Sharif Digital Repository

Understanding the adsorption dynamics of nanoparticles at solid-liquid interfaces is of paramount importance to engineer nanoparticles for a variety of applications. The nanoparticle surface chemistry is significant for controlling the adsorption dynamics. This study aimed to experimentally examine the adsorption of surface-modified round-shaped silica nanoparticles (with an average diameter of 12 nm), grafted with hydrophobic (propyl chains) and/or hydrophilic (polyethylene glycol chains) agents, at an aqueous solution-silica interface with spherical soda-lime glass beads (diameter of 3 mm) being used as adsorbents. While no measurable adsorption was observed for solely hydrophobic or... 

Controlling evaporation plays an essential role in arid and semi-arid water resources systems where it accounts for a considerable amount of reservoirs outflow. In this study, we have evaluated evaporation reduction efficiency of different kinds of self-assembled nano-thickness films. The films consist of six different combinations of stearyl and cetyl alcohols with additives such as jojoba oil, stearic acid, and calcium hydroxide. The study lasted from July to August and utilized two pairs of class A evaporation pans: one pair was semi-floating on Chitgar lake water surface while the other one was located on the shore. The experimental results showed that a monolayer containing 3:1 stearyl... 

One problem that has always been a challenge for geotechnical engineers is construction on problematic and soft soils. Traditional methods of lime and cement stabilisation can be used to treat soils with these properties. The main drawback of lime addition to the clayey soils is a significant loss in ductility of lime-treated soils. Using ductile materials such as geogrids in lime-treated soils is one of the most effective ways to increase the soil ductility. Therefore, the effect of geogrids and lime on unconfined compressive strength (UCS), failure strain (ɛf), secant modulus (Es), deformability indexes (ID), resilient modulus (Mr), bulk modulus (K), and shear modulus (G) of the treated... 

Employing an effective rheological model for the flow of drilling fluid that can accurately predict changing conditions is of significant importance in drilling fluid optimization. Traditional generalized Newtonian models cannot predict the time change condition, viscoelastic behavior, role of each component, or microstructural behaviors within the fluid. Consequently, the present research aims to develop constitutive equations in the framework of generalized bracket formalisms and the extra tensor concept that connect the microscopic and macroscopic properties and can overcome the aforementioned problems of traditional rheological models. The developed model is applicable for drilling fluid... 

Incorporation of reclaimed asphalt pavement (RAP) and crumb rubber (CR) materials into asphalt mixtures have been of great importance from sustainability point of view. Although, inclusion of RAP materials in asphalt mixtures improves the rutting resistance at high temperature, the low temperature (LT) and intermediate temperature (IT) cracking performance of RAP mixtures may need additional considerations. In this regard, different schemes of modification have been applied to RAP mixtures to address its performance weaknesses. This study evaluated the effect of RAP and CR in combination with Sasobit and hydrated lime on the cracking performance of asphalt mixtures. The LT and IT... 

Employing an effective rheological model for the flow of drilling fluid that can accurately predict changing conditions is of significant importance in drilling fluid optimization. Traditional generalized Newtonian models cannot predict the time change condition, viscoelastic behavior, role of each component, or microstructural behaviors within the fluid. Consequently, the present research aims to develop constitutive equations in the framework of generalized bracket formalisms and the extra tensor concept that connect the microscopic and macroscopic properties and can overcome the aforementioned problems of traditional rheological models. The developed model is applicable for drilling fluid... 

Mud filtration happens during an overbalanced drilling operation that causes mud invasion into pores and fractures. The productivity of a formation is significantly affected by the invasion of the mud into the near-wellbore area during the mud loss process. A considerable number of studies have evaluated mud filtration statically; however, a few studies have considered the dynamic behavior of a mud loss process during overbalanced drilling, which results in the inadequate prediction of the mud loss volume and inflicted damage to the formation. In this study, a near-wellbore simulation system (NeWSS) was designed to evaluate the dynamic mud loss behavior using dimensionless parameters and... 

Low Salinity Waterflooding (LSWF) has become a popular tertiary injection EOR method recently. Both fluid-fluid and fluid-rock interactions are suggested as the contributing mechanisms on the effectiveness of LSWF. Considering the contradictory remarks in the literature, the dominating mechanisms and necessary conditions for Low Salinity Effect (LSE) varies for different crude oil-brine-rock (CBR) systems. The aim of the present study is to investigate LSE for an oil field in the Middle East that is composed of separate sandstone and limestone layers. Contact angles and Interfacial Tension (IFT) are measured to have more insight on the CBR under investigation. Visual experiments were... 

Studies on copper zinc tin sulpher selenide (CZTSSe) thin-film material and its applications as a base material are intensively being researched since it is an earth-abundant, inexpensive, flexible, and interesting material for next-generation optoelectronic technologies. Apropos, this study explores and reports the synthesis of CZTSSe thin films and their key optoelectronics characteristics. The reported films are fabricated on a soda-lime glass substrate by using a physical vapor deposition technique, and then annealed from 250 to 450 °C. From the X-ray diffraction analysis, the structure of the as-deposited thin films is found to be amorphous in nature. Annealed thin films of CZTSSe... 

Studies on copper zinc tin sulpher selenide (CZTSSe) thin-film material and its applications as a base material are intensively being researched since it is an earth-abundant, inexpensive, flexible, and interesting material for next-generation optoelectronic technologies. Apropos, this study explores and reports the synthesis of CZTSSe thin films and their key optoelectronics characteristics. The reported films are fabricated on a soda-lime glass substrate by using a physical vapor deposition technique, and then annealed from 250 to 450 °C. From the X-ray diffraction analysis, the structure of the as-deposited thin films is found to be amorphous in nature. Annealed thin films of CZTSSe... 

In this paper, an advanced integrated pixel-level method based on the deep convolutional neural network (DCNN) approach named DeepLabv3+ is proposed for weak interlayers detection and quantification. Furthermore, a database containing 32,040 images of limestone, dolomite, loess clay, and red clay is established to verify this method. The proposed model is then trained, validated, and tested via feeding multiple weak interlayers. Moreover, robustness and adaptability of the proposed model are evaluated, and the weak interlayers are extracted. Compared with the fully convolutional network (FCN)-based method and traditional image techniques, the proposed model provides higher accuracy in terms... 

Characterization and calcination behavior of a low-grade manganese ore, as a part of Mn ferroalloys production, was studied by XRF, ex-situ XRD, in-situ XRD, and SEM-EDS techniques. Calcination experiments were carried out at and up to 900 °C (1173 K) in air and argon atmospheres. The samples were in particles and powder forms. The results indicated that both quartz and calcite phases in the ore exhibit a bimodal spatial distribution; as relatively large regions and finely distributed in the Mn- and Fe-containing phases. By Rietveld analysis of the in-situ XRD data, the reactions occurring upon heating during the calcination process were deduced. Thermal decomposition and reactive diffusion... 

Cell survival during the early stages of transplantation and before new blood vessels formation is a major challenge in translational applications of 3D bioprinted tissues. Supplementing oxygen (O2) to transplanted cells via an O2 generating source such as calcium peroxide (CPO) is an attractive approach to ensure cell viability. Calcium peroxide also produces calcium hydroxide that reduces the viscosity of bioinks, which is a limiting factor for bioprinting. Therefore, adapting this solution into 3D bioprinting is of significant importance. In this study, a gelatin methacryloyl (GelMA) bioink that is optimized in terms of pH and viscosity is developed. The improved rheological properties... 

Targeting on the selenium free, pure sulfide kesterite compound (CZTS) allows retention of the higher band gap nontoxic absorber for a single-junction solar cell. In this work, CZTS thin films were deposited by the PLD method and the Structural/optical properties, as well as Mott–Schottky analysis, were studied at different substrate temperatures. Without undergoing the sulfurization process, the single-phase CZTS thin film is prepared at 300 ℃. In the second step, a numerical simulation is performed using the solar cell capacitance simulator to study the effect of the grading layer of MoS(Se)2 on the rear side of pure sulfide kesterite based solar cells. The device with a MoSe2 coated... 

One problem that has always been a challenge for geotechnical engineers is construction on problematic and soft soils. Traditional methods of lime and cement stabilisation can be used to treat soils with these properties. The main drawback of lime addition to the clayey soils is a significant loss in ductility of lime-treated soils. Using ductile materials such as geogrids in lime-treated soils is one of the most effective ways to increase the soil ductility. Therefore, the effect of geogrids and lime on unconfined compressive strength (UCS), failure strain (ɛf), secant modulus (Es), deformability indexes (ID), resilient modulus (Mr), bulk modulus (K), and shear modulus (G) of the treated... 

The petroleum industry suffers from reservoir souring phenomena, which has negative impacts on production facilities, health, and environment. Injection of incompatible water into the reservoir (waterflooding), which is considered as an enhanced oil recovery (EOR) method, is one of the most common causes of reservoir souring. In general, injected brine, especially seawater, contains high amounts of sulfate ion (SO42−). A high concentration of sulfate in the presence of sulfate-reducing bacteria (SRB) leads to the microbial reservoir souring. During this phenomenon, sulfide, specifically hydrogen sulfide gas (H2S) appears in the producing fluid of the reservoir. In this paper, a coupled... 

Low Salinity Waterflooding (LSWF) has become a popular tertiary injection EOR method recently. Both fluid-fluid and fluid-rock interactions are suggested as the contributing mechanisms on the effectiveness of LSWF. Considering the contradictory remarks in the literature, the dominating mechanisms and necessary conditions for Low Salinity Effect (LSE) varies for different crude oil-brine-rock (CBR) systems. The aim of the present study is to investigate LSE for an oil field in the Middle East that is composed of separate sandstone and limestone layers. Contact angles and Interfacial Tension (IFT) are measured to have more insight on the CBR under investigation. Visual experiments were... 

The aim of this study was to investigate the influences of combination of the two different SiO2 nanoparticles (15 nm and 80 nm) on compressive, flexural and tensile strength of ternary blended concrete. SiO2 nanoparticles with two different sizes of 15 and 80 nm have been used as a partial cement replacement by 0.5, 1.0, 1.5 and 2.0 wt.% in 16 different proportions of mixture followed by curing in lime solution for 7, 28 and 90 days. The results indicate that in all curing ages in lime solution specimens with 2.0% of 15 nm plus 1.5% of 80 nm cement replacement achieved higher mechanical properties. The continuous cement paste with the lowest delicate zones might be due to the fact of quick... 

This research evaluates the effect of filler type and content on rutting resistance of asphaltic materials by using laboratory experiments. To examine the effect of filler type, two traditional fillers (Silica sandstone powder and Portland cement) and a new recycled lime powder (Eggshell) were considered. To investigate the effect of filler content, three different filler contents were used. Marshall Stability test was performed on full mixes in order to determine the optimum binder content of the mixtures. Then, the static creep test was performed on Fine Aggregate Matrix (FAM) samples. The permanent strain after 10 minutes of recovery (PS-660) was considered as the indicator of potential... 

There are very limited researches carried out to investigate the influence of saturation degrees, freezing-thawing, and curing times on geotechnical properties of lime concrete (LC) and lime-cement concrete (LCC) due to the capillary action and changes in groundwater table. Subsequently, the primary goal of this research is to investigate the influence of these parameters on mechanical properties of LC and LCC using unconfined compression tests, namely uniaxial compressive strength (UCS), stress-strain behavior, deformability index (I D ), secant modulus (E S ), failure strain, bulk modulus (K), resilient modulus (M R ), brittleness index (I B ), and shear modulus (G). At first, the...