Sharif Digital Repository

Nitrogen has emerged as a competitive gas injection alternative for gas-based enhanced oil recovery processes in the past two decades. The injection of nitrogen into the reservoirs has improved the oil recovery efficiency in various oil reservoirs from heavy to volatile oils. As it is known, interfacial tension (IFT) plays a key role in any enhanced oil recovery process, particularly gas injection processes; therefore, its accurate determination is crucial for the design of any gas injection process especially at reservoir condition. In this study, an axisymmetric drop shape analysis (ADSA) was utilized to measure the equilibrium IFTs between crude oil and N2 at different temperature levels... 

There are different thermodynamic models that have been applied for modelling of asphaltene precipitation caused by various reasons, such as solvent/CO2 injection and pressure depletion. In this work, two computer codes based on two different asphaltene precipitation thermodynamic models-the first being the thermodynamic micellization model with a different characterization approach and the second being the solid model-have been developed and used for predicting asphaltene precipitation data reported in the literature as well as in the obtained data for Sarvak reservoir crude, which is one of the most potentially problematic Iranian heavy oil reserves under gas injection conditions. For the... 

Water and miscible gas injection scenarios are considered in an Iranian oil reservoir for the purpose of recovery improvement. Firstly reservoir fluid modeling and modeling of a slim tube test were performed. Then, water alternating gas (WAG) injection was evaluated by optimizing the WAG half cycle and WAG ratio. Alternatively, hybrid WAG and separate injection of water and gas in the top and bottom of the reservoir were also investigated. The numerical simulation results showed that the optimum WAG, with half cycle of 1.5 years and WAG ratio of one, gave the highest recovery factor. Moreover, economic evaluation of these scenarios indicated that WAG had the highest net present value and was... 

In this work, a thermodynamic approach is used for modeling the phase behavior of asphaltene precipitation. The precipitated asphaltene phase is represented by an improved solid model, and the oil and gas phases are modeled with an equation of state. The Peng-Robinson equation of state (PR-EOS) was used to perform flash calculations. Then, the onset point and the amount of precipitated asphaltene were predicted. A computer code based on the solid model was developed and used for predicting asphaltene precipitation data reported in the literature as well as the experimental data obtained from high-pressure, high-temperature asphaltene precipitation experiments performed on Sarvak reservoir... 

Typical non-hydrocarbon gases, which have been utilized in miscible and immiscible processes, are carbon dioxide and nitrogen. These gases are usually injected separately and have been rarely utilized together as a tertiary recovery process. In this article, the authors have experimentally focused on sequential carbon dioxide and nitrogen gas injection as a new enhanced oil recovery method. The periodic injections of carbon dioxide and nitrogen have been repeated for six injection pore volumes. Sensitivity analysis of injection pressure, injection volume, and injection rate has also been investigated in core flood experiments. The experimental results have revealed that a sequential miscible... 

Asphaltene precipitation problems manifest themselves in different stages of oil reservoirs production. Experimental and modeling investigations are, therefore, employed as promising tools to assist in predictions of asphaltene precipitation problems and selection of proper production facilities. This study concerns experimental and modeling investigations of asphaltene precipitation during natural production and gas injection operations for a heavy Iranian crude oil at reservoir conditions. First, with design and performance of high pressure-high temperature experiments, asphaltene precipitation behavior is comprehensively investigated; the effects of pressure and temperature are fully... 

The use of water-alternating-gas injection can potentially lead to improved oil recovery from the fields; simultaneous water and gas injection is a form of water-alternating-gas injection. However, there is still an incomplete understanding of these processes and the need for comparative work is inevitable. Core flood experiments and compositional simulations of water-alternating-gas and simultaneous water and gas processes are presented. Immiscible, near miscible, and miscible modes of injection are covered. Matching process is done and optimization of design parameters (injection rate, slug size, water-alternating-gas ratio, and injection gas) is performed. Experimental data demonstrate... 

Multiple contact miscible floods such as injection of relatively inexpensive gases into oil reservoirs are considered as well-established enhanced oil recovery (EOR) techniques for conventional reservoirs. A fundamental factor in the design of gas injection project is the minimum miscibility pressure (MMP), whereas local sweep efficiency from gas injection is very much dependent on the MMP. Slim tube displacements, and rising bubble apparatus (RBA) are two main tests that are used for experimentally determination of MMP but these tests are both costly and time consuming. Hence, searching for quick and accurate mathematical determination of gas-oil MMP is inevitable. The objective of this... 

Crude oil reservoirs have different temperatures, compositions, and pressures, therefore oil recovery performance by CO2 injection varies from one case to another. Furthermore, it is predicted that lower interfacial tension between injected CO2 and reservoir fluid results in more oil recovery. In this study, we investigate the effect of temperature on the equilibrium interfacial tension between CO2 and three different oil fluids at different pressures. Also minimum miscible pressure (MMP) is measured by the vanishing interfacial tension (VIT) technique to determine the temperature effect on the CO2 miscible gas injection. The results on different pure and mixtures of hydrocarbon fluids show... 

CO2 injection is a potentially viable method of enhanced oil recovery for medium oil reservoirs. The authors compare the effect of gas injection strategy (simultaneous water-alternating gas [SWAG], water-alternating gas [WAG], and continuous gas injection [CGI]) on recovery in immiscible, near-miscible, and miscible modes of injection. It has been proved that CGI is not the most efficient injection scenario in oil-wet reservoirs. Miscible and near-miscible core flood tests demonstrated high oil recoveries in all injection strategies due to high capillary numbers achieved as a result of miscibility. The fluid mechanics of floods were discussed using pressure drop data, different mechanics was... 

The objective of this study was to experimentally investigate the performance of water-alternating gas (WAG) injection in one of Iran's oil reservoirs that encountered a severe pressure drop in recent years. Because one of the most appropriate studies to evaluate the reservoir occurs generally on rock cores taken from the reservoir, core samples drilled out of the reservoir's rock matrix were used for alternating injection of water and gas. In the experiments, the fluid system consisted of reservoir dead oil, live oil, Co 2, and synthetic brine; the porous media were a number of carbonate cores chosen from the oilfield from which the oil samples had been taken. All coreflood experiments were... 

Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate the effects of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples have been studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Extensive published data from the literature are also used in model development. The scaling approach is attractive because it is simple and... 

In this study, the main recovery mechanisms behind oil/water/gas interactions during the water-alternating-gas (WAG) injection process, in a network of matrix/fracture, were fundamentally investigated. A visual micromodel was utilized to provide insights into the potential applications of WAG process in fractured oil-wet media as well as the possibility of observing microscopic displacement behavior of fluids in the model. The model was made of an oil-wet facture/matrix network system, comprised of four matrix blocks surrounded with fractures. Different WAG injection scenarios, such as slug arrangements and the effects of fluid injection rates on oil recovery were studied. A new equation... 

This paper investigates the efficiency and performance of several of the fiooding techniques popular in secondary and enhanced oil recovery. These processes include water fiooding, immiscible and miscible gas fiooding, and several forms of water-alternating-gas (WAG) injection. The study is carried out numerically on a typical one-dimensional domain using an advanced high-resolution central scheme. Some performance indices such as oil cut drop, breakthrough time, and sweep efficiency were employed to evaluate the appropriateness of each injection strategy  

Precipitation, aggregation, and breakup of asphaltene particles are studied under natural depletion and nitrogen injection processes by means of high pressure filtration and a photographic procedure coupled with image analysis. Filtration results show that nitrogen destabilizes asphaltenes extremely, and the problem is more severe for heavier crude samples. Bimodal histograms of particle size distribution show two agglomeration mechanisms: cluster aggregation dominant around bubble point pressure and diffusion limited far away. The fractal structure of aggregates is also altered by gas injection; it is observed that the flocculent masses grow in size and become more compact and organized... 

Asphaltene instability is one of the major problems in gas injection projects throughout the world. Numerous models have been developed to predict asphaltene precipitation; The scaling equation is an attractive tool because of its simplicity and not involving complex properties of asphaltene. In this work, a new scaling model is presented to account for asphaltene precipitation due to gas injection at reservoir conditions. Extensive published data from literature have been used in model preparation. To check predictive capability of the equation, miscible gas injection experiments are conducted for a southwest Iranian oil reservoir. Experimental results show that methane injection has... 

Carbon dioxide miscible flooding has become a popular method for Enhanced Oil Recovery (EOR) because it not only efficiently enhances oil recovery but also considerably reduces green house gas emissions. However, it can significantly cause asphaltene deposition, which leads to serious production problems such as wettability alteration, plugging of the reservoir formation, blocking the transportation pipelines, etc. It is crucial to investigate the effects of different factors on asphaltene deposition. A novel experimental setup was prepared to employ a high-pressure visual cell for investigation of asphaltene deposition on a model rock under typical reservoir conditions. The evolution of... 

This work concerns with experimental investigation of CO2 WAG injection to light crude oil in near miscible conditions which has been rarely attended in the available literature. Here, several core flood experiments at three constant injection rates and four WAG ratios are conducted on sandstone rocks saturated with light crude oil in presence of saline water. The results showed that higher injection rate has a better performance regarding oil recovery for smaller PVs of injected fluids, while lower injection rate showed higher ultimate recovery for a 30% increase in injected PVs. Secondary continuous gas injection showed a superior performance than all the other WAG injections in different... 

Immiscible gas injection is one of the most common enhanced oil recovery methods used under various reservoir conditions. In this work, the immiscible recycle gas injection, as an EOR scenario for improving recovery efficiency in one of the south-west Iranian oil reservoirs, is simulated by a commercial simulator, ECLIPSE. The reservoir fluid is light oil, with an API of 43. The oil bearing formations are carbonate, and so a dual porosity/dual permeability behavior was chosen for better representation of the fracture system. Different sensitivity analyses with respect to several parameters like the number and location of injection/production wells, production/injection rate, completion... 

Asphaltene precipitation during natural depletion and miscible gas injection is a common problem in oilfields throughout the world. In this work, static precipitation tests are conducted to investigate effect of pressure, temperature and gas type and concentration on asphaltene instability. Three different oil samples are studied under reservoir conditions with/without nitrogen and methane injection. Besides applying common thermodynamic models, a new scaling equation is presented to predict asphaltene precipitation under HPHT gas injection. Published data from literature are also used in model development. The scaling approach is attractive because it is simple and complex asphaltene...