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helium
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An Economic Approach To Study & Optimization of Helium liquefier
, M.Sc. Thesis Sharif University of Technology ; Afshin, Hossein (Supervisor)
Abstract
Gas liquefaction is one of the main applications of Cryogenics science. Due to the unique properties of Helium, it is a strategic product in the world. Therefore, appropriate and applicable analysis should be used to investigate and optimize the Helium liquefaction cycles. In the current study, the goal is to find the optimal point with the help of energy and exergy analysis based on economic criterion, for the various parameters of Collins’ cycle. In order to simulate the cycle, a computer code is developed. First, sensitivity analysis of different parameters affecting the exergy efficiency and liquid fraction of the cycle has been done. Then, Artificial Neural Network and Genetic Algorithm...
Design and Optimization of Helium Recovery Process from Natural Gas
, M.Sc. Thesis Sharif University of Technology ; Afshin, Hossein (Supervisor) ; Farhanieh, Bijan (Co-Supervisor)
Abstract
Helium is a valuable substance that is widely used in industry and medicine because of its unique properties. Due to the increasing demand for helium in the global market, several helium extraction units have been launched in the world in recent years; Nevertheless, there is still a significant gap between projected global helium production capacity and demand. Today, natural gas is known as the main source of helium on the earth. The method of industrial extraction of helium from natural gas is cryogenic. Due to the low temperature of this process, relatively high power consumption is used to extract helium from natural gas. Therefore, the optimization of this process is of great...
Synthesis of Graphene Oxide and Graphene Oxide Membrane for Separation of Gas Mixtures
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Sirus (Supervisor) ; Karimi Sabet, Javad (Supervisor) ; Mousavi, Abbas (Co-Advisor)
Abstract
Thin film graphene oxide(GO) membranes have been promising potential for gas purification due to thin lamellar microstructure, stable a few atom thick layers and very short intersheet distances. In this research, the nanoporous graphene oxide membranes have been prepared by vacuum and pressurized ultrafiltration on the modified polyacrylonitryle(mPAN) sublayer for helium separation from Nitrogen and carbon dioxide gas mixture. The separation performance of synthesized GO membrane was controlled by varying parameters such as concentration of stabilized aqueous GO solution, pores size range of support and its surface properties, centrifuge time, applied pressure after synthesis, humidity,...
One Dimensional Numerical Solution of Pulsating Flow in a Pulse Tube Cycle Considering Real Gas Behavior
, M.Sc. Thesis Sharif University of Technology ; Saidi, Mohammad Hassan (Supervisor) ; Kazemzade Hannani, Siamak (Co-Advisor)
Abstract
Helium gas is the working fluid in common Pulse Tube Refrigerators (PTRs) due to its brilliant properties in reaching cryogenics temperature as low as 4 K. Generally ideal gas equation of state has been used to evaluate thermodynamic performance of He. However using ideal gas equation of state for He in 10 bar and 5 K causes considerable error on estimation of density. The objective is to use real gas equation of state for temperatures near zero Kelvin. This approach makes an accurate prediction of PT cooling capacity and COP. In this thesis the objective is to realize the most relevant equations of state describing the proper behavior of He in the regions of operating point of PTR. Later on...
The Modeling of Hydrogen Purification and Carbon Dioxide Capture by two Dimensional Porous Membranes Using Molecular Dynamicssimulations
, M.Sc. Thesis Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
Carbon dioxide is one of the most significant greenhouse gases in biocycle. This gas makes the equilibrium temperature by absorbing IR radiations on the earth. It is the reason that prevent the earth from freezing. Increasing CO2 emissions in atmosphere, makes problems such as global warming. According to the Kyoto Protocol, all the countries attended to this protocol, must decrease greenhouse gases emissions. Although H2 fuel is one of the best alternative fuel against fossil fuels, the most important industrial process (steam-methane reforming) produce CO2 as by-product. Thus, gas separation has a prominent role in industrial processes such as CO2 capture and H2 purification.Today, gas...
Design and Simulation of Cryogenic Spiral Heat-exchanger for Gas Liquefaction Plant
, M.Sc. Thesis Sharif University of Technology ; Afshin, Hossein (Supervisor)
Abstract
Heat exchangers are one of the most important components used in liquefaction cycles and overall efficiency of the cycle mainly depends on the heat exchangers effectiveness. It has been shown that the effectiveness of these equipments should be high enough to be able to liquefy a gas. Spiral heat exchangers are used frequently in cryogenic industry and specially in Helium liquefaction industry due to their specific characteristics, however according to literature review it turns out that little study is done in the field of simulation and geometrical parameter investigation of these kind of heat exchangers, so in this study the design and simulation of these cryogenics heat exchangers are...
A Numerical Model Development for Cryogenic Spiral Wound Heat Exchanger Design Considering Temperature dependent thermo-physical properties, Heat Leakage, and Longitudinal Heat Conduction
, M.Sc. Thesis Sharif University of Technology ; Afshin, Hossein (Supervisor)
Abstract
Cryogenic temperature is below than 123 Kelvin and any physical study that occurs below this temperature is Cryogenic science. Cryogenic has varaiety of application in medical, industry, food, oil and gas etc. Based on this paper and its relavant source spiral wound HE is one of the most optimum HE for cryogenic application specially for helium liquification cycle. In order to liquefy helium in helium cycle efficiency of spiral wound HE shall be over than 85 percent. For this reason and special fluid behavour in low temperature considering property variation, heat in leak and axial conduction is vital for calculating efficiency in cryogenic temperature of helium liquification cycle. In this...
Study of Effective Parameters on Helium Liquefaction Cycle using Exergy Analysis
, M.Sc. Thesis Sharif University of Technology ; Afshin, Hosein (Supervisor)
Abstract
Liquefaction of gases is one of the applications of cryogenic science. Among the gases, Helium has the lowest boiling point, which at a pressure of 1atm is approximately 4.2K. Liquid helium can be used to cool superconductors in transportation equipment, military radars, and medical imaging equipment. For helium liquefaction, various cycles are used; these cycles have different parameters in their structure such as of input mass fraction to expanders, heat exchanger effectiveness, expander arrangement and ... which their analysis for improving the performance of the cycle is important. In this research, the aim is to study 2, 3 and 4 expander cycle with various parameters and structure. For...
Design and Optimization of Helium Extraction and Liquefaction Cycle from Natural Gas by Direct Method
, Ph.D. Dissertation Sharif University of Technology ; Afshin, Hossein (Supervisor)
Abstract
Helium is known as a strategic material due to its unique properties and applications in the development of advanced industries. Currently, natural gas is the only source from which helium can be produced economically. The United States, Qatar, Algeria, and Russia have the largest share of helium production, respectively. In this research, the process of helium extraction from natural gas and its liquefaction, independent of LNG production based on helium in South Pars gas of Iran, which is the largest helium reservoir in the world, were designed and simulated.In the helium liquefaction section, the speed and accuracy of the process simulation were improved by developing a home code based on...
Three Dimensional Simulation and Experimental Modeling of Two Stage GM Type Pulse Tube Refrigeration with Double-Inlet
, M.Sc. Thesis Sharif University of Technology ; Saidi, Mohammad Hassan (Supervisor)
Abstract
There are numerous ways available to achieve low temperatures that cryocoolers might be among the most important of them. In the meantime, the pulse tube refrigerator has a special place due to its simple geometry and not be using any moving parts. This simple property make the pulse tube refrigerator one of the most popular methods to achieve low temperatures. Nowadays, a pulse tube refrigerator is used for cooling in the range of 4 to 123 Kelvin in two form of one-stage and two-stage and up to an approximate power of 1 KW. Today, due to the temperature and the amount of power required for cooling, as well as the time it takes to reach that temperature, this chiller is used in medical,...
Automated trace determination of earthy-musty odorous compounds in water samples by on-line purge-and-trap-gas chromatography-mass spectrometry
, Article Journal of Chromatography A ; Volume 1136, Issue 2 , 2006 , Pages 170-175 ; 00219673 (ISSN) ; Lacorte, S ; Bagheri, H ; Barceló, D ; Sharif University of Technology
2006
Abstract
An automated technique based on purge-and-trap coupled to gas chromatography with mass spectrometric detection has been developed and optimized for the trace determination of five of the most important water odorants; 2-isopropyl-3-methoxypyrazine, 2-isobutyl-3-methoxypyrazine, 2-methylisoborneol, 2,4,6-trichloroanisole and geosmin. The extraction method was absolutely solvent-free. Analytes were purged from 20 ml of water sample containing sodium chloride at room temperature by a flow of He and trapped on a Tenax sorbent. The desorption step was performed with helium and temperature programming and desorbed analytes were directly transferred to a gas chromatograph coupled to a mass...
Observation of quasi mono-energetic electron bunches in the new ellipsoid cavity model
, Article Laser and Particle Beams ; Volume 27, Issue 2 , 2009 , Pages 223-231 ; 02630346 (ISSN) ; Navid, H. A ; Zobdeh, P ; Sharif University of Technology
2009
Abstract
In this work, we introduce a new ellipsoid model to describe bubble acceleration of electrons and discuss the required conditions of forming it. We have found that the electron trajectory is strongly related to background electron energy and cavity potential ratio. In the ellipsoid cavity regime, the quality of the electron beam is improved in contrast to other methods, such as that using periodic plasma wakefield, spherical cavity regime, and plasma channel guided acceleration. The trajectory of the electron motion can be described as hyperbola, parabola, or ellipsoid path. It is influenced by the position and energy of the electrons and the electrostatic potential of the cavity. In the...
Numerical study of species separation in rarefied gas mixture flow through micronozzles using DSMC
, Article Physics of Fluids ; Volume 31, Issue 4 , 2019 ; 10706631 (ISSN) ; Darbandi, M ; Sharif University of Technology
American Institute of Physics Inc
2019
Abstract
This work investigates the species separation in the rarefied flow of the argon-helium mixture through convergent-divergent micronozzles. Imposing a molecular mass ratio in the order of 10, the flow of this mixture can lead to the formation of serious nonhomogeneous phenomena such as the species separation. This study is performed in the ranges of 2.0-4.0 for the geometrical expansion ratio, 200-400 K for the wall temperature, and 0.003-1.454 for the inlet Knudsen number. The effects of these parameters are examined on the separative performances of micronozzle. The direct simulation Monte Carlo method is selected as the solution method because it can provide reliable solutions in the...
Improving mixed-matrix membrane performance: Via PMMA grafting from functionalized NH2-UiO-66
, Article Journal of Materials Chemistry A ; Volume 6, Issue 6 , 2018 , Pages 2775-2791 ; 20507488 (ISSN) ; Shojaei, A ; Mousavi, S. A ; Sharif University of Technology
Royal Society of Chemistry
2018
Abstract
The major obstacles in gas separation by mixed-matrix membranes (MMMs) are poor dispersion and poor affinity between polymers and fillers. The present study demonstrates that these challenges can be overcome appropriately by utilizing a series of synthesized stand-alone MMMs. The matrix used was polymethyl methacrylate (PMMA) and the MMMs were synthesized by in situ polymerization of methyl methacrylate (MMA) in the presence of UiO-66, NH2-UiO-66 and vinyl group attached UiO-66. In situ polymerization of MMA in the presence of vinyl attached UiO-66 resulted in PMMA grafted UiO-66 with a high degree of grafting. Microscopic analysis by field emission scanning electron microscopy (FESEM)...
Synthesis and characterization of pure metallic titanium nanoparticles by an electromagnetic levitation melting gas condensation method
, Article RSC Advances ; Vol. 4, issue. 14 , 2014 , pp. 7104-7108 ; ISSN: 20462069 ; Halali, M ; Sharif University of Technology
Abstract
Pure titanium nanoparticles were synthesized by utilizing an Electromagnetic Levitation Melting Gas Condensation (ELM-GC) method. Pure bulk titanium samples were melted and evaporated by electromagnetic levitation technique in an inert gas atmosphere in a silica tube. Titanium nanoparticles were formed from ascending vapor by employing high purity argon and helium as carrier gases and cooling agents. Particle size and morphology of the produced nanoparticles were studied by Field-Emission Scanning Electron Microscopy (FE-SEM) and Dynamic Light Scattering (DLS) analysis. Results showed almost spherical nanoparticles with a narrow size distribution under both cooling atmospheres. The purity of...
Studying dynamic pull-in behavior of microbeams by means of the homotopy analysis method
, Article 2008 ASME International Mechanical Engineering Congress and Exposition, IMECE 2008, Boston, MA, 31 October 2008 through 6 November 2008 ; Volume 13, Issue PART A , 2009 , Pages 129-135 ; 9780791848746 (ISBN) ; Tajalli, S. A ; Ahmadian, M. T ; Sharif University of Technology
2009
Abstract
In this study, the homotopy analysis method (HAM) is used to study dynamic pull-in instability in microbeams considering different sources of nonlinearity. Electrostatic actuation, fringing field effect and midplane stretching causes strong nonlinearity in microbeams. In order to investigate dynamic pull-in behavior, using Galerkin's decomposition method, the nonlinear partial differential equation of motion is reduced to a single nonlinear ordinary differential equation. The obtained equation is solved analytically in time domain using HAM. The problem is studied by two separate manners: direct use of HAM and indirect use of HAM in conjunction with He's Modified Lindstedt- Poincaré Method....
Production of silver nanoparticles by electromagnetic levitation gas condensation
, Article Chemical Engineering Journal ; Volume 168, Issue 1 , March , 2011 , Pages 441-445 ; 13858947 (ISSN) ; Halali, M ; Sharif University of Technology
2011
Abstract
Electromagnetic levitation gas condensation (ELGC) method was used to synthesize silver nanoparticles (NPs). Silver droplets were melted and levitated stably at about 1130°C with appropriate flat coils in a 10mm OD silica tube. High purity argon, nitrogen and helium were employed as carrier gases and cooling media. Morphology and particle size of the products were investigated by scanning and transmission electron microscopy (SEM and TEM), X-ray diffraction (XRD), energy dispersive X-ray analysis (EDAX) and dynamic light scattering (DLS). The DLS, SEM and TEM studies demonstrated narrow size distribution of spherical shape silver NPs with mean particle size of about 60, 50 and 30nm...
Investigation of effective parameters on the performance of the helium liquefaction cycle
, Article International Journal of Heat and Technology ; Volume 37, Issue 4 , 2019 , Pages 1009-1018 ; 03928764 (ISSN) ; Eslami, M ; Afshin, H ; Sharif University of Technology
International Information and Engineering Technology Association
2019
Abstract
Due to its unique properties, helium has wide application in different industries and scientific fields, which has turned it into a strategic material. Helium liquefaction plants include wide temperature range from 300 k to 4.2 k, so these plants have high energy consumption. A lot of studies have done to optimize the operation of these cycles. In this research, an exergy analysis is performed for a liquid helium production plant. The optimal performance of 3 and 4 stage cycles is extracted using parametric study and the results are compared with those of Collins dual-expander cycle. The results show that by increasing the number of cooling stages, not only the compressor optimum discharge...
Investigation of effective parameters on the performance of the helium liquefaction cycle
, Article International Journal of Heat and Technology ; Volume 37, Issue 4 , 2019 , Pages 1009-1018 ; 03928764 (ISSN) ; Eslami, M ; Afshin, H ; Sharif University of Technology
International Information and Engineering Technology Association
2019
Abstract
Due to its unique properties, helium has wide application in different industries and scientific fields, which has turned it into a strategic material. Helium liquefaction plants include wide temperature range from 300 k to 4.2 k, so these plants have high energy consumption. A lot of studies have done to optimize the operation of these cycles. In this research, an exergy analysis is performed for a liquid helium production plant. The optimal performance of 3 and 4 stage cycles is extracted using parametric study and the results are compared with those of Collins dual-expander cycle. The results show that by increasing the number of cooling stages, not only the compressor optimum discharge...
Ballistic molecular transport through two-dimensional channels
, Article Nature ; Volume 558 , 20 June , 2018 , Pages 420-423 ; 00280836 (ISSN) ; Geim, A. K ; Janardanan, A ; Rooney, A. P ; Esfandiar, A ; Hu, S ; Dar, S. A ; Grigorieva, I. V ; Haigh, S. J ; Wang, F. C ; Radha, B ; Sharif University of Technology
Nature Publishing Group
2018
Abstract
Gas permeation through nanoscale pores is ubiquitous in nature and has an important role in many technologies 1,2 . Because the pore size is typically smaller than the mean free path of gas molecules, the flow of the gas molecules is conventionally described by Knudsen theory, which assumes diffuse reflection (random-angle scattering) at confining walls 3-7 . This assumption holds surprisingly well in experiments, with only a few cases of partially specular (mirror-like) reflection known 5,8-11 . Here we report gas transport through ångström-scale channels with atomically flat walls 12,13 and show that surface scattering can be either diffuse or specular, depending on the fine details of the...