Sharif Digital Repository

Based on the new standards, less than 10 ppm sulfur is allowed for the automotive fuels. This has led researchers to try improving the present conventional methods as well as seeking alternative routes for refinement of the petroleum products so much to comply with the requirements. Since thiophenic fragments such as dibenzothiophene (DBT) are the most durable sulfur compounds in the current hydrodisulfurization method, many studies have been conducted over recent years on how to remove these compounds. In this thesis, the desulfurization of dibenzothiophene from gasoline via adsorption method was studied. In order to carry out the adsorption process, a nanocomposite of graphitic-carbon... 

Electron states of diamond vacancy under stress were studied theoretically. The generalized Hubbard model is used to calculate the electrons energy levels. The results shows that the degeneracy of some levels (T, with triple space degeneracy) reduced to levels with lower degeneracy (E, with double space degeneracy and A, without degeneracy). Besides this spiting of degeneracy the energy of all states changed and therefore the transition energy between these states changed too. Jahn-Teller effect was observed  

In this thesis, firstly we have developed a coupled dynamic for the orbit and attitude of a solar sail. Secondly, we found an optimal trajectory from the Earth to Mars and tried to control the system on the optimal trajectory by a control mechanis which moves the center of mass of the sail. The solar sail is considered to be rigid and Ideally reflective which means the sail reflects the full extent of the photons it receives. Adjusting the center of mass of the sail is done by changing the position of two sliding masses rode on two rails perpendicular to each other. Moving the center of mass of the sail brings about a change in the attitude of the sail which then causes a deflection in the... 

Gas turbine engine control is a demanding task that requires the regulation of the thrust as well as the satisfaction of the limitations such as engine aerodynamic instability, over temperature and over speed. Fuzzy logic is an attractive technique for the control of poor understood unmodeled, or complex systems especially where the experience of human operators is available to provide qualitative rules. In such cases, it has been found that control decisions can be made on the basis of linguistic measures or fuzzy algorithms. The controller that is designed on the basis of this theory is called fuzzy logic controller. The main objective of this thesis is hardware implementation of fuzzy... 

The purpose of this thesis is design of an adaptive tracking control for input-quantized strict-feedback fractional order nonlinear systems with unknown dynamics and asymmetric time-varying output constraints. The controller design is achieved by using a hysteretic quantizer to avoid chattering and not needing the quantization parameters. The fuzzy logic method has been used to solve the problem of unknown dynamics. Also, due to the asymmetric time-varying output constraints, the Barrier Lyapunov function has been used. In this thesis, less restrictive assumptions have been considered than the work performed in previous researches.By utilizing the adaptive backstepping approach and based on... 

In the present work, trajectory optimization of the Dual-Arm Cam-Lock robot considering kinematic and dynamic redundancy is performed. First, the optimal control problem is solved only considering kinematic redundancy and then is solved considering dynamic redundancy. General form of the dynamic model for the system is developed using Lagrangian relations. Global optimization method is used for redundancy resolution problem. A performance index is defined based on the consumed kinetic energy and is minimized through a desired trajectory using the global optimization method. Formulations of optimal control problem are derived and initial boundary problem is changed to two point boundary value... 

Natural boron consists of two stable isotopes, mass 10 (19.3%) and mass 11 (80.7%). 10B isotope has a large thermal neutron capture cross-section and it therefore, used widely in such aspects as modern industry, military equipment, medical science and so on. specially the demand of atomic energy industry for the boron isotope is increased severely. So the separation of 10B from natural boron has received very wide attention at present. There are many kinds of methods on the boron isotopes separation, such as chemical exchange reaction and distillation in boron trifluoride method, ion exchange in boric acid solution method, counter current recycle membrane cascades in boron trifluoride... 

The magnetic MOF-based catalytic system has been reported here to be an efficient catalyst for synthesis of carbamates under optimal conditions. The robust MOF catalyst was built based on magnetic nanoparticles and HKUST-1 which further modified with thioacetamide and carbonization. The catalyst structure was confirmed by various techniques. Furthermore, the products’ yields were obtained in good to excellent for all reactions under mild conditions which result from superior activity of the synthesized heterogeneous catalyst containing Cupper. Also, the magnetic property of the MOF-based catalyst makes it easy to separate from reaction mediums and reuse in the next runs. In summary, the... 

Advances in genetics and biology have led to the ability to produce therapeutic genes and modify defective genes in patients' genomes, resulting in a solution to many genetic diseases. Many genetic diseases can be overcome through gene therapy by transferring therapeutic genes into the cell nucleus. However, researchers have not yet been able to develop a safe, high-efficiency carrier for the transfer of genes to the target cell, and this has become a bottleneck for the clinical applications of gene therapy. In this study, the ZIF-8 organic-metallic framework was used as a new vector for the transfer of therapeutic genes to target cells. For this purpose, ZIF-8 was synthesized by a... 

Five-Level Active-Neutral-Point -Clamped (5L-ANPC) converter is used for medium-voltage and high-power applications. In many of these applications, availability and robustness against fault are the most important issues. On the other hand, this converter is made of a large number of power semiconductor switches, diodes and capacitors which could increase the failure probability. Thus, fault detection of power circuit elements is necessary for fault tolerant operation of the converter. In this thesis, following an introduction to the topology and operation principles of Five-Level Active Neutral point clamped converter, a novel open-circuit fault detection and localization method is... 

Deep reactive ion etching is one of the most used techniques for manufacturing micro-structures. The most popular silicon DRIE technique is Bosch process. Ability to manufacture high aspect ratio features made Bosch process the main technique for developing micro-electromechanical devices. Dry etching is a combination of physical and chemical processes. The chemical processes play a very important role due to their speed of material removing and also due to their high selectivity. Also chemical processes are responsible for development of passive resist layer on the surface. On the other hand, if not controlled properly it can reduce anisotropy, resulting in a low quality etch. In this... 

The Atomic Energy Organization of Iran (AEOI) has launched a program of low level waste management. This program also includes waste produced at Uranium Conversion Facility (UCF) of Esfahan. The liquid waste, which was generated during the operation of plant and concentrated in lagoon, was characterized for the development of the treatment process. The aim of this study was to recovery of uranium content of liquid waste in the lagoon. The recovery of uranium has the advantage of saving this valuable metal and the avoidance of unacceptable discarding solution to the environment. Uranium may be recovered from an aqueous solution by precipitation, solvent extraction and ion exchange.... 

One of the most promising strategies for fighting cancer is the drug delivery process using synthetic nanoparticles. Once in biological milieu, the nanoparticle surfaces get covered with a layer of biomolecules called the “Protein Corona”. The protein corona formation changes the nanoparticles interaction with the human body dictating a new fate for them. The protein corona composition is not only dependent on the nanoparticle itself, but also it is affected by the health condition of patients as recently discovered through the experimental studies. Here, the effect of disease on the protein corona formation is discussed through the molecular dynamics simulations. A multiscale simulation... 

In recent years, application of nanotechnology in medicine is growing rapidly, specially, in the area of drug delivery. One of most import applications of nanotechnology is the using of nanoparticles as a carrier in targeted drug delivery systems. Simulation of drug delivery and prediction of drug release are developing in experimental and industrial areas. Mathematical modeling is used in drug delivery systems because they are time and cost saving and also can be used to predict drug behavior. The aim of this research, is to provide a framework for designing nano drug carriers. To this end, uptake of nanoparticles into different types of cells with different characteristics, in different...