Sharif Digital Repository

The search for cathode materials with fast oxygen reduction reaction (ORR) catalytic activities and high ionic conductivity is the key obstacle to SOFCs commercialization and its operation at low temperatures. In order to search for a cathode with enhanced catalytic functionality, herein we report a single-phase CoFe2O4 (CFO) and CoGd0.2Fe1.80O4 (CGFO), which can be employed as an active cathode to improve electrocatalytic ORR functionalities at low temperature. It is found that CGFO having enriched oxygen vacancies exhibits the least polarization resistance (RP) of 0.42 Ωcm2 compared to the pure CFO which shows polarization resistance of 0.56 Ω cm2 under H2/air conditions. Furthermore,... 

In this study, magnesium boro/carbothermal reduction of zirconium silicate (ZrSiO4) was employed to synthesize zirconium-based composite nanopowders of ZrB2–SiC, ZrB2–ZrC–SiC, ZrC–SiC, and ZrC. For this aim, three different temperatures of 1200 °C, 1300 °C, and 1450 °C were selected as the supposed temperatures for synthesis. Elemental Mg and NaCl were also selected to assist reduction process. In addition, effects of different C/Zr ratios as well as using elemental boron and B4C as two different boron sources were investigated on the final produced phases. Subsequently, XRD and SEM/EDS analyses were carried out to elaborate microstructure and phase studies. Finally, STA carried out up to... 

Topological orders have been intrinsically identified in a class of systems such as fractional quantum Hall states and spin liquids. Accessing such states often requires extreme conditions such as low temperatures, high magnetic fields, pure samples, etc. Another approach would be to engineer the topological orders in systems with more accessible ingredients. In this work, we present networks of Majorana bound states, which are currently accessible in semiconductor nanowires proximitized to conventional superconductors, and show that the effective low-energy theory is topologically ordered. We first demonstrate the main principles in a lattice made of Kitaev superconducting chains comprising... 

Understanding the motion characteristics of fullerene clusters on the graphene surface is critical for designing surface manipulation systems. Toward this purpose, using the molecular dynamics method, we evaluated six clusters of fullerenes including 1, 2, 3, 5, 10, and 25 molecules on the graphene surface, in the temperature range of 25 to 500 K. First, the surface motion of clusters is studied at 200 K and lower temperatures, in which fullerenes remain as a single group. The trajectories of the motion as well as the diffusion coefficients indicate the reduction of surface mobility as a response to the increase of the fullerene number. The clusters show normal diffusion at the temperature... 

Incorporation of reclaimed asphalt pavement (RAP) and crumb rubber (CR) materials into asphalt mixtures have been of great importance from sustainability point of view. Although, inclusion of RAP materials in asphalt mixtures improves the rutting resistance at high temperature, the low temperature (LT) and intermediate temperature (IT) cracking performance of RAP mixtures may need additional considerations. In this regard, different schemes of modification have been applied to RAP mixtures to address its performance weaknesses. This study evaluated the effect of RAP and CR in combination with Sasobit and hydrated lime on the cracking performance of asphalt mixtures. The LT and IT... 

Herbal medicine wastes (HMWs) are byproducts of medicine factories, which are mainly landfilled for their environmental problems. Only bearing in mind the contamination and concerns caused by the COVID-19 pandemic and environmental emissions, the worth of herbal medicine wastes management and conversion to green products can be understood. In this work, subcritical water treatment was carried out batch-wise in a stainless tube reactor in the pressure range of 0.792–30.0 MPa, varying the temperature (127–327 °C) and time (1–60 min) of extraction. This resulted in new and green material sources, including organic acids, amino acids, and sugars. Amazingly, at very low extraction times (below 5... 

Direct reduction of iron process in steel industry has special production conditions. Low quality cooling water, low cold and high hot cooling water temperature, space limitation for new equipment installation, high value-added of product and severe effect of cooling water temperature on production rate are of these conditions. Considering technical and economic constraints and limitations, this situation makes this process an attractive case study for converting the existing wet cooling tower to hybrid cooling system. In this paper, based on integration of process, dry and wet cooling system and ambient conditions profiles, a new method for designing hybrid cooling system has been proposed.... 

Conventional additives used in drilling fluid may have detrimental short- and long-term impacts on the surrounding environment. The employment of biodegradable green material in drilling fluid as alternative additives will eliminate these harmful impacts. In this study, acorn shell powder is proposed as a novel biodegradable additive for application in drilling fluid. First, the acorn shell powder was prepared and then characterized in terms of chemical structure, particle size, and morphology. The acorn shell powder, with four different concentrations, was then introduced into a water-based fluid; its functionality in the fluid system was evaluated with respect to rheological and filtration... 

In terms of manufacturability, there is a high tendency to deposit light-absorbing CuInS2 films by solution processing methods like ink-based depositions. In particular, for nanoparticle inks, the synthesis of highly dispersed and stable inks, with uniformity in the deposition process, is a serious challenge. Here, we demonstrate a novel two-step low-temperature CuInS2 film deposition method in which the In2S3 is deposited first. It then partially is converted into CuInS2 through the infiltration of Cu+ ions in the In2S3 layer in a dip-coating process. The resulting films are highly uniform, with diffraction peaks indicating the formation of pure CuInS2 phase. The proper stoichiometry of... 

The present work aims to fabricate cordierite/BZBS glass (Bi2O3-ZnO-B2O3-SiO2) composites through one-step heat treatment. Cordierite was synthesized from a solid-state reaction of aluminum hydroxide, magnesium hydroxide, and silica gel. BZBS glass was obtained through the classic melt quenching technique. Milled cordierite powder was mixed with different volume fractions of glass powders and heat treated at 950 °C. Considering the densification behavior along with the microwave dielectric features, two composites (C70G30 and C60G40) were chosen for further examination. These composites were separately heat treated at different temperatures from 650 up to 900 °C, then characterized due to... 

Surface modification of SnO2 electron transporting layer (ETL) plays a critical role in the performance of SnO2-based planar perovskite solar cells (PSC). Here, we show how long-time NH4F-based water bath treatment of SnO2 layer makes smoothing and morphological improvements and enhances the device performance. Recently it was shown that short-time NH4F treatment (2 sec) with spin coating method reduces interface traps by improving surface chemistry. Here we observe the smoothing of SnO2 films as a result of long-time NH4F treatment, which could be a result of a slight etching-deposition process. Absorption and resistivity measurements indicate that SnO2 etching process is involved in... 

Three steels were designed based on HSLA-100 with additional levels of Mn, Ni, Cr and Cu. The steels were prepared by controlled rolling and tempered at temperatures in range of 550-700°C. The continuous cooling time curves were shifted to longer times and lower temperatures with the increased tendency for the formation of martensite at lower cooling rates. The microstructures revealed that controlled rolling results in austenite with uniform fine grain structure. The steel with the highest amount of Mn showed the greatest strength after tempering at 750 °C. The top strength was attributed to the formation of Cu-rich particles. The steel with 1.03 wt.% Mn, tempered at 650 °C exhibited the... 

Organic Rankine Cycles (ORCs) are promising approaches for generating power from medium or low temperature heat sources. In this regard, ORCs can be used to indirectly produce power from solar energy. Due to intermittent nature of solar energy, storage unit should be coupled with solar ORCs to improve the output power and operating hours. In this article, studies on solar ORCs integrated with various types of storage units were reviewed; the main findings of such studies were extracted and provided. Based on the findings, several factors such as the temperature and pressure at the inlet of the turbine, as well as the operating condition affect the performance of solar ORCs with thermal... 

Three novel geothermal-based organic Rankine cycle (ORC) systems are proposed to enhance the efficiency and for waste heat recovery purpose. The proposed systems are modeled based on a basic ORC system (concept 1), an ORC system with an internal heat exchanger (concept 2), and a regenerative ORC system (concept 3). Accordingly, two thermoelectric generators (TEG) are introduced into the systems to exploit the waste heat of the system. The condenser is replaced with a TEG unit while the other TEG unit is used to recover the waste heat of the reinjected geothermal fluid. A comprehensive numerical investigation is conducted to compare the proposed systems from the thermodynamic and... 

Three novel geothermal-based organic Rankine cycle (ORC) systems are proposed to enhance the efficiency and for waste heat recovery purpose. The proposed systems are modeled based on a basic ORC system (concept 1), an ORC system with an internal heat exchanger (concept 2), and a regenerative ORC system (concept 3). Accordingly, two thermoelectric generators (TEG) are introduced into the systems to exploit the waste heat of the system. The condenser is replaced with a TEG unit while the other TEG unit is used to recover the waste heat of the reinjected geothermal fluid. A comprehensive numerical investigation is conducted to compare the proposed systems from the thermodynamic and... 

Severe plastic deformation (SPD) processes have received less attention at low temperatures (sub-zero and cryogenics). Hence, in this study, SPD of a commercially pure aluminum (AA1050) through Multi-Directional Forging (MDF) at Low-Temperature (LTMDF) and Room-Temperature (RTMDF) is investigated for different strains. Multi-directionally forged (MDFed) samples were annealed at 150, 250, 350, and 450 °C for 1 h, and some samples were stored at room temperature for periods up to 1 year. Results show that the hardness values and flow stress of LTMDFed aluminum are higher than those of RTMDFed ones. The ratio of yield strength to hardness for LTMDF is similar to that for RTMDF. Surprisingly,... 

Phenomenological constitutive modeling of Ti-6Al-4V at temperatures between 923 and 1023 K under 0.0005–0.05 s−1 quasi-static rates is studied based on a phenomenological approach. For this purpose, the Johnson–Cook constitutive model is revisited. At low temperature conditions under moderate to high strain rates, the material’s stress–strain curves are the most similar to power-law function. Contrary to this, at high temperature conditions under low to moderate strain rates, the saturation-type function well describes the stress–strain curves. On the other hand, it is illustrated that the Johnson–Cook constitutive model is feeble to predict the material’s behavior correctly. Accordingly, in... 

The strain-induced martensitic transformation greatly affects the plastic behavior of the metastable austenitic stainless steels. The martensitic transformation continuously changes the initially homogeneous material into a strongly heterogeneous bi-phase one. In addition to the hardening behavior, this phenomenon would influence the damage growth and load-carrying capacity of the material during the plastic deformation. In this study, plastic behavior of the material AISI 304 including the hardening and damage growth, has been examined at low temperature; where a high rate of martensitic transformation affects the microstructure strongly. Experimental analysis and microscopic observations... 

Free polymer graphene aerogel nanoparticles (GA NPs) were synthesized by using reduction/aggregation of graphene oxide (GO) sheets in the presence of vitamin C (as a biocompatible reductant agent) at a low temperature (40 °C), followed by an effective sonication. Synthesis of GA NPs in doxorubicin hydrochloride (DOX)-containing solution results in the simultaneous synthesis and drug loading with higher performance (than that of the separately synthesized and loaded samples). To investigate the mechanism of loading and the capability of GA NPs in the loading of other drug structures, two groups of ionized (DOX, Amikacin sulfate and, D-glucosamine hydrochloride) and non-ionized (Paclitaxel... 

Characterization and calcination behavior of a low-grade manganese ore, as a part of Mn ferroalloys production, was studied by XRF, ex-situ XRD, in-situ XRD, and SEM-EDS techniques. Calcination experiments were carried out at and up to 900 °C (1173 K) in air and argon atmospheres. The samples were in particles and powder forms. The results indicated that both quartz and calcite phases in the ore exhibit a bimodal spatial distribution; as relatively large regions and finely distributed in the Mn- and Fe-containing phases. By Rietveld analysis of the in-situ XRD data, the reactions occurring upon heating during the calcination process were deduced. Thermal decomposition and reactive diffusion...