Sharif Digital Repository

Nowadays a major part of energy, fresh water and sewer water in over the world are transmitted by buried pipe, and always these lines are under the loads and different stresses such as corrosion, earth quick and etc.
In many countries the age of these lines are more than 30 years which causes corrosion of the pipe wall and the necessity of health investigating of transmission lines has a special importance for the governments and leak detection can also keep the natural environment healthyand the costs will come down significantly, scientists and researchers have always tried different ways to check the health of the pipes.
In the field of leak detection and the problems of age... 

Most of the investigations during the two past decades focused on the effect of moisture and temperature on the bond at the interface of carbon or glass-fabrics and concrete, masonry or timber. Few investigations have studied the effect of chemical solutions, dry heat exposure and ultravilolent (UV) radiation on the bond at the interface of other types of fiber reinforced-polymers (FRPs) and masonry, timber and concrete in the short and long terms. Therefore, this research aims to investigate the effect of five chemical solutions with pH of 2.5±0.1, 7±0.1, 7.25±0.1, 10±0.1 and 12.5±0.1 on the interfacial bond strength between seven types of FRPs (unidirectional, bidirectional and hybrids)... 

The subject of this thesis to assessment environmental impacts of active desalination plants in Kish Island, which explains the problems derived from concentrate discharges in to the sea, sewage network, absorbing wells and ground surface.
It also studies its impacts on land and marine ecosystem and underground aquifers that are strategic resources in Kish Island. In addition, the environmental studies done in other countries, the existing regulations and by laws in the field of environmental impacts of desalination plants and concentrate discharges are re-mentioned. Concentrates contain chemicals, which are used in pre-filtration of MED and Ro systems, which are dangerous for marine... 

In this research, the technology of fabrication and deposition of nanoparticle inks from chalcogenide compounds and then use of them in the fabrication of CuInGaS2 and Perovskite thin-film solar cells have been considered. In the first step, the synthesis of CuInGaS2 family compounds with variable In / Ga ratio and also the change of the stoichiometric ratio of Cu component using oleylamine solvent is investigated. In addition to these compounds, the synthesis of CuSnS, CuBaSnS, and CuZnSnS nanoparticles is also investigated. The synthesized nanoparticles were analyzed by XRD, DLS, UV-Vis, ICP, PL, SEM, EDX, and TEM. Then, the stability of the ink made of CuInGaS2 nanoparticles in different... 

Nowadays, beside of two-dimensional tungsten disulfide nanosheets, its hybrid nanostructures also provide active sites for physisorption of gas molecules due to their high surface-to-volume ratio, surface active site (such as sulfur vacancies, surface defects, and p-n junctions) and active edges, and are very attractive for gas sensing applications. In this research, tungsten disulfide layered crystallines were grown by chemical vapor phase transport and its two-dimensional nanoflakes were prepared by liquid exfoliation method. So, a thin film of the nanoflakes was deposited on a silicon oxide substrate by drop casting method, and its gas sensing properties were investigated for water and... 

A global concern has arisen owing to rapid industrial development and population growth, resulting in energy scarcity and earth pollution. In this regard, developing green and sustainable methods for producing clean energy and solving environmental pollution problems have absorbed enormous attention. Among various auspicious strategies, semiconductor photocatalysis has been widely studied in recent years owing to its capabilities to obtain hydrogen as an energy carrier, to remove organic pollutants, and to reduce CO2 emission by converting solar energy into chemical energy. Recently, a metal-free semiconductor photocatalyst based on graphitic carbon nitride, g-C3N4, has received much... 

Titanium trisulfide (TiS3), a transition metal chalcogenide, bears the potential to replace silicon, when taking the form of nanoflakes, due to its favorable band gap and optical response. In this work, first we investigate the response of TiS3 nanoflakes to gas detection through a careful quantum computational approach and a few succinct measurements. The computations are benchmarked and compared with a relevant experiment at each step, where their results/conclusions are discussed. The most stable surface of TiS3 particles is determined to (001), in agreement with the literature. The adsorption of 5 gas molecules is characterized through formulating and estimating their adsorption... 

Molybdenum disulfide (MoS2) nanoflakes, a two-dimensional crystal with tunable bandgap depends on number of layers, is a promising candidate for future nanoelectronic devices. In the present research, flower shaped MoS2 nanoflakes have been synthesized via hydrothermal method. As part of the research, the growth of triangular MoS2 monolayer up to 10 micrometers has optimized by carring out several chemical vapor deposition experiments with varying deposition parameters. The prepared samples were characterized using optical, scanning electron, and atomic force microscopes, x-ray diffraction analysis, and Raman spectroscopy. Based on the experimental results, the growth mechanism has been... 

Aseptic loosening and infection are two major problems of bone implants. Aseptic loosening occurs due to poor cell growth and poor adhesion to the implant surface over time. Bone infection at the implant site occurs mainly by the staphylococcus aureus bacteria. In some cases, infection occurs in the short term and in the early times after implantation, and in some cases, infection occurs in later times. The aim of this study is to synthesize and evaluate antibacterial coatings, while having cell growth-promoting components and cell differentiation to solve bone implant problems simultaneously. Also, the issue of bacterial resistance to antibiotics and their risks in bone implants is another... 

Experimental studies of regular cell structure of a weak detonation wave in a gaseous mixture of hydrogen and oxygen diluted with argon have shown that for a constant initial thermodynamic condition, the final cell size differs by repeating the tests. The question is that if these different final cell sizes for a constant initial condition are because of test errors, or the experiments would lead to a domain of solution in the form of different final cell sizes? Therefore, the aim of this study is to investigate, numerically, the evolution process and domain of variation of cellular structure of a weak detonation, and their dependency to unstable wavelengths obtained from linear instability... 

One of the most important world issues is environmental constraints regarding the pollutants released by transportation fuels and refinery products, sulfur reduction being one of the most significant objectives. Deep hydrodesulfurization processes result in great sulfur reduction in refinery streams. However, such harsh process conditions increase undesired side reactions and facilitate coke formation as well as affecting the surfaces. More effective alternatives for hard process conditions are highly active and selective hydrodesulfurization catalysts, which enable the process to be performed at milder pressure and reaction conditions. Catalyst bases play a very important role in hydrogen... 

In this project, two types of graphene obtained from chemical and chemical vapor deposition (CVD) methods were studied for gas/vapor sensing applications . In chemical method, oxidation and exfoliation of graphite was performed in liquid phase. AFM, XPS, Raman spectroscopy and Uv-visible spectroscopy were indicated that single layers synthesis of graphene oxide (GO) sheets was formed successfully. Reduction of the GO to reduced graphene oxide (RGO) was chemically done by hydrazine as a conventional reducing agent and melatonin as a green alternative. Photocatalytic reduction and hybridization of GO with TiO2 was also studied. TEM, SEM and AFM analyses confirmed nucleation and growth of TiO2... 

In this research we focus on fabrication, characterization and performance of biosensors based on vertically aligned carbon nanotubes. Carbon nanotubes have been used as high density carbon nanotubes and nanoelectrode array. Carbon nanotubes have been grown using plasma enhanced chemical vapor deposition method. Characterization and performance of biosensors have been studied by cyclic voltammetry and electrochemical impedance spectroscopy methods.
The mediator-less glutamate biosensor is prepared based on covalently attached glutamate dehydrogenase on vertically aligned carbon nanotubes. The biosensor has a low detection limit of 57 nM, two linear range of 0.1-20 µM with sensitivity of... 

Considering the operation of the current nuclear reactors and the country's policy to achieve 10,000 megawatts of nuclear power in the horizon of 1420, as well as the construction of research reactors, we will face a huge amount of radioactive waste in the coming years. Meanwhile, spent ion exchange resins constitute a large amount of low and intermediate level (LILW) solid radioactive waste produced from the nuclear industry. Therefore, appropriate precautionary measures should be taken for the immobilization and disposal of these radioactive wastes in order to ensure the sustainable development of the nuclear industry and the protection of the environment and human health. In this study,... 

As nuclear energy continues to be used as a useful energy resource, waste management, especially management of high-level nuclear waste (HLW), will always be a major concern, as the future generations should not be deprived of the valuable benefits of this energy. Vitrification of liquid high-level radioactive waste (HLW) has received greater attention, worldwide, than any other high-level waste solidification process. The high solubility of HLW in borosilicate glass, the controllable temperature of this type of glass and its low leaching rate in repository environment, have introduced borosilicate glass as a suitable host for HLW immobilization. In this project, the immobilization of the... 

In this study graphene and graphene adsorbent for the Co2+ ion were created from sodium phenoxide and calcium phenoxide, respectively, using the chemical vapor deposition method, and their chemical, physical, and morphological properties were investigated using FT-IR, UV, XRD, Raman, TEM, FE-SEM, and XPS. The results suggest that the optimum reaction condition for synthesizing mono-layer and multi-layer graphene is the 750 °C temperature for 30 min. The Co2+ adsorbing properties of the synthesized graphene adsorbent from calcium phenoxide was investigated. The investigation of solvation properties suggests insolubility above 650 °C and the kinetic data suggest the rapidness of the Co2+... 

1H-MRS thermometry as one of MRI thermometry methods, provides useful information about the distribution of the absolute temperature of tissue that can be used in diagnostic and therapeutic applications. It seems that the magnetic field inhomogeneity and the reduction of spectra resolution also affects the accuracy of MRS thermometry. To our knowledge, effects of magnetic field inhomogeneity on MRS thermometry has never been reported. In this study, we evaluated the effect of susceptibility inhomogeneity on MRS thermometry. In the first stage, MRS thermometry equation was derived in the presence of field inhomogeneity. Then simulation used for estimate the effect of filed inhomogeneity based... 

In this study, simultaneous production of bioelectricity and algal biomass, wastewater treatment and carbon dioxide capturing in an Algal-Cathode Photosynthetic Microbial Fuel Cell has been evaluated. The performance of the system under different light intensity (3500, 5000, 7000 and 10000 lux) and also different light:dark regime (24:00, 12:12 and 8:16 hour) has been studied. The results show that, light intensity has direct effects on performance of Photosynthetic Microbial Fuel Cell (PMFC) with changing dissolved oxygen in biological cathode. So, the PMFC can reach power density of 125.96 mW/m3 with optimized light intensity of 5000 lux and simultaneously columbic efficiency and COD... 

Natural boron includes two stable isotopes 10B and 11B with 19.3 and 80.7 weight percent respectivley.10B isotope has a high thermal neutron absorption cross section. So isotope 10B material is suitable for making atomic reactor control rods. Other and even more important applications of 10B are in disclosing neutrons in order to measure neutron reactors fluxes and also are in nuclear physics laboratories and medical radiation. This isotope also is used in the pharmaceutical and the military industries. There are several methods for separating boron isotopes. Among the distillation methods, thermal diffusion of BF3, distillation of BF3, distillation of methyl borate, boric acid distillation...