. Furthermore, shrinkage and feeding in the casts from gray iron, besides surface finishing by machining are easy. The other properties of gray iron are resistance against sliding wear, high thermal conduction coefficient, low module of elasticity and thermally shock resistance. In this research, the effects of added nitrogen as an alloying element and cooling rate on microstructure, hardness and tensile properties of... 

Steel shear wall systems have been introduced as a lateral load resisting system since 1970s. Based on the designer’s choice, this system can be used with or without stiffeners. Employing stiffeners prevents the elastic buckling of steel plates which can enhance the system to absorb more energy. The design code for using stiffeners has not developed yet in Iran since this kind of systems is not common practice. In this study, the Response Modification Factor (R), as an important factor in the design procedures of structures, is investigated for 1,3,5,7 and 10-story regular and irregular building structures which have un-stiffened steel shear walls with 3, 4.5 and 6 millimeters thickness with... 

In massive construction projects such as construction of high-rise buildings, bridges, and concrete pavements, engineers strive to set up an on-site concrete batching plant; however in most cases, due to the lack of space availability, it is not possible to do so.Therefore, in order to procure high quality concrete, ready mixed concrete suppliers are sought. The notable management point is the distance between the ready mixed concrete plant and the construction site. The investigations show that the increased hauling time of ready-mixed concrete could significantly influence the quality of produced concrete. This issue is of more importance in the urban areas (e.g Tehran) as the traffic... 

Dithiocarbamates are a group of compounds that nowadays have been used extensively in pharmaceutical agents, organicsynthesis and as fungicides in agriculture.We haveshown, an efficient. regiospecific method for the synthesis of cyclic dithiocarbamates by one-pot three-component cascade reaction of an amine, CS2 and α,β-unsaturated aldehyde via Michael addition/hemiamination reaction in watre under a mild and green procedure with excellent yields and complete regioselectivity  

Crude oil is naturally not applicable to the refining processes to obtain important products. Most of the crude oil refining process produce heavy hydrocarbons that are not used much in the same way. More refineries are looking for a process to remove the heavy components and converts these materials into valuable material. There are different process for upgrading heavy residual oil. One of the main processes in residual upgrading is Delayed Coking. The high flexibility to the different feeds and no need for a catalyst, causing a shift in the approach to the refinery for processing heavy crude oil by Delayed Coking. The aim of this project is calculated the sulfur content and and yield of... 

During live broadcast of sports events (such as soccer matches), it is usually useful to provide more information to the audience by adding graphical elements to the video feed; elements such as offside line, distance to goal, and virtual advertisement. This requires to extract information about the camera; for instance, camera position, rotation, and focal length. Hence, we need a method to find the camera calibration data from the image. Previous works have focused on extracting this information based on the points on the pitch. But, that led to insufficient data for projecting 3D points which can be located outside of the pitch. In this thesis, in the preprocessing stage of the first... 

The investigations on hydrophobic surfaces have attracted lots of intrests in science and technology. Silica sols have been used extensively in the area of producing hydrophobic coatings. On the other hand, carbon-based materials have attracted of a great deal of scientific interest in recent years. The purpose of this research is synthesis and investigation on the properties of Silica- Graphene Oxide nanocomposite coating.Graphene Oxide synthesized by using Hummer’s method. Silica nanoparticles were prepared using sol-gel process and tetraethylorthosilicate (TEOS) as precursor. The surface hydroxyl groups of silica nanoparticles are replaced with Methyl groups by treatment with... 

Additive manufacturing (Simply called A.M.) is a group of manufacturing technologies that is developing rapidly and is being used widely in some industries like car manufacturing, Aerospace and producing Biomedical devices, In a way that some researchers believe that A.M. methods will change the future of manufacturing. One of the most important A.M. techniques is the Selective Laser Sintering (SLS) method that is mostly used in industrial applications. A SLS machine has a lot of sub systems and mechanisms that have key role in the Laser Sintering process. One of the mechanisms of SLS machine is the Powder Dispensing mechanism that produce layers of unsintered powder as thin as 100 microns... 

Acidizing efficiency depends on various factors such as formation properties, reservoir and stimulation fluid types and injection scenario. Among these factors, heterogeneity of reservoir’s formation (layered reservoirs and permeability variation versus depth) strongly affect acidizing performance. Accordingly, applying a reliable technique that distribute stimulation fluid uniformly is essential. The aim of carbonate matrix acidizing is to improve fluid flow specially in low permeability zones. Stimulation fluid cannot enter into the low permeability layer due to existence of high permeability layers which are in contact with low permeability ones. So, the stimulation fluid should be... 

In this study, the zirconia antistatic coating was synthesized by dip coating sol-gel route on glass substrate. The solution contains ZrCl4 as precursor and isopropanol as solvent to synthesize zirconium oxide. The effects of environmental humidity and solution concentration on the coating characterization were analyzed. MPTS and primer binder were added as binding agents in the solution to observe the effect of binding agents on the coating adhesion. Solution stability and antistatic coating characterization were analyzed by zita potential test, FTIR spectroscopy, EDX analysis, FESEM and AFM microscopy, pencil hardness test, thickness test, antidust ability and spectrophotometer. The... 

Selective Laser Sintering (SLS) is one of the powder-based Additive Manufacturing (AM) technology in which parts built by CO2 laser. In this research work, Titanium-PMMA-Stearic Acid powders are mixed together to produce parts by Indirect Metal Laser Sintering (IMLS) method. The optimum process parameters such as energy density, Percentage composition of Titanium-PMMA and Scan Sintering are obtained by adopting the Taguchi method for getting the maximum density and minimum porosity. Experiments are planned by Taguchi’s Mix-L8 orthogonal array. According to the results obtained from this study, the percentage of combination Ti-PMMA and Energy density, respectively, are a major parameters that... 

One of the most important manufacturing methods using technologies AM, is the SLS method. This method because it would significantly reduce the construction time is the ability to build a variety of materials, is pervasive. The SLS devices input is part CAD file which is then part layered, a layer of powder is poured on the bed. Each layer is defined contour on the part and then scanned by laser inner layer is hatched by laser. Scanning algorithms and hatching in the SLS is an important part of building that has an impact on properties part and a lot of research has been done about it. synthetic scan algorithms presented in this study. The purpose of this algorithm is that part warpage and... 

SiCl4 catalyzed Michael addition reaction of aliphatic and aromatic amines with different α,β- unsaturated compounds and one-pot three component Mannich reaction under solvent-free condition were investigated. β-amino carbonyl compound were synthesized in high yield in short reaction time. Furthermore, in the Mannich reaction good yield and excellent stereoselectivity were observed. In addition, the synthesis of 2-substituted benzothiazoles from aromatic aldehydes and 2 aminothiophenol in moderate to excellent yields in water in the presence of PTSA catalyst (10 mol%). This method provides a simple and efficient protocol in terms of mild reaction conditions, clean reaction profiles, small... 

Development of strategically important processes which are environmentally benign with simple methodology and work-up by low toxic material is currently reciving considerable attention.In recent years, dithiocarbamates (DTCs) and their synthesis with a green procedure have received many attention because of their undeniable applications.These synthetic compounds play important roles either in academia and industry. Here a simple, efficient and regiospecific method for synthesis of dithiocarbamates is described by one-pot three-component reaction of an amine, CS2 and alkyl vinyl ether via Markovnikov addition reaction in poly ethylene glycol (PEG) under a mild and green procedure with... 

This thesis contains two parts .In the first part a catalyst such as AlCl3/Al20 has been demonstrated to catalyze Michael addition reaction of amines to a,�- unsaturated compounds with high yields , short reaction time and under solvent-free condition.The Michael addition to a,�- unsaturated compounds produces quantitively the mono addition products.The next part is about olefins epoxidation . Alkene epoxidation is a useful reaction in organic synthesis. Epoxides play an important role in industrial intermediates for the production of fine chemicals as well as pharmaceuticals .The hydrogen peroxide has been used as an oxidant because it is considered as an economical and appropriate reagent... 

Recently, a new method to investigate chip seal performance has developed by a research team at Sharif University of Technology. This study investigates the effect of various additives such as CRM, SBR Latex, Hydrated Lime and Ordinary Portland Cement (OPC), on the curing time of chip seal by this method. In addition, the chip seal treatments were investigated in different climate conditions like Wet and Wet-Freeze zones. The overall performance of mixture specimens evaluated using creep loading test. In fact, the bonding properties between aggregates and surface of Hot Mix Asphalt measured. The test results were analyzed by using of the work and time parameters. These parameters were... 

Demand for the petroleum products is continuously increasing. Crude oil cannot be used as it is extracted, so that, there should be some treatment that may ended up producing heavy hydrocarbons. Therefore, refineries are searching for developing new technologies for upgrading those heavy materials and convert more and more bottom-of-the-barrel into high value distillate. Amongst the different residua upgrading processes, thermal upgrading processes are of the most interest and account for over 60% of total residua processing capacity. In this work, we investigate the effect of different additives in a delayed coking process. We used vacuum distillation residue of Abadan heavy crude oil... 

Dental implants should be biocompatible. This ability cause bone growth beside implant and increases stability of implant. Manufactoring method and materials used in implants are main parameters affectig biocompatibility of implants. Fabrication of functionally graded structures is a novel method to increase biocompatibility. Stress shielding is one of the main causes of failures in current dental implants. This phenomenon takes place due to different young modulus of dental implants and host bone. Pouros structures remedial this problem and implant’s young modulus comes closer to host bone. The aim of this project is to study feasibily of fabrication of functionally graded titanium dental...