Sharif Digital Repository

In this work, a newly formulated sulfonate-based surfactant and two other commercial sulfate-based surfactants with the capability of tolerating harsh underground reservoir conditions, such as high-saline formation water and high temperature, were prepared. Sodium metaborate as an effective alkali compound was also used to provide alkali-surfactant combination. Interfacial tension (IFT) measurements as well as wettability examinations for different salinities and mixture conditions were performed for an extended range of the chemical concentrations. The wettability tests including both contact angle measurements and Amott cell tests were performed on saturated Berea sandstone plug samples... 

Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

A newly-designed surfactant was formulated to tolerate the harsh conditions of oil reservoirs, including high salinity of the formation brine and temperature. The specific emulsion and interfacial tension (IFT) behavior of this new surface active agent were investigated by performing emulsion stability tests, emulsion size analysis, and IFT behavior in the presence of four different types of alkalis. Image processing was utilized to analyze the droplet size distribution using microscopic images of the samples. The results show that depending on the composition of the mixtures, the optimum phase region and interfacial tension behavior change considerably. Solutions containing a higher... 

The use of adjusted/optimized saline water categorized into two different classes namely smart water (SW) and low salinity (LoSal) water injection has been proposed for more oil recovery from specific types of oil reservoirs. There are possible mechanisms concerning SW flooding that have been proposed in the literature, some of them are still subject to more examination. In this study, an experimental investigation is performed to determine the influence of type and amount of salt to the surface properties including interfacial tension (IFT) and contact angle (CA) of aqueous solution + acidic and asphaltenic crude oil + carbonate rock systems. For this purpose, the concentration of different... 

Understanding the fresh groundwater lens (FGL) behavior and potential threat of climatic-induced seawater intrusion (SWI) are significant for the future water resources management of many small islands. In this paper, the FGL of Kish Island, an arid-region case in the Persian Gulf, Iran, is modeled using two-dimensional (2D) and three-dimensional (3D) simulations. These simulations are based on the application of SUTRA, a density-dependent groundwater numerical model. Also, the numerical model parameters are calibrated using PEST, an automated parameter estimation code. Firstly a detailed conceptualization of the FGL model is completed to understand the sensitivity of the FGL to some... 

The main objective of this paper is to provide comparative quantitative examinations on the capabilities of two-dimensional horizontal and pseudo-three-dimensional (3D) modelling approaches for simulating spatial and temporal variability of the flow and salinity in Lake Urmia, Iran. The water quality in the lake has been an environmentally important subject partly because this shallow hypersaline aquatic ecosystem is considered to be one of the largest natural habitats of a unique multicellular organism, Artemia urmiana. This brine shrimp is the major food source for many of the protected and rare shorebirds that visit the lake. A.urmiana can grow and survive in certain ranges of salinity,... 

Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

In salting-out liquid-liquid extraction (SALLE) technique, water-miscible organic solvents are used for extraction of polar analytes from saline solutions. In this study, for the first time, a coupled 1-mL syringes system was utilized to perform a miniaturized SALLE method. Sulfanilamide antibiotic was extracted and determined via the developed method followed by high performance liquid chromatography-ultraviolet detection (HPLC-UV). The extraction process was carried out by rapid shooting of acetonitrile as extraction solvent (syringe B) into saline aqueous sample solution (syringe A), and then the shooting was repeated several times at a rate of 1 cycle s-1. Thereby, an extremely large... 

In this paper we examine how exchange flow in Urmia Lake plays a crucial role in dynamics of the lake. Urmia Lake, a very large hyper-saline lake of high ecological significance, is located in northwest of Iran with a 15-km causeway dividing it into north and south lakes. A 1250-m opening in the causeway near the east coast links the two lakes. The differences in mean water levels and densities of the two lakes increase in spring due to large freshwater inflows into the south lake. High evaporation dominates the lake in summer. By incorporating the results of a two-layer hydraulics theory into a mixing model of the lake, we show that the exchange flow through the opening diminishes the water... 

In this study, the performance of an aerobic moving bed biofilm reactor (MBBR) was assessed for the removal of phenol as the sole substrate from saline wastewater. The effect of several parameters namely inlet phenol concentration (200-1200 mg/L), hydraulic retention time (8-24 h), inlet salt content (10-70 g/L), phenol shock loading, hydraulic shock loading and salt shock loading on the performance of the 10 L MBBR inoculated with a mixed culture of active biomass gradually acclimated to phenol and salt were evaluated in terms of phenol and chemical oxygen demand (COD) removal efficiencies. The results indicated that phenol and COD removal efficiencies are affected by HRT, phenol and salt... 

The implementation of Monte Carlo simulations (MCSs) for the propagation of uncertainty in real-world seawater intrusion (SWI) numerical models often becomes computationally prohibitive due to the large number of deterministic solves needed to achieve an acceptable level of accuracy. Previous studies have mostly relied on parallelization and grid computing to decrease the computational time of MCSs. However, another approach which has received less attention in the literature is to decrease the number of deterministic simulations by using more efficient sampling strategies. Sampling efficiency is a measure of the optimality of a sampling strategy. A more efficient sampling strategy requires... 

Movement and transportation of fine particles in formations leads to clogging the pores and reduction in permeability. This type of formation damage is stronglycontingent upon water salinity and ionic conditions in the formation. The main parameters which control the particle release are the interactions and forces between particles and porous medium surfaces. Changing salinity which leads to pH alteration, affects these interactions and subsequently the fine migration process. Hence, pH and salinity variations should be considered to study and evaluate the portion of fine migration in formation damage. The principal challenge in this research therefore, is to try to change the surface... 

A number of challenges including instability, nonconvergence, nonuniqueness, nonoptimality, and lack of a general guideline for inverse modelling have limited the application of automatic calibration by generic inversion codes in solving the saltwater intrusion problem in real-world cases. A systematic parameter selection procedure for the selection of a small number of independent parameters is applied to a real case of saltwater intrusion in a small island aquifer system in the semiarid region of the Persian Gulf. The methodology aims at reducing parameter nonuniqueness and uncertainty and the time spent on inverse modelling computations. Subsequent to the automatic calibration of the... 

Remote sensing is an effective tool for capturing spatial and temporal variations of water surface temperature (WST) in large lakes. The WST of Urmia Lake in northwestern Iran was examined from 2007 to 2010, using MODIS land surface temperature (LST) products. Spatial and temporal (diurnal, monthly, seasonal and inter-annual) variations of Urmia Lake WST were also investigated. Results indicate that the MODIS-derived WSTs are in a good agreement with the in situ data (R2=0.92 and bias=-0.27). Spatial analysis of WST revealed that there are three thermal zones along the lake: the shallow region in barriers of the causeway, islands and the shoreline; the south part; and the deep north parts.... 

Microscopic and macroscopic displacements of polymer flooding to heavy oil at various levels of salinity and connate water saturation have been investigated. Both oil-wet and water-wet conditions in fractured five-spot micromodel systems, initially saturated with the heavy crude oil are utilized. The primary contribution is to examine the role of salinity, wettability, connate water, and fracture geometry in the recovery efficiency of the system. The microscopic results revealed that the increase in the connate water saturation decreases the oil recovery, independent of the wettability conditions. Moreover, the increase in salinity of the injected fluids lowers the recovery efficiency due to... 

Urmia Lake in the northwest of Iran is the second largest hyper-saline lake worldwide. During the past two decades, a significant water level decline has occurred in the lake. The existing estimations for the lake water balance are widely variable because the lake bathymetry is unknown. The main focus of this study is to extract the volume-area-elevation (V-A-L) characteristics of Urmia Lake utilizing remote sensing data and analytical models. V-A-L equations of the lake were determined using radar altimetry data and their concurrent satellite-derived surface data. Next, two approximate models, a power model (PM) and a truncated pyramid model (TPM), were parameterized for Urmia Lake and... 

In order to evaluate the long-term viability, the iron content stability, and the labeling efficiency of mammalian cells using magnetic cell labeling; dextran-coated ultrasmall superparamagnetic iron oxide (USPIOs) nanoparticles with plain surfaces having a hydrodynamic size of 25 nm were used for this study. Tests were carried out in four groups each containing 5 flasks of 5.5 × 10 6 AD-293 embryonic kidney cells. The cell lines were incubated for 24 h using four different iron concentrations with and without protamine sulfate (Pro), washed with phosphate-buffered saline (PBS) and centrifuged three times to remove the unbounded USPIOs. Cell viability was also verified using USPIOs. There... 

Due to the hopeful potential of nanoparticles in medicine, they have attracted much attention for various applications such as targeted drug/gene delivery, separation or imaging. Interaction of NPs with the biological environment can lead to a wide range of cellular responses. In order to have safe NPs for biomedical applications, the current biocompatibility researches are particularly focused on the severe toxic mechanisms which cause cells death. These mechanisms are apoptosis, autophagy and necrosis, which can also be intricately linked with the cell-life cycle, as there are various check-points and controls in a cell's life cycle to ensure appropriate division processes. Mechanisms by... 

This work concerns with experimental investigation of CO2 WAG injection to light crude oil in near miscible conditions which has been rarely attended in the available literature. Here, several core flood experiments at three constant injection rates and four WAG ratios are conducted on sandstone rocks saturated with light crude oil in presence of saline water. The results showed that higher injection rate has a better performance regarding oil recovery for smaller PVs of injected fluids, while lower injection rate showed higher ultimate recovery for a 30% increase in injected PVs. Secondary continuous gas injection showed a superior performance than all the other WAG injections in different... 

Dissolved air precipitation/solvent sublation (DAP/SS) was used for treatment of simulated and real oilfield produced water to generate very fine bubbles which are necessary for effective separation. In this method micro bubbles produced by saturation of air in a pressurized packed column were released in an atmospheric column leading the bubbles to raise resulting trapped contaminants in the Gibbs layer around them to be removed by a layer of immiscible solvent at the top of column. The method was conducted to solutions including Benzene, Toluene and Chlorobenzene (ClB) as part of BTEX contaminants in produced water, mixture of them as simulated produced water and real oilfield produced...