Sharif Digital Repository

Curcumin incorporated polyurethanes (CPU) are gaining much attention as a biomaterial. However, challenges are still remained due to hydrophobicity and low mechanical strength of CPU. Herein, we synthesized the CPU/ZnO nanocomposites with good mechanical and improved hydrophilic properties via in-situ polymerization. A series of curcumin incorporated polyurethane with different concentrations of ZnO nanoparticles (ZnCPU) are synthesized by using the curcumin, polyethylene glycol (PEG) as the soft segment, hexamethylene diisocyanate (HDI) as the hard segment, and 1,4-butanediol (BDO) as the chain extender. The addition of ZnO nanoparticles (NPs) facilitated the soft domain of PU which is... 

Due to population growth and industrial development, Iran is facing the challenge of energy supply in various industrial, power plant, agricultural, and residential sectors. While most of Iran's energy supply comes from fossil fuels, these fuels have devastating environmental impacts. Therefore, Iran has to invest more in its renewable energy sources. Given that many locations of Iran have significant wind, solar, and geothermal potential, this study used a combination of SWOT, multicriteria decision-making approaches, and game theory to identify the best renewable energy development plans for the country. The Stepwise Weight Assessment Ratio Analysis (SWARA) technique was applied to weight... 

The use of hybrid renewable energy has increased in recent years due to the growing environmental concerns caused by the consumption of fossil fuels. The purpose of this study was the economic-environmental feasibility of using hybrid energy systems in one of the most polluted and populated provinces in Iran, Isfahan province. Various components of the hybrid energy system such as wind turbine (WT), photovoltaic panel (PV), diesel generator (DG), converter (CV) along with two scenarios of energy storage including battery (BT) and hydrogen storage have been considered in modeling the energy system. Six scenarios were considered based on the combination of different components for supplying... 

While Afghanistan's power sector is almost completely dependent on fossil fuels, it still cannot meet the rising power demand of this country. Deploying a combination of renewable energy systems with hydrogen production as the excess energy storage mechanism could be a sustainable long-term approach for addressing some of the energy problems of Afghanistan. Since Badakhshan is known to have a higher average wind speed than any other Afghan province, in this study, a technical, economic, and carbon footprint assessment was performed to investigate the potential for wind power and hydrogen production in this province. Wind data of four stations in Badakhshan were used for technical assessment... 

Due to population growth and industrial development, Iran is facing the challenge of energy supply in various industrial, power plant, agricultural, and residential sectors. While most of Iran's energy supply comes from fossil fuels, these fuels have devastating environmental impacts. Therefore, Iran has to invest more in its renewable energy sources. Given that many locations of Iran have significant wind, solar, and geothermal potential, this study used a combination of SWOT, multicriteria decision-making approaches, and game theory to identify the best renewable energy development plans for the country. The Stepwise Weight Assessment Ratio Analysis (SWARA) technique was applied to weight... 

The objective of the present study is the development of an optimization model for identifying the best configuration of renewable-based integrated energy systems. The system includes a combination of renewable energy systems such as wind, solar, hydropower and hydrogen production, storage facilities and conventional fossil-fuel generators. The developed tool consists of various modules where water heating assumes the utilization of waste energy as an option. Furthermore, the application, which is demonstrated for a case study in Tehran, has been considered. The power exchange with the distribution network and injection of hydrogen produced from excess renewable sources into gas network are... 

In this study, the optimal sizing and performance analysis of a standalone integrated solar power system equipped with different storage scenarios to supply the power demand of a household is presented. One of the main purposes when applying solar energy resource is to face the increasing environmental pollutions resulting from fossil fuel based electricity sector. To this end, and to compare and examine two energy storage technologies (battery and hydrogen storage technology), three storage scenarios including battery only, hydrogen storage technology only and hybrid storage options are evaluated. An optimization framework based on Energy Hub concept is used to determine the optimum sizes... 

In order to achieve the international climate goals and to keep the global temperature increase below 2 °C, carbon capture and storage in large point sources of CO2 emissions has received considerable attention. In recent years, mitigation of CO2 emissions from the power sector has been studied extensively whereas other industrial point source emitters such as hydrogen industry have also great potential for CO2 abatement. This study aims to draw an updated comparison between different hydrogen and power cogeneration systems using natural gas and coal as feedstock. The goal is to show the relative advantage of cogeneration systems with respect to CO2 emission reduction costs. Accordingly, the... 

The performance of the tower based concentrated solar thermal (CST-tower) plant is very sensitive to the operation strategy of the plant and the incident heat flux on the receiver. To date, most studies have been examined only the design mode characteristics of the cavity receivers, but this paper significantly expands the literature by considering non-design operating conditions of this important sub-component of the CST-tower plants. A feasible non-design operating conditions of the cavity receivers that was considered in this study is the storage mode of operation. Two practical dynamic control strategies were examined then to find the most efficient approach: fixed solar field mass... 

Solar energy will make a valuable contribution for power generation in the future. However the intermittency of solar energy has become an important issue in the utilization of PV system, especially small scale distributed solar energy conversion systems. The issue can be addressed through the management of production and storage of the energy in the form of hydrogen. The hydrogen can be produced by solar photovoltaic (PV) powered electrolysis of water. The amount of transferred energy to an electrolyzer from a PV module is a function of the distance between maximum power points (MPP) of PV module and the electrolyzer operating points. The distance can be minimized by optimizing the number... 

The future of urban energy systems relies on the transition to "smart energy networks" which incorporate energy storage with renewable energy sources such as wind and solar. Hydrogen provides a desirable energy vector for both energy storage and exchange of energy between energy hubs within a smart energy network. This paper aims to develop a generic mathematical model for the optimal energy management of future communities where hydrogen is used as an energy vector. An energy hub is a novel concept that systematically and holistically considers the energy requirements of both mobility and stationary loads. In order to perform optimization studies, the minimization of capital cost of... 

Hydrogen is an important storage medium and can be produced by the water electrolysis. In this research, energy transfer loss between a photovoltaic (PV) unit and electrolyzer is minimized by optimizing the size and operating condition of an electrolyzer directly connected to a PV module. In directly coupled photovoltaic-electrolyzer (PV/EL) systems, there is a mismatch between output PV's maximum power point characteristic and input PEM electrolyzer's characteristic. With proper sizing optimization methods, it is possible to directly couple photovoltaic-electrolyzer systems. The evolutionary optimization algorithms like genetic algorithm (GA), particle swarm optimization (PSO) and... 

In the present work the interaction of hydrogen molecules with perfect, defective and scandium doped polycyclic aromatic hydrocarbon (PAH) has been evaluated. At first the potential barrier for the penetration of hydrogen molecules through PAH structures has been investigated and then the adsorption of hydrogen molecules over PAH structures has been studied. To model the graphene surface for barrier calculations, it is shown that coronene can successfully estimate the graphene monolayer. The barrier height is calculated for perfect and two different defective PAH structures including Stone-Wales (SW) and 585. It is found that PAH even with small defects is impermeable to hydrogen molecules.... 

Hydrogen is a flexible energy carrier and storage medium and can be generated by electrolysis of water. In this research, hydrogen generation is maximized by optimizing the optimal sizing and operating condition of an electrolyzer directly connected to a PV module. The method presented here is based on Particle swarm optimization algorithm (PSO). The hydrogen, in this study, was produced using a proton exchange membrane (PEM) electrolyzer. The required power was supplied by a photovoltaic module rated at 80 watt. In order to optimize Hydrogen generation, the cell number of the electrolyser and its activity must be 9 and 3, respectively. As a result, it is possible to closely match the... 

The effect of particle size, lattice strain and crystallite size on the hydrogen desorption properties of nanocrystalline magnesium hydride powder was investigated. Commercial MgH2 powder was milled in a Spex 8000M up to 16 h and its structural evolution and desorption characteristics at different time intervals were examined using various analytical techniques. At the early stage of milling, the formation of metastable γ-MgH2 phase was noticed. While the crystallite size gradually decreased to 12 nm with increasing the milling time, the accumulated lattice strain gained a maximum value of 0·9% after 4 h milling. The highest drop in the desorption temperature (∼100°C) was attained at the... 

Using multi-walled carbon nanotubes (MWCNTs), the present study focuses on their electrochemical hydrogen storage capacities. The results showed that the hydrogen desorption process is composed of two steps with voltages around -0.75 and -0.15 V. Hydrogen adsorption at -0.15 V took place at temperatures above 30 °C, and the amount of energy required for adsorbing hydrogen was 1.68 eV. The hydrogen storage capacity increased with increasing electrolyte temperature from 30 to 60 °C in both steps. The hydrogen storage capacity of the MWCNTs treated at different atmospheres showed that the decrease in the graphitization of MWCNTs led to the increase in hydrogen adsorption. The results also... 

We have synthesized nanocrystalline MgH2-5at% TiCr1.2Fe0.6 nanocomposite powder by high-energy mechanical alloying for onboard hydrogen storage application. Magnesium hydride and the elemental Ti, Cr, and Ni powders were milled in a SPEX 800 mill under a high purity argon atmosphere. The dehydrogenation properties of the nanocomposite were studied by simultaneous thermal analyzer. The crystallite size of the nanocomposite was determined by XRD method. It is shown that nanometric grain structure, ultrafine particle size, and the catalytic effect of the transition metals possess a relatively low desorption temperature (262 °C) with 5.5wt % hydrogen release for the nanocomposite powder. The... 

Hydrogen storage capacities of raw, oxidized, purified and Fe-doped multi-walled carbon nanotubes (MWCNTs) were studied by electrochemical method. Based on transmission electron microscopy and Raman spectroscopic data, thermal oxidation removed defective graphite shells at the outer walls of MWCNTs. The analysis results indicated that the acid treatment dissolved most of the catalysts and opened some tips of the MWCNTs. Thermal gravimetric analysis and differential scanning calorimetry results illustrated that by oxidation and purification of MWCNTs, the weight loss peak shifts toward a higher temperature. N2 adsorption isotherms of the purified and oxidized MWCNTs showed an increase in N2... 

Work carried out in Iran seems to indicate that nanostructured materials may hold a key to fuel storage in a future hydrogen economy.... © 2009 Elsevier Ltd. All rights reserved  

The effects of HCl, HNO3, H2SO4 and HF acids on the purification and the electrochemical hydrogen storage of multi-walled carbon nanotubes (MWCNTs) were studied. The MWCNTs were synthesized on Fe-Ni catalyst by thermal chemical vapor deposition method. The X-ray diffraction and thermal gravimetric analysis results indicated that the MWCNTs purified by HF acid had the highest impurities as compared with the other acids. The N2 adsorption results at 77 K indicated that all the samples were mainly mesoporous and the purified MWCNTs by HF acid had the highest surface area as compared with the other acids. The hydrogen storage capacities of the purified MWCNTs by the following acids were in...