Sharif Digital Repository

In recent years, key questions about the interaction of 2D MXene nanomaterials in electrochemical and biomedical applications have been raised. Most research has focused on clarifying the exclusive properties of the materials; however, only limited reports have described the biomedical applications of 2D nanomaterials. 2D MXenes are monolayer atomic nanosheets resulting from MAX phase ceramics. The hydrophilic properties, metallic conductivity, stability, and exclusive physiochemical performances make them promising materials for electrochemical and biomedical applications, including CO2 reduction, H2 evolution, energy conversion and storage, supercapacitors, stimuli-responsive drug delivery... 

ABSTRACTs: The need for fully dense material with well-engineered microstructures has led to the promising emergence of innovative sintering technologies among which the Spark Plasma Sintering (SPS) is one of the most favorite. Unlike the conventional sintering processes, SPS takes advantage of a current flow passing through the sintering die and metallic powders by which fast densification with minimal grain growth and enhanced physicomechanical properties can be obtained. Albeit there is a growing interest in the exploitation of SPS in producing sufficiently consolidated metallic parts, no analytical review has been released over the effects of SPS parameters on the densification behavior,... 

In this work, sessile drop and low-bond axisymmetric drop shape analysis methods were coupled to provide some new aspects on stick-slip behavior as well as stick time of a drop on calcite surfaces. Slightly hydrophobic calcite surfaces typified with three irregular roughnesses were used to create irregular surfaces to mimic defects for the water-calcite-air systems. Polishing papers of 200, 600, and 1200 grit and a polishing machine were used to prepare surfaces. X-ray diffraction, energy dispersive X-ray spectroscopy, Fourier transform infrared, and atomic force microscopy techniques were employed to evaluate the chemical and physical properties of surfaces. A model was developed to predict... 

Effect of sandblasting of the copper electrode structures before deposition of gold thin film for micro electrical impedance tomography (EIT) system has been studied experimentally. The comparison has been performed on the unmodified copper electrodes and the sandblasted electrodes before deposition of gold layer, using structural analysis while their performance in EIT system has been measured and analyzed. The results of scanning electron microscopy and atomic force microscopy show that the sandblasting of the electrodes results in the deposition of gold film with smaller grain size and uniformly, comparing to the unmodified structure. The measurement of impedance shows that the... 

DeePore2 is a deep learning workflow for rapid estimation of a wide range of porous material properties based on the binarized micro–tomography images. By combining naturally occurring porous textures we generated 17,700 semi–real 3–D micro–structures of porous geo–materials with size of 2563 voxels and 30 physical properties of each sample are calculated using physical simulations on the corresponding pore network models. Next, a designed feed–forward convolutional neural network (CNN) is trained based on the dataset to estimate several morphological, hydraulic, electrical, and mechanical characteristics of the porous material in a fraction of a second. In order to fine–tune the CNN design,... 

Yttria-stabilized tetragonal zirconia polycrystals (Y-TZP) have been widely applied in fixed partial prostheses as well as dental uses i.e. a substructure for crowns. However, Y-TZP has limited applications, which is due to the presence of defects in its microstructure introduced during the manufacturing process. Accordingly, due to Y-TZP limitations, the novel (X)Y-TZP- 20Al2O3-(80-X) SiO2 (X = 65, 70 and 75) ceramic nanocomposites were successfully fabricated via the powder metallurgy method. X-ray diffraction (XRD) patterns of commercial powders showed the stabilization of monoclinic zirconia (ZM) by increasing the silica content. In order to determine the fracture load and micro-bending... 

N-annulated perylene based materials show outstanding and tunable optical and physical properties, making them suitable to be charge transport materials for optoelectronic applications. However, this type of materials has so far not been well studied in solar cells. Here, we develop a new hole transport material (HTM), namely S5, based on perylene building block terms, for organic-inorganic hybrid perovskite solar cells (PSCs). We have systematically studied the influences of the film thickness of S5 on their photovoltaic performance, and a low concentration of S5 with a thinner HTM film is favorable for obtaining higher solar cell efficiency. S5 shows excellent energy alignment with... 

A simple chemisorption method was used to graft on the surface of MWCNTs and Graphene nanoparticles to prepare stable kerosene-based MWCNTs and Graphene nanofluids. The prepared nanofluids remained stable for more than five months and no sedimentation was observed. Regarding the effect of temperature on thermo-physical properties, it was observed that although increasing nanoparticle concentration led to an increase in the fluid viscosity, it was negligible enough at lower nanoparticle loading. Moreover, adding nanoparticles to the base fluid did not have any noticeable impact on the fluid density which was negligible even at high concentrations. The thermal conductivity improvement was... 

In this study, the range of applicability for Cassie–Baxter and Wenzel equations for estimating apparent contact angle on rough surfaces is numerically discussed. To do this, circular drops with different sizes are simulated on rough surfaces with a square pillar pattern and randomly distributed cylindrical pillar. With the aid of numerical method, the local surface fraction, local length fraction and local roughness factor for drops with different sizes on the surface are computed. Then, the global surface fraction and global roughness factor have been compared with the local surface fraction and local roughness factor, respectively. Local surface and local length fractions, as well as... 

In this study, a novel pseudo-three-dimensional model is developed to find out both fluid and solid temperature distributions in multi-stream plate fin heat exchangers. In this simulation algorithm, heat exchangers can be in either parallel flow or cross flow configuration. The model considerations include: heat leakage of cap plates and side plates, conduction throughout the solid matrix of the heat exchanger, variable physical properties, and inlet mass flow rate maldistribution. Using the computational code, the effects of different factors such as: the number of layers, mass flow variation, inlet mass flow rate maldistribution, and stacking pattern on the thermal performance of the heat... 

Despite many efforts into the study of fluids interaction in low salinity water flooding, they are not probing the basics of transport phenomena between the involved phases. This work is aimed to bring new understanding of fluid–fluid interaction during low salinity water flooding through a series of organized experiments in which a crude oil sample with known properties was kept in contact with different brine solutions of various ionic strengths. Measuring brine pH, conductivity and crude oil viscosity and density for a period of 45 days illustrates the strong effect of the contact time and ionic strength on the dissociation of polar components and physical properties of the crude oil and... 

Purpose: This paper aims to numerically study the compositional flow of two- and three-phase fluids in one-dimensional porous media and to make a comparison between several upwind and central numerical schemes. Design/methodology/approach: Implicit pressure explicit composition (IMPEC) procedure is used for discretization of governing equations. The pressure equation is solved implicitly, whereas the mass conservation equations are solved explicitly using different upwind (UPW) and central (CEN) numerical schemes. These include classical upwind (UPW-CLS), flux-based decomposition upwind (UPW-FLX), variable-based decomposition upwind (UPW-VAR), Roe’s upwind (UPW-ROE), local Lax–Friedrichs... 

Despite many efforts into the study of fluids interaction in low salinity water flooding, they are not probing the basics of transport phenomena between the involved phases. This work is aimed to bring new understanding of fluid–fluid interaction during low salinity water flooding through a series of organized experiments in which a crude oil sample with known properties was kept in contact with different brine solutions of various ionic strengths. Measuring brine pH, conductivity and crude oil viscosity and density for a period of 45 days illustrates the strong effect of the contact time and ionic strength on the dissociation of polar components and physical properties of the crude oil and... 

This investigation presents both theoretical and experimental studies on the size of a growing bubble in power-law non-Newtonian liquids. At first, some previous works on the prediction of bubble size in Newtonian liquids have been extended by considering the balance of forces acting on the bubble at the moment of separation. Predicted bubble sizes were validated against the experimental results for a wide range of operating conditions, including different gas flow rates and needle diameters as well as a wide range of physical properties of the Newtonian liquids. Furthermore, in order to determine the size of the bubbles formed in power-law non-Newtonian liquids with a similar analysis, the... 

Nowadays, environmental hazards caused by plastic wastes are a major concern in academia and industry. Utilization of biodegradable polymers derived from renewable sources for replacing common petroleum-based plastics is a potential solution for reducing the problem. In this regard, starch has become one of the most promising alternatives to non-biodegradable polymers for depleting plastic waste thanks to its low expense, abundance, renewability and biodegradability. However, the main drawbacks of starch are its poor processability, weak mechanical properties and severe hydrophilicity. In this work, thermoplastic starch (TPS) samples have been prepared using glycerol and sorbitol as... 

In this paper an analytical approach to study the effect of the substrate physical properties on the kinetics of adhesion and motility behavior of cells is presented. Cell adhesion is mediated by the binding of cell wall receptors and substrate's complementary ligands, and tight adhesion is accomplished by the recruitment of the cell wall binders to the adhesion zone. The binders' movement is modeled as their axisymmetric diffusion in the fluid-like cell membrane. In order to preserve the thermodynamic consistency, the energy balance for the cell-substrate interaction is imposed on the diffusion equation. Solving the axisymmetric diffusion-energy balance coupled equations, it turns out that... 

Naturally fractured reservoirs (NFRs) contribute in large extent to oil and gas production to the ever increasing market demand of fossil energy. It is believed that the vertical displacement of oil during gas injection assisted by gravity drainage (GAGD) is one of the most efficient methods for oil recovery in these reservoirs. Hence, in this work, unconsolidated packed models of cylindrical geometry surrounded by fracture were utilized in order to perform a series of flow visualization experiments during which the contribution of different parameters such as the extent of matrix permeability, physical properties of oil (viscosity, density, and surface tension) and the withdrawal rate was... 

The laser forming process is one of the last technologies on forming of sheet metals with laser beam heat distribution. In this process laser beam moves across the top surface of the sheet metal and the heated zone expands and causes a great moment that deforms the sheet metal. Subsequently, the heated zone gets cooled and provides a reverse strain and moment. The final bending angle is a combination of two phases. Due to the complexity of the process, it is studied with different approaches; FEM analysis and analytical as well as empirical methods. The laser forming is a sensible process regarding the material properties. Also, because of the temperature change during the process, it is... 

In the present study, a prediction model was derived for the effective angle of shearing resistance (φ′) of soils using a novel hybrid method coupling genetic programming (GP) and orthogonal least squares algorithm (OLS). The proposed nonlinear model relates φ′ to the basic soil physical properties. A comprehensive experimental database of consolidated-drained triaxial tests was used to develop the model. Traditional GP and least square regression analyses were performed to benchmark the GP/OLS model against classical approaches. Validity of the model was verified using a part of laboratory data that were not involved in the calibration process. The statistical measures of correlation... 

In this study, the local composition based models such as the Wilson, the nonrandom two-liquid (NRTL), and the Wilson-NRF have been applied in correlation and estimation of density, viscosity, and surface tension of biodiesels. The thermodynamic models have been used in correlating the thermophysical properties for 215 experimental data points. These models have the interaction energy between each pair that is considered as adjustable parameters. To decrease the number of these adjustable parameters, it is assumed that the biodiesels are composed of two hypothetical components. The average absolute deviation (AADs) of the correlated density of biodiesels for the Wilson, the NRTL, and the...