Sharif Digital Repository

Considering the operation of the current nuclear reactors and the country's policy to achieve 10,000 megawatts of nuclear power in the horizon of 1420, as well as the construction of research reactors, we will face a huge amount of radioactive waste in the coming years. Meanwhile, spent ion exchange resins constitute a large amount of low and intermediate level (LILW) solid radioactive waste produced from the nuclear industry. Therefore, appropriate precautionary measures should be taken for the immobilization and disposal of these radioactive wastes in order to ensure the sustainable development of the nuclear industry and the protection of the environment and human health. In this study,... 

The current study was attributed to uranium uptake by Varion-AP resin from Saghand, Iran Uranium Mine, ore leach liquor. A suitable high-efficiency system was designed for continuous ion exchange at the bench scale and the uranium uptake parameters were optimized. In this system, 1 reactors was used with a volume of 3 liters in stage with the same height difference. A leach liquor containing uranium with a concentration of between 200 and 300 mg/l was flowed from the feed storage by gravity between reactor 1 to 10 at a flow rate of 30 lit/h and Varion-AP resin was transferred in counter-current flow from stage 10 to 1 by a pneumatic pump. The output of each reactor had a screener that... 

Ion exchange resins are widely used in nuclear industries. These spent resins result in the production of a large amount of low and intermediate level radioactive wastes, therefore, the treatment and immobilization of spent ion exchange resins are the major problems in the development of nuclear power plants.In this research, in a laboratory scale, we tried to find the suitable procedure and formulation to immobilize a specific group of cation-exchange resins which is used in Bushehr nuclear power plant (AMBERLITE IRN-97H) in the cement matrix. The solidification matrix consists of five constituents: anti sulfate slag type portland cement, cation-exchange resins, diatomite, sodium hydroxide... 

In this study, uranium removal from phosphoric acid with doulite resin was examined. Different uptake properties of the doulite resin were examined using batch, stirred and column methods. Langmuier, freundlich and dubinin equation was fitted the isotherm data and freundlich equation showed the best fitting. Adsorption kinetics was controlled by slow intraparticle diffusion of UO22+ ions in resin, and it obeyed a shrinking core model. Also a pseudo-second order chemical reaction fairly fitted the kinetics data  

One of the common and efficient methods in the construction of large-scale structures from composites is the Vacuum Assisted Resin Transfer Molding (VARTM) method, which is widely used in the automotive industry, wind turbine blades, warships and pleasure boats, etc. VARTM is one of the liquid molding methods in which one side of the closed mold is replaced with a vacuum bag and the resin flows into the mold only with the help of air pressure (pressure of one atmosphere). One of the main challenges in the vacuum resin molding process is to be aware of the physics governing the flow motion in the porous mold so that the dry spots formed in the mold can be located accordingly. On the other... 

This project has been carried out to investigate the feasibility of using thermoplastic materials in constructing large wind turbine blades made of composite materials. By proving the similarity of the mechanical behavior of blades made of thermoplastic and thermosetting composite materials, the possibility of using these materials with better recycling capabilities has been studied. By studying different thermosetting and thermoplastic resins and checking the Processing methods and mechanical properties of thermoplastic resins, the materials for blades have been selected. The suitable manufacturing method for producing large blades with dimensions above 30 meters is the vacuum-assisted... 

In recent years, liquid resin injection processes for aviation applications have been considered an alternative to conventional autoclave-based processes. At present, these processes have challenges that have been denied industry trust due to their inability to be objectively reproducible. In the last decade, some software has been developed to simulate the vacuum injection process, but this software does not have enough capability to predict the injection network, and an operator with sufficient empirical knowledge must use this software. In recent years, researchers have used this softwares to simulate the process, but so far no software has been developed that can offer injection... 

In this study composite is built based on epoxy which is reinforced with 3D graphen foam using the RTM (resin transfer molding) method in which the molding is done by hand, through injecting epoxy to graphen foam.Good scattering and neat meshing of 3d graphen planes in composite have resulted in its improved mechanical quilities.The subject of the present study is the synthesis of graphen foam from graphen oxide and making graphen foam/epoxy composite in order to improve its mechanical properties. In order to do that, firstly graphen foam is forged from graphen oxide in a 3d mesh, in a way that single graphen planes in polymer matrixes are eliminated.Having very little density, very high... 

Nowadays, composites have wide applications in different industries especially in aerospace industry because of their high strength to weight ratio. Epoxy 5052 for its relatively good mechanical properties and high thermal resistance has vaidly use for manufacturing of large composite components. However; fracture toghness of epoxy resins is not good in comparison to their other exceptional properties. Therefore, researchers have endeavored to improve this characteristic with different approaches. One of these methods is nanotechnology. Since the components in aerospace industry are often under impact loads and impact strength of these materials has been less studied, effect of carbon... 

Resin Transfer Molding (RTM) which is one of the categories of Liquid Composite Molding (LCM) process, is considered as one of the most important process in polymer composite manufacturing. To improve this manufacturing method and reaching higher qualities, numerous modified methods has been developed. One of these modified methods is Vaccum Assisted Resin Trasnfer Molding with Flexible Tooling which is considerably applicable in manufacturing parts with high quality, large and complex geometry. Although, this manufacturing method has variety of advantages, there are some problems such as void formation making production difficult and dependent to experimental trial and error. So numerical... 

Here, we have simulated isothermal vacuum assisted resin transfer moulding (VARTM) using a control volume/finite element scheme. Two dimensional and dimensional (shell geometries) spatial discretization is used. Resin motion through fibers is enforced by vacuum negative pressure in downstream. The governing equations are mass conservation and well known Darcy equation. Using an unstructured triangular grid, complex geometries could be modelled. Application of a quasi-steady algorithm results in a system of linear equation for pressure distribution. This system must be solved in each time step. The point successive over-relaxation (PSOR) scheme is used to solve the system of linear... 

Because of increasing usage of modified polymers and consequent necessity for investigation and modeling of mechanical behavior of these materials, it is important to get a yield criterion for these materials. For this purpose the Gurson yield criterion presented for porous metals, was modified with regard to mechanical properties of polymers. Indeed pressure sensitivity of polymers and their large elastic strain during deformation, makes using of Gurson yield criterion problematic for modified polymers.
For modification of Gurson criterion, macroscopic hydrostatic yield stress equation was derived for a thick-walled spherical shell of epoxy and then Gurson criterion was modified with... 

The repair of pipes that deteriorate over time or due to various factors is a critical issue in engineering. Consequently, effective and novel repair methods, especially using FRP (Fiber-Reinforced Polymer) composites, have gained significant importance. In this research, the repair and connection of pipes using FRP are examined. In the pipe repair section, through hydrostatic testing, various factors such as the damaged area, the number of sharp corner points, the width of the sheets, the number of layers, and the pre- stress condition of the FRP are studied for their impact on the pipe's ultimate pressure tolerance. Also, in the pipe connection section, with hydrostatic tests, the ultimate... 

Due to population growth, the demand for water supply has increased. This need has drawn attention to the use of consumed and treatable water resources. Organic pollutants are a key source of water pollution. On the other hand, petrochemical oil pollution and frequent oil accidents during oil production or maritime transport have become one of the environmental problems.There are different methods for water and oil separation and water purification that in the present project, selective separation can be achieved by using hydrophobic materials and surface roughness and creating surfaces with two properties: superhydrophobic and ultra-oil friendly. This method is also very effective, cheap... 

Nowdays, one of the most important concerns for scientists is increasing CO2 emmisions and global warming. To overcome this problem, a large number of studies have been carried out to improve energy system performance and reducing the overall energy consumption. One solution to this problem is using the superhydrophobic surfaces with contact angle larger than 150°.In this study, we try to reduce the pressure drop through the galvanized pipes. So, by reducing the pressure drop, power required for pumps can be reduced. To this end, two different coatings by silica nano-particles which were modified with first hydrophobic agent are used. In first coating which is named as PS coating, stearic... 

With increasing awareness, artificial materials have been replaced by recyclable materials and green materials. In the manufacture of composites, natural and degradable materials are also used. The main object of this research is the fabrication of natural fiber reinforced composites. In this research, fibers are used that are cultivated in the country. Also, the effect of fiber length, fiber mass percentage and fiber correction on composite properties was investigated. The fiber length factor is at two levels of 5 mm and 9 mm, the percentage of fiber mass is in four levels of 5%, 10%, 12.5% and 15%, and the factor for correction of fibers is also in two groups of modified fibers and... 

The use of Vacuum Infusion Process (VIP) in some industries , to achieve optimal injection strategy is based on trial and error and it comes to the production of defective and unusable parts.The main problem is that no resin penetrate in some areas and creat dry spots and unsaturated resin regions Because of inadequate or incorrect positioning of the resin inlet and air outlet.Simulation is a powerful tool for understanding and identifying the behavior of resin flow and thereby save time and cost.In this research,in order to avoid the empirical testing of different injection techniques and avoid wasting time and cost in traditional methods of trial and error,the use of vacuum... 

Polypropylene (PP) is one of the most widely used commercial plastics in various industrial applications due to its desirable physical and mechanical properties and low cost. Engineering properties of this polymer depend very much on its crystalline structure. It is a common practice in polymer industry to modify crystalline structure by means of nucleating agents. Since nucleating agents are added in a rather low level to polymers, some investigators have tried this task in modifying crystalline structure of polypropylene by incorporating nucleating agent masterbatches. However, none have looked at the possible influence of the carrier resin in such masterbatches on the performance of... 

Epoxy resins are used for a wide number of application due to good stiffness, chemical resistant and dimensional stability. This is the reason of their use as matrix in composite material. The incorporation of a small amount of carbon nanotubes (CNTs) in epoxy increases mechanical properties if nanocomposite have strong interfacial interaction between epoxy and CNTs, fine dispersion of CNTs and high final aspect ratio CNTs. In Noncovalent functionalization by polymer surfactant, CNTs are dispersed in a solvent/surfactant solution by ultra-sonication and then added to epoxy. In this thesis a novel study of toughening and mechanical properties of epoxy/ rubber/ CNT nanocomposite is presented.... 

Epoxy resins are relatively brittle and have low resistance to crack propagation. It is common to add rubber particles to improve crack resistance in epoxies, although these particles may deteriorate the strength of the matrix. Different nanomaterials are used to overcome the inherent brittleness of epoxies and to keep the mechanical properties. Among them, carbon nanotubes has been attracted many attentions. Fractue behavior and mechanical properties of two kind of novel nanocomposites, i.e, epoxy/carbon nanotube and epoxy/rubber/carbon nanotube are investigated in current study. Electron microscopy investigations were done to assure the CNTs distribution and fracture mechanisms as well....