Sharif Digital Repository

TiO2 and transition metal (Cr, Mn, Fe, Co, Ni, Cu, and Zn) doped TiO2 nanoparticles were synthesized by the sol–gel method using 2-hydroxylethylammonium formate as an ionic liquid. All the prepared samples were calcined at 500 °C and characterized by X-ray diffraction (XRD), BET surface area determination, energy dispersive X-ray (EDX) analysis, diffuse reflectance spectroscopy (DRS), and Fourier transformed infrared (FT-IR) techniques. The studies revealed that transition metal (TM) doped nanoparticles have smaller crystalline size and higher surface area than pure TiO2. Dopant ions in the TiO2 structure caused significant absorption shift into the visible region. The results of... 

TiO2 nanoparticles were prepared by the sol - gel process using 2-hydroxylethy- lammonium formate as an ionic liquid. Nanoparticles were crystallized at various temperatures (300-700°C). The products were characterized using X-ray diffraction (XRD), nitrogen adsorption - desorption isotherms and scanning electron microscopy (SEM) techniques. It was found that the resulting TiO2 nanoparticles had good thermal stability either to resist collapse or the anatase-to-rutile phase transformation during heat treatment. The photocatalytic activity of the nanocrystalline TiO2 was evaluated by the degradation of Acid Blue 92 (AB92) which is\ commonly used as a textile dye. The results showed that the... 

Copper oxide-titania catalysts with nanocrystalline mesoporous structure were prepared by sol-gel technique using tetra isopropyl ortho titanate (TiPT) as the inorganic precursor and amino-2 ethanol as the swelling agent. Characterization was performed using X-ray diffraction (XRD), fourier transformed infrared spectra (FTIR), scanning electron microscopy (SEM), diffuse reflectance UV-Vis spectroscopy (DRS), and N2 adsorption-desorption measurements. It was found that CuO (0.025-0.1 mol ratio) has some effect on the particle size, surface area, pore-volume, pore-diameter, crystallinity of the particles, and crystalline phase of TiO2 nanocrystalline. The results indicated that 0.1 CuO-TiO2... 

Nanocrystalline and nanostructured TiO2-Cr2O3 thin films and powders were prepared by a facile and straightforward aqueous particulate sol-gel route at low temperature of 400°C. The prepared sols showed a narrow particle size distribution with hydrodynamic diameter in the range of 17.7 nm to 19.0 nm. Moreover, the sols were stable over 4 months, with constant zeta potential measured during this period. The effect of the Cr:Ti molar ratio on the crystallization behavior of the products was studied. X-ray diffraction (XRD) analysis revealed that the powders crystallized at low temperature of 400°C, containing anatase-TiO2, rutile-TiO2, and Cr2O3 phases, depending on the annealing temperature... 

This work aims to develop a chemically modified sol–gel synthesis pathway for obtaining various barium titanate nanostructures. The method is able to prepare different BaTiO3 nanostructures such as highly stable nanoparticle embedded colloids, highly transparent amorphous nanolayers, nanocrystalline BaTiO3 powders and ultrathin BaTiO3 nanostructured films directly from a precursor solution. All the products have been prepared at a lower temperature and in a more cost-effective way in contrast to other established sol–gel methods. The results show that the optical transparency of the thin films has been significantly improved in contrast to the similar researches. The deposited thin film is... 

The low temperature perovskite-type calcium titanate (CaTiO3) thin films and powders with nanocrystalline and mesoporous structure were prepared by a straightforward particulate sol-gel route. The prepared sol had a narrow particle size distribution about 17 nm. X-ray diffraction and Fourier transform infrared spectroscopy revealed that, the synthesized powders had highly pure and crystallized CaTiO3 structure with preferable orientation growth along (1 2 1) direction at 400-800 °C. The activation energy of crystal growth was calculated 5.73 kJ/mol. Furthermore, transmission electron microscope images showed that the average crystallite size of the powders annealed at 400 °C was around 3.5... 

The aim of current research is to investigate the substrate electropolishing effect on corrosion resistance of Ni-Mo thin films. For this purpose, corrosion resistance of coatings deposited on mild steel substrates, that was electropolished or mechanically polished, have been compared in 3.5 wt.% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The structural properties of Ni-Mo thin films were evaluated using X-ray diffraction (XRD) and their morphology, microstructure and chemical composition were also investigated using scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS). Temperature and acidity of deposition... 

Highly porous nanocrystalline alumina was synthesized using two different precipitation processes and precipitating agents, which were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and porosimetry analyses. Different precipitating agents yielded nanocrystalline alumina catalysts with different morphologies and textural properties. Batch precipitation using sodium bicarbonate at constant pH resulted in a highly porous nanocrystalline γ-alumina catalyst, having surface area of 351.47 m2 g-1, total pore volume of 1.68 cm3 g -1 and mean pore diameter of 19.17 nm. The mean crystallite size was also determined to be 3.8 nm, based on the XRD results. Catalytic... 

Pechini process was used for preparation of three kinds of nanocrystalline powders of yttria-stabilized zirconia (YSZ): doped with 1.5 mol% nickel oxide, doped with 15 mol% ceria, and doped with 1.5 mol% nickel oxide plus 15 mol% ceria. Zirconium chloride, yttrium nitrate, cerium nitrate, nickel nitrate, citric acid and ethylene glycol were polymerized at 80 °C to produce a gel. XRD, SEM and TEM analyses were used to investigate the crystalline phases and microstructures of obtained compounds. The results of XRD revealed the formation of nanocrystalline powder at 900 °C. Morphology of the powder calcined at 900 °C, examined with a scanning electron microscope, showed that the presence of... 

In this investigation, application of the least square support vector machine (LSSVM) for modeling of the electrical resistivity of the magnetic Zn-Mn-S nanocrystalline semiconductor films has been described. The model has been trained based on the experimental data obtained from a published work by Sreekantha Reddy et al. The model inputs are temperature and variations in the concentrations of Zn, Mn. The results indicate that LSSVM is able to be used for accurate prediction of the electrical resistivity of the Zn-Mn-S nanocrystalline semiconductor films  

In this research, bioactive glass (BG) of the type CaO-P2O 5-SiO2 and nanocrystalline forsterite (NF) bioceramic were successfully synthesized via sol-gel processing method. Heat-treatment process was done to obtain phase-pure nanopowders. After characterization of each sample, the nanocomposite samples were prepared by cold pressing method and sintered at 1000°C. The samples were fully characterized by X-ray powder diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR) analyses. The average nanocrystallite size was determined using the Debye-Scherrer's formula 19.6 nm. The bioactivity was examined in vitro... 

Ferrite nanocrystals are an interesting material due to their rich physical properties. Here we add nonmagnetic dopants Zn and Cu to nickel ferrite nanocrystals, Ni1-xMxFe2O4 (0 ≤ x ≤ 1, M = Cu, Zn), and study how relevant properties of the samples are modified accordingly. Basically, these dopings cause a rearrangement of Fe +3 ions into the two preexisting octahedral and tetrahedral sites. In fact, this, we show, induces pertinent magnetic properties of the doped samples. In the case of the Cu-doping, the Jahn-Teller effect also emerges, which we identify through the Fourier Transform Infra-Red Spectroscopy of the samples. Moreover, we show an increase in the lattice parameters of the... 

Nanocrystalline TiO 2-Fe 2O 3 thin films and powders were prepared by a straightforward aqueous particulate sol-gel route at the low temperature of 300 °C. Titanium(IV) isopropoxide and iron(III) chloride were used as precursors, and hydroxypropyl cellulose was used as a polymeric fugitive agent in order to increase the specific surface area. X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) revealed that the powder crystallised at the low temperature of 300 °C, containing anatase-TiO 2 and hematite-Fe 2O 3 phases. Furthermore, it was found that Fe 2O 3 retarded the anatase-to-rutile transformation up to 500 °C. The activation energies for crystallite growth of TiO 2... 

Thorium dioxide (thoria) nano-particle was synthesized by employing supercritical water (SCW) as an excellent reaction environment for hydrothermal crystallization of metal oxide particles. This method is ideal for production of ultrafine powder having controlled stoichiometry, high quality, purity and crystallinity. The nano-crystalline thoria was prepared in a stainless steel (316 L) autoclave, fed with an aqueous solution of Th(NO 3) 4.5H 2O as a reactant and took place under SCW condition up to 450 °C for 45 min. The product was recovered and characterized by X-Ray Diffraction (XRD), Thermal Gravimetry Analysis (TG/DTA) and Brunauer, Emmett and Teller (BET) surface area analysis. The... 

A sonochemistry-based synthesis method was used to produce nanocrystalline nickel oxide powder with ∼20 nm average crystallite diameter from Ni(OH)2 precursor. Ultrasound waves were applied to the primary solution to intensify the Ni(OH)2 precipitation. Dried precipitates were calcined at 320 °C to form nanocrystalline NiO particles. The morphology of the produced powder was characterized by transmission electron microscopy. Using sonochemical waves resulted in lowering of the size of the nickel oxide crystallites. FT-IR spectroscopy and X-ray diffraction revealed high purity well-crystallized structure of the synthesized powder. Photoluminescence spectroscopy confirmed production of a wide... 

Hierarchical submicrometer TiO 2 hollow spheres with outer diameter of 300-700 nm and shell thickness of 200 nm are synthesized by liquid phase deposition of TiO 2 over carbon microspheres as sacrificial templates. The final TiO 2 hollow spheres are applied as a scattering layer on top of a transparent nanocrystalline TiO 2 film, serving as the photoanode of a dye-sensitized solar cell (DSC). In addition to efficient light scattering, the mesoporous structure of TiO 2 hollow spheres provides a high surface area, 74 m 2/g, which allows for higher dye loading. This dual functioning suggests that TiO 2 hollow spheres may be good replacements for conventional TiO 2 spheres as scatterers in DSCs.... 

Undoped and copper doped nanostructured zinc oxides were synthesized by using a series of synthetic layered material, undoped and copper doped zinc hydroxide nitrates at various molar percentages of copper (2-10) within the layers as precursors. The layered materials were heat-treated at 500 °C to produce zinc oxide nanostructures with crystallite sizes in the range of 23-35 nm. Optical studies of the nanostructured copper doped zinc oxides showed the decrease in band gap with increasing content of the doping agent, copper  

TiO2 thin films containing different concentrations of Ag nanoparticles have been synthesized by sol-gel method. According to UV-visible spectra, presence of an intense surface plasmon resonance peak at 490 nm of wavelength indicated formation of silver nanoparticles in the TiO2 films. Based on atomic force microscopy (AFM) analysis, the surface roughness and the effective surface ratio increased by increasing the Ag mol%. Moreover, scanning electron microscopy (SEM) images showed formation of Ag nanoparticles on the surface for the samples containing high Ag concentration. X-ray diffraction (XRD) patterns revealed that the size of Ag nanocrystals increased by increasing the Ag content in... 

The aim of this study was to investigate the thermal behavior of Mg-doped calcium phosphate compounds. Nanocrystalline HA and β-TCP mixtures containing different magnesium contents were synthesized via an alkoxide sol gel method. The ratio of (Ca+Mg)P was kept constant at 1.67, and the Mg content ranged between 0 and 3 mol%. The influence of magnesium on the phase composition, chemical structure, thermal behavior and morphological characteristics of nanopowders was analyzed using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Simultaneous Thermogravimetry and Differential Thermal Analysis (STA/DTA), Scanning Electron Microscopy (SEM) and Transmission Electron... 

The low temperature perovskite-type strontium titanate (SrTiO 3) thin films and powders with nanocrystalline and mesoporous structure were prepared by a straightforward particulate sol-gel route. The prepared sol had a narrow particle size distribution with hydrodynamic diameter of about 17 nm. X-ray diffraction (XRD) revealed that the synthesized powders had a perovskite-SrTiO 3 structure with preferable orientation growth along the (1 0 0) direction. TEM images showed that the average crystallite size of the powders annealed in the range 300-800°C was around 8 nm. FE-SEM analysis and AFM images revealed that the deposited thin films had mesoporous and nanocrystalline structure with the...