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    Experimental Investigation into the Direct Contact of Working Fluid with Phase Change Material and its Effect on the Heat Transfer Rate

    , M.Sc. Thesis Sharif University of Technology Ranjbar Kermani, Javad (Author) ; Shafii, Mohammad Behshad (Supervisor)
    Abstract
    The unique properties of phase change materials (PCMs), such as high latent heat and nearly constant phase change temperature, have made them a suitable option for use in thermal energy storage systems and thermal management systems. However, the low thermal conductivity of these materials has imposed limitations on their widespread use in industries. In this study, for the first time, the effect of injecting a boiling fluid (BF) into the PCM container to enhance heat transfer and accelerate the solidification process has been experimentally investigated. In this regard, paraffin wax and acetone have been selected as the PCM and the BF, and the effects of parameters such as the initial... 

    Thermodynamically Consistent Phase Field Modeling of Interaction Between Crack Propagation and Phase Transformation

    , Ph.D. Dissertation Sharif University of Technology Jafarzadeh, Hossein (Author) ; Farrahi, Gholam Hossein (Supervisor) ; Javanbakht, Mahdi (Co-Supervisor)
    Abstract
    According to the widespread application of shape memory alloys, their study in the presence of cracks has received lots of attention in the last two decades. The phase transformation ahead of the crack tip may change the stress field and the fracture behavior, especially at the nanoscale. Thus, modeling this phenomenon helps to recognize the affecting factors on crack propagation and prediction of material behavior when cracks exist. In the first step of this thesis, a phase field approach for crack propagation was presented, first by considering fracture as phase transformation and then as bond breaking. According to the scaling-up strategy, the developed theory is applicable from the... 

    Finite Element Analysis of Repair Welding Residual Stress in Pressure Vessels and Piping System

    , M.Sc. Thesis Sharif University of Technology Ehsani, Mohammad (Author) ; Farrahi, Gholamhossein (Supervisor)
    Abstract
    Repair welding is one of the most prevalent processes in repair and maintenance part of all industries. Amongst the issues of welding processes are residual stresses and distortions. Thus prediction of residual stresses and their distribution are important for designing welding procedure specifications. Circumferential butt weld is often used for joining steam and hot water lines in plants. Due to the intense concentration of heat in the welding, the regions near the weld line undergo severe thermal cycles. The thermal cycles cause non-uniform heating and cooling in the material, thus generating inhomogeneous plastic deformation and residual stresses in the weldment. The presence of residual... 

    Investigating The Transformation Of Strain-Induced Martensite During Deformation and its Effect on the Wear Behavior of Austenitic Stainless Steel

    , M.Sc. Thesis Sharif University of Technology Zare, Mahdi (Author) ; Serajzadeh, Siamak (Supervisor)
    Abstract
    In austenitic stainless steel types 304 and 316, due to the instability of the austenite phase, the martensite phase is formed by plastic deformation below the Md temperature. In this research, the cold rolling of 304L austenitic stainless steel and the transformation of austenite to strain-induced martensite and its effect on mechanical properties, especially wear, were studied. In this way, the samples were rolled in two modes and four passes in each mode. In the first case, the samples were cooled between each pass in water as a cooling liquid, and in the second case, the samples were cooled in each pass without using water and by air. Next, tests such as hardness measurement, uniaxial... 

    Correlation Between Mechanical Properties and Microstructure Evolution of Al / Al2O3-Al3Ti-CNT Hybrid Nanocomposites Produced by Plasma Plasma Sintering (SPS) based on Thermal Decomposition of Aluminum Titanate Nanostructure

    , M.Sc. Thesis Sharif University of Technology Azarniya, Abolfazl (Author) ; Madaah Hosseini, Hamid Reza (Supervisor) ; Ramakrishna, Seeram (Co-Supervisor)
    Abstract
    In this research, aluminum titanate or tialite with the chemical composition of Al2TiO5 was synthesized as nanostructured form using the sol-gel method with the aim to serve as a chemical source for aluminum and titanium elements within the fabrication of in-situ Al2O3-Al3Ti-reinforced aluminum matrix nanocomposites. Since the aforementioned nanocomposite is produced based on the thermal decomposition of tialite, the thermar decomposition of this material in air atmosphere, under applied mechanical strain, and direct contact with the underlying aluminum was comprehensively evaluated. The empirical results showed that as tialite is exposed to aluminium, the reaction starts from low... 

    Study on the Phase Transformation and Mechanical Behavior of Duplex Stainless Steel Resistance Spot Welds

    , M.Sc. Thesis Sharif University of Technology Arabi, Hassan (Author) ; Pouranvari, Majid (Supervisor) ; Movahedi, Mojtaba (Supervisor)
    Abstract
    Use of materials with both high strength and good formability in car structure is a serious approach in the automotive industry to reduce weight as well as maintain the security of occupants. Stainless steels such as duplex steels are one of the most attractive candidates. Thus, metallurgical and mechanical behavior during resistance spot is important. The aim of this work is to study the microstructure-property relationships in resistance spot welding of duplex stainless steel. Austenite-ferrite phase balance and weld nugget size are two key factors determining the mechanical properties of these steels. High cooling rate of resistance spot welding can have a significant impact on the... 

    The Effect of Ultra-rapid Annealing on Microstructure and Mechanical Properties of Severely Deformed Low-carbon Steel

    , Ph.D. Dissertation Sharif University of Technology Mostafaei, Mohammad Ali (Author) ; Kazeminezhad, Mohsen (Supervisor)
    Abstract
    Severe plastic deformation (SPD) can refine microstructure of steel and increase its strain energy. Ultra-rapid annealing (URA) influences on the temperature and kinetics of recrystallization and transformation, and causes to improve the mechanical properties of steel. In this research, low-carbon steel with the average grain size of 80 μm was subjected to SPD using 2 passes of constrained groove pressing (CGP) method and its grains size is reduced to 30 μm. Ultra-rapid annealing with the reference heating rate of 200 oC/s was performed on SPDed steel up to subcritical and intercritical temperature ranges. Other heating rates of 75 oC/s to 1800 oC/s were performed for further examinations.... 

    Finite Size Effect in SLE(k,p)

    , M.Sc. Thesis Sharif University of Technology Amir Bagheri, Amir Ali (Author) ; Moghimi Araghi, Saman (Supervisor)
    Abstract
    Conformal Field Theory provides an efficient method for studying physical problems in critical point. Correlation length becomes converge in this point. It can also be clarified that some curves are observed in geometrical phase transition which are conformal invariant and they can be studied using SLE(k). The first mathematical generalization of SLE(k) while keeping the self-similarity property, leads to SLE(k,p). Conformal field theory and SLE are interrelated and their parameters are interpretable for each other. One usually studies the problem in the upper-half plane. Here we consider the problem using a map like (w=L/π Ln z) between the upper-half plane and a special region (e.g. a... 

    The effects of CaF2 in mica glass-ceramics

    , Article Defect and Diffusion Forum ; Volume 334-335 , 2013 , Pages 258-263 ; 10120386 (ISSN) ; 9783037856628 (ISBN) Ghasemzadeh, M ; Nemati, A ; Sharif University of Technology
    2013
    Abstract
    Different concentrations of CaF2 were incorporated in mica glass-ceramics to evaluate their effects on the crystallization and microstructure. The kinetics of phase transformations, and the microstructures of the final crystalline phase were found to be dependent on the concentration of nucleation agents. The results showed that CaF2 in high concentration had a synergistic effect and enhanced the formation of interlocked mica crystals. Non-isothermal DTA experiments showed that the crystallization activation energies of base glasses were changed in the range of 235-405 kJ/mol, while the crystallization activation energies of samples with addition of CaF2 were changed in the range of 419-747... 

    Kinetics and reaction mechanism of isothermal oxidation of Iranian ilmenite concentrate powder

    , Article Journal of Thermal Analysis and Calorimetry ; Volume 112, Issue 2 , 2013 , Pages 781-789 ; 13886150 (ISSN) Mozammel, M ; Sadrnezhaad, S. K ; Khoshnevisan, A ; Youzbashizadeh, H ; Sharif University of Technology
    2013
    Abstract
    Thermal oxidation of commercial ilmenite concentrate from Kahnouj titanium mines, Iran, at 500-950 C was investigated for the first time. Fractional conversion was calculated from mass change of the samples during oxidation. Maximum FeO to Fe2O3 conversion of 98.63 % occurred at 900 C after 120 min. Curve fit trials together with SEM line scan results indicated constant-size shrinking core model as the closest kinetic mechanism of the oxidation process. Below 750 C, chemical reaction with activation energy of 80.65 kJ mol-1 and between 775 and 950 C, ash diffusion with activation energy of 53.50 kJ mol-1 were the prevailing mechanisms. X-ray diffraction patterns approved presence of... 

    Effect of η phase on mechanical properties of the iron-based superalloy using shear punch testing

    , Article ISIJ International ; Volume 53, Issue 2 , 2013 , Pages 311-316 ; 09151559 (ISSN) Seifollahi, M ; Kheirandish, S ; Razavi, S. H ; Abbasi, S. M ; Sahrapour, P ; Sharif University of Technology
    2013
    Abstract
    In this paper, the shear deformation behavior of A286 Iron-based superalloy was studied with an emphasis on the influence of η phase on shear strength. The η (Ni3Ti phase precipitates at high temperature heat treatment or during services at the expense of gamma prime phase. According to the microstructural features, no evidences of η phase were found at 650 and 720°C. η phase precipitated at 780 and 840°C and the amount of it increased with an increase the time and temperature. Because of using the alloy as fasteners, investigation of shear properties and the influence of η phase on it are indispensable. The shear strength of the alloy with different volume fractions of η was examined. It... 

    On phase transformations in a Ni-based superalloy

    , Article Philosophical Magazine ; Volume 93, Issue 10-12 , Mar , 2013 , Pages 1351-1370 ; 14786435 (ISSN) Asgari, S ; Sharghi Moshtaghin, R ; Sadeghahmadi, M ; Pirouz, P ; Sharif University of Technology
    2013
    Abstract
    In this study, a particular nickel-based superalloy has been studied by transmission electron microscopy and the results are discussed in terms of phase transformations that may have taken place. The alloy has been found to consist of three major phases; a FCC γ phase containing a random distribution of nearly spherical γ′ - Ni3Al(Ti) - precipitates and elongated thin Ni3Ti(Ta) platelets with a hexagonal structure. The orientation relationships between the different phases have been determined; loss of coherency and possible occurrence of misfit-relieving interfacial dislocations are discussed and compared with experimental observations, and possible mechanisms of phase transformations are... 

    Microstructure and phase transformation behavior of a stress-assisted heat-treated Ti-Rich NiTi shape memory alloy

    , Article Journal of Materials Engineering and Performance ; Volume 21, Issue 8 , August , 2012 , Pages 1806-1812 ; 10599495 (ISSN) Ahadi, A ; Rezaei, E ; Sharif University of Technology
    Springer  2012
    Abstract
    In this study, the effects of stress-assisted heat treatment on the microstructure and phase transformation of a Ti-rich (Ti-49.52 at.% Ni) shape memory alloy were investigated. For this purpose, the alloy was heat treated at temperature of 500 °C for 10 h under applied stresses of 100 and 200 MPa. XRD, TEM, and repeated thermal cycling were employed to study the microstructure and transformation behavior of the heat-treated materials. Room temperature XRD diffractogram of the stress-free heat-treated material showed a weak reflection of austenite (B2), while that for the stress-assisted heat-treated materials had a high intensity implying the presence of residual austenite in the... 

    Modeling of austenite to ferrite transformation

    , Article Bulletin of Materials Science ; Volume 35, Issue 3 , 2012 , Pages 395-398 ; 02504707 (ISSN) Kazeminezhad, M ; Sharif University of Technology
    2012
    Abstract
    In this research, an algorithm based on the Q-state Potts model is presented for modeling the austenite to ferrite transformation. In the algorithm, it is possible to exactly track boundary migration of the phase formed during transformation. In the algorithm, effects of changes in chemical free energy, strain free energy and interfacial energies of austenite-austenite, ferrite-ferrite and austenite-ferrite during transformation are considered. From the algorithm, the kinetics of transformation and mean ferrite grain size for different cooling rates are calculated. It is found that there is a good agreement between the calculated and experimental results  

    The effect of TLP bonding temperature on microstructural and mechanical property of joints made using FSX-414 superalloy

    , Article Materials Science and Engineering A ; Volume 546 , June , 2012 , Pages 291-300 ; 09215093 (ISSN) Bakhtiari, R ; Ekrami, A ; Khan, T. I ; Sharif University of Technology
    2012
    Abstract
    The bonding temperature is an important parameter for optimization of the Transient Liquid Phase (TLP) bonding process in order to achieve a sound joint with good mechanical properties. However, the bonding temperature used can also be restricted by the microstructural stability of the base metal. In this study, the effect of bonding temperature (1050-1200 °C) on the joint microstructure and mechanical properties was studied for TLP bonding of FSX-414 superalloy using MBF-80 interlayer with thickness of 50 μm. Increasing bonding temperature from 1050 to 1150 °C caused reduction in the time required for complete isothermal solidification in agreement with models based on the diffusion induced... 

    Assembly of CeO 2-TiO 2 nanoparticles prepared in room temperature ionic liquid on graphene nanosheets for photocatalytic degradation of pollutants

    , Article Journal of Hazardous Materials ; Volume 199-200 , 2012 , Pages 170-178 ; 03043894 (ISSN) Ghasemi, S ; Setayesh, S. R ; Habibi Yangjeh, A ; Hormozi Nezhad, M. R ; Gholami, M. R ; Sharif University of Technology
    2012
    Abstract
    CeO 2-TiO 2 nanoparticles were prepared by the sol-gel process using 2-hydroxylethylammonium formate as room-temperature ionic liquid and calcined at different temperatures (500-700°C). CeO 2-TiO 2-graphene nanocomposites were prepared by hydrothermal reaction of graphene oxide with CeO 2-TiO 2 nanoparticles in aqueous solution of ethanol. The photocatalysts were characterized by X-ray diffraction, BET surface area, diffuse reflectance spectroscopy, scanning electron microscopy, and Fourier transformed infrared techniques. The results demonstrate that the room-temperature ionic liquid inhibits the anatase-rutile phase transformation. This effect was promoted by addition of CeO 2 to TiO 2.... 

    A phase-shift three-phase bidirectional series resonant DC/DC converter

    , Article IECON Proceedings (Industrial Electronics Conference), 7 November 2011 through 10 November 2011 ; November , 2011 , Pages 1137-1143 ; SSN :1553572X ; 9781612849720 (ISBN) Mirzahosseini, R ; Tahami, F ; Sharif University of Technology
    2011
    Abstract
    The demand for bidirectional DC/DC converters is increasing because of their potential capability for sustainable energy conversion systems where the power is to be captured from or stored in energy storage elements. This paper presents a three-phase series resonant bidirectional converter which is suitable for high power applications. The converter consists of two three-phase full bridge networks, the resonant tanks and a high frequency three-phase transformer. All switches can work either in ZVS or ZCS mode. The voltage drop on leakage inductances is minimized by choosing the switching frequency close to the resonant frequency, allowing high efficient power conversion. The phasor analysis... 

    Effect of Y2O3 and Er2O3 co-dopants on phase stabilization of bismuth oxide

    , Article Ceramics International ; Volume 37, Issue 8 , 2011 , Pages 3451-3455 ; 02728842 (ISSN) Arasteh, S ; Maghsoudipour, A ; Alizadeh, M ; Nemati, A ; Sharif University of Technology
    2011
    Abstract
    Bi2O3 compositions were prepared to investigate the effect of rare earth metal oxides as co-dopants on phase stability of bismuth oxide. Compositions containing 9-14 mol% of Y2O3 and Er2O3 were synthesized by solid state reaction. The structural characterization was carried out using X-ray powder diffraction. The XRD results show that the samples containing 12 and 14 mol% total dopants had cubic structure, whereas the samples with lower dopant concentrations were tetragonal. Comparing the lattice parameters of the cubic phases of (Bi 2O3)0.88(Y2O3) 0.06(Er2O3)0.06 and (Bi 2O3)0.86(Y2O3) 0.07(Er2O3)0.07 revealed that lattice parameter decreases by increasing the dopant concentration. The XRD... 

    A 3-D constitutive model for pressure-dependent phase transformation of porous shape memory alloys

    , Article Journal of the Mechanical Behavior of Biomedical Materials ; Volume 42 , 2015 , Pages 292-310 ; 17516161 (ISSN) Ashrafi, M. J ; Arghavani, J ; Naghdabadi, R ; Sohrabpour, S ; Sharif University of Technology
    Abstract
    Porous shape memory alloys (SMAs) exhibit the interesting characteristics of porous metals together with shape memory effect and pseudo-elasticity of SMAs that make them appropriate for biomedical applications. In this paper, a 3-D phenomenological constitutive model for the pseudo-elastic behavior and shape memory effect of porous SMAs is developed within the framework of irreversible thermodynamics. Comparing to micromechanical and computational models, the proposed model is computationally cost effective and predicts the behavior of porous SMAs under proportional and non-proportional multiaxial loadings. Considering the pressure dependency of phase transformation in porous SMAs, proper... 

    Welding metallurgy of stainless steels during resistance spot welding part II –heat affected zone and mechanical performance

    , Article Science and Technology of Welding and Joining ; Volume 20, Issue 6 , 2015 , Pages 512-521 ; 13621718 (ISSN) Alizadeh Sh, M ; Pouranvari, M ; Marashi, S. P. H ; Sharif University of Technology
    Maney Publishing  2015
    Abstract
    Implementation of new materials in automotive body-in-white requires through knowledge of their metallurgical response to welding process thermal cycle. This two-part paper aims at understanding the physical and mechanical metallurgy of stainless steels, as interesting candidates for automotive application, during resistance spot welding. The second part addresses the phase transformations in the heat affected zone of three types of stainless steels including austenitic, ferritic and duplex steels. Failure modes and mechanical properties of stainless steel resistance spot welds are discussed. The peak load and energy absorption of stainless steel resistance spot welds are compared with...