Sharif Digital Repository

Today, regarding the limitation and environmental side effects of fossil fuel resources, solar hydrogen production is one of the main interests in the energy research area. The development of visible light sensitized semiconductors based on non-toxic components, low cost and available bio-species is an ongoing approach for H2 generation based on water splitting reactions. Here, two different morphologies of TiO2 photoanodes, nanoparticulated and nanotubular, have been modified with simply extracted bacteriorhodopsin (bR) without any linker. Achieving a significant enhancement in photoconversion efficiency of TiO2 photoanodes, η% was increased from 2.9 to 16.5 by bR addition to the TiO2... 

Nanoparticulated TiO 2 fibers as one-dimensional long structures were introduced into TiO 2 P25 nanoparticle films using coelectrophoretic deposition. This prevented the usual crack formation occurring in wet coatings, and resulted in less porosity and higher roughness factor of the films that provided more favorable conditions for electron transport. The films used as the photoanode of a dye solar cell (DSC) produced 65% higher photovoltaic efficiency. TiO 2 fibers can be excellent binders in single-step, organic-free electrophoretic deposition of TiO 2 for DSC photoanode  

Stirling engines operate in a variety of temperatures and the electric power production via dish Stirling systems could be considered as an appropriate alternative for high-temperature solar concentrator energy harvesting systems. To this end, by performing various studies and analyses on the engine, Stirling cycle, and heat exchangers while utilizing the solar energy as the input thermal energy of the Stirling engine, parameters with the highest effect on the output power and engine stability are detected and considered as optimization variables. In this case, output power, thermal efficiency, and economic evaluation are taken to be the three suitable objective functions for multi-objective... 

Stirling engines operate in a variety of temperatures and the electric power production via dish Stirling systems could be considered as an appropriate alternative for high-temperature solar concentrator energy harvesting systems. To this end, by performing various studies and analyses on the engine, Stirling cycle, and heat exchangers while utilizing the solar energy as the input thermal energy of the Stirling engine, parameters with the highest effect on the output power and engine stability are detected and considered as optimization variables. In this case, output power, thermal efficiency, and economic evaluation are taken to be the three suitable objective functions for multi-objective... 

In manufacturing amorphous silicon solar cells, thin films are deposited at high temperatures (200-400 °C) on a thick substrate using sputtering and plasma enhanced chemical vapor deposition (PECVD) methods. Since the thin films and substrate have different thermal expansion coefficients, cooling the system from deposition temperature to room temperature induces thermal residual stresses in both the films and substrate. In addition, these stresses, especially those having been induced in the amorphous silicon layer can change the carrier mobility and band gap energy of the silicon and consequently affect the solar cell efficiency. In this paper, a 2D finite element model is proposed to... 

Solar energy exists extensively in all parts of the world. However the intermittency of solar energy presents critical challenges to PV system. The intermittency can be covered by storing solar energy in chemical bonds such as hydrogen. This process can be performed by photovoltaic powered electrolysis of water. The energy transfer efficiency between PV and electrolyzer is subject to the distance between maximum power points (MPP) of PV module and operating points. The operating points can be adjusted by optimizing the design parameters of the electrolyzer but the maximum power points are function of PV module characteristics, solar radiation and ambient temperature. Therefore the weather... 

The effect of substitutional Li doping into NiOx hole transporting layer (HTL) for use in inverted perovskite solar cells was systematically studied. Li doped NiOx thin films with preferential crystal growth along the (111) plane were deposited using a simple solution-based process. Mott-Schottky analysis showed that hole carrier concentration (NA) is doubled by Li doping. Utilizing 4 % Li in NiOx improved the power conversion efficiency (PCE) of solar devices from 9.0 % to 12.6 %. Photoluminescence quenching investigations demonstrate better hole capturing properties of Li:NiOx compared to that of NiOx, leading to higher current densities by Li doping. The electrical conductivity of NiOx is... 

In order to achieve the international climate goals and to keep the global temperature increase below 2 °C, carbon capture and storage in large point sources of CO2 emissions has received considerable attention. In recent years, mitigation of CO2 emissions from the power sector has been studied extensively whereas other industrial point source emitters such as hydrogen industry have also great potential for CO2 abatement. This study aims to draw an updated comparison between different hydrogen and power cogeneration systems using natural gas and coal as feedstock. The goal is to show the relative advantage of cogeneration systems with respect to CO2 emission reduction costs. Accordingly, the... 

The techno-economic and environmental performance of hybrid solar hydrogen energy systems was investigated to provide combined cooling, heating and power (CCHP) demands of a standalone greenhouse in Iran to achieve sustainable agriculture based on an optimization procedure. From the environmental point of view, by deploying hybrid energy systems, 83%, to 100% of emissions can be avoided. Also a sensitivity analysis was performed on the hybrid energy systems in order to study the effect of major parameter variation on the systems justification. It was concluded that hybrid solar systems are economically competitive with conventional systems, for high solar intensity locations with high diesel... 

The combination of concentrating photovoltaic (CPV) and organic Rankine cycle (ORC) systems not only leads to a reduction of photovoltaic (PV) operating temperature, but also leads to an additional electric power production. Increase in the temperature of the PV decreases its operating efficiency, while increases the ORC efficiency. Therefore, there is an optimum temperature in which the total electricity produced by the combined system will be maximum. In this study, a modified CPV/ORC system is simulated and the optimum operating temperature of the PV panel is determined for different PV efficiencies. The most striking result is that increase in the PV nominal efficiency will result in the... 

The combination of concentrating photovoltaic (CPV) and organic Rankine cycle (ORC) systems not only leads to a reduction of photovoltaic (PV) operating temperature, but also leads to an additional electric power production. Increase in the temperature of the PV decreases its operating efficiency, while increases the ORC efficiency. Therefore, there is an optimum temperature in which the total electricity produced by the combined system will be maximum. In this study, a modified CPV/ORC system is simulated and the optimum operating temperature of the PV panel is determined for different PV efficiencies. The most striking result is that increase in the PV nominal efficiency will result in the... 

Solar energy generation is one of the most efficient approach to solve emerging environment and energy challenges. In this context, solar assisted dissociation of water into oxygen and hydrogen utilizing scalable and high performance electrocatalysts plays key role since the produced hydrogen is a clean energy carrier. Here, cobalt based nanoflakes with metallic core and oxidized surface were grown on the designed carbonaceous layer for anodic oxygen evolution reaction (OER) using an electrochemical approach. Carbonaceous layers containing proper amount of carbon nanotubes (CNT) and reduced graphene oxide (rGO) species were used to optimize the system. Although higher weight percent of rGO... 

In dye-sensitized solar cells recombination reactions at the TiO2 photoanode with the electrolyte interface plays a critical role in cell efficiency. Recombination of injected electrons in the TiO2 with acceptors in the electrolyte usually occurs on uncovered areas of TiO2 surfaces. In this work, we report electropolymerization of polymer films on nanoporous TiO2 electrode surfaces using an ionic liquid as the growth medium. The choice of ionic liquid as the growth medium for this study is based on the insolubility of dye N719 in this electrolyte, thus avoiding dye molecule detachment from the TiO2 photoanode surface over the entire potential range investigated during the... 

Hybrid perovskite solar cells (PSCs) have gained significant attention owing to their excellent physicochemical and photovoltaic properties. PSCs typically consist of a perovskite light absorber sandwiched between two carrier selective layers optimized with respect to optimal band alignment and low interfacial recombination. The quality of the perovskite layer and interfaces play major roles in the fabrication of high-performance PSCs. In the present work, we systematically investigate the planar structure PSCs based on TiO2 and TiO2/ZnO electron transport layers (ETLs), which provide deeper insight into the charge recombination and accumulation mechanisms. We show that the double-layer... 

Colloidal quantum dot solar cells have recently attracted significant attention due to their low-processing cost and surging photovoltaic performance. In this paper, a novel, reproducible, and simple solution-based process based on supercritical fluid toluene is presented for in situ growth and deposition PbS nanocrystals with oleic-acid passivation. A lead precursor containing sulfur was mixed with oleic acid in toluene and processed in a supercritical fluid condition at different temperatures of 140, 270 and 330 °C for 20 min. The quantum dots were deposited on a fluorine-doped tin oxide glass substrate inside the supercritical reactor. Transmission electron microscopy, X-ray diffraction,... 

Enhancing stability against photocorrosion and improving photocurrent response are the main challenges toward the development of cupric oxide (CuO) based photocathodes for solar-driven hydrogen production. In this paper, stable and efficient CuO-photocathodes have been developed using in situ materials engineering and through gold-palladium (Au-Pd) nanoparticles deposition on the CuO surface. The CuO photocathode exhibits a photocurrent generation of ∼3 mA/cm2 at 0 V v/s RHE. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis and X-ray spectroscopy (XPS) confirm the formation of oxygen-rich (O-rich) CuO film which demonstrates a highly stable photocathode with retained... 

Challenging problems in the design and analysis of photovoltaic (PV) systems stem from the nonlinear current–voltage (I–V) characteristics of solar cells. This paper presents an analytical analysis based on a describing function method to investigate the transient and steady-state characteristics of a three-phase single-stage grid-connected PV system. In this study, the nonlinear I–V characteristic of the PV array is linearized around the operating point. The nonlinear dynamic of the maximum power point tracking controller is divided into two parts of continuous and discrete. For the continuous part, the common small-signal linearization is applied, while for the discontinuous part, a... 

Stand-alone hybrid power systems are an alternative to main electricity grids, where the grid extension is costly or the trifling local consumption would not justify its expansion. However, lack of consistency and uniformity in renewable energy sources, and the restrictions of energy storage systems make system sizing a challenging task. Optimum size of a stand-alone system depends on several factors including energy demand function. In this paper, different types of demand functions are addressed for optimising a solar-hydrogen supply system. Different parameters are defined to investigate the impact of household population on the power generation cost, and also to determine the optimum... 

Stand-alone hybrid power systems are an alternative to main electricity grids, where the grid extension is costly or the trifling local consumption would not justify its expansion. However, lack of consistency and uniformity in renewable energy sources, and the restrictions of energy storage systems make system sizing a challenging task. Optimum size of a stand-alone system depends on several factors including energy demand function. In this paper, different types of demand functions are addressed for optimising a solar-hydrogen supply system. Different parameters are defined to investigate the impact of household population on the power generation cost, and also to determine the optimum... 

Stand-alone hybrid power systems are an alternative to main electricity grids, where the grid extension is costly or the trifling local consumption would not justify its expansion. However, lack of consistency and uniformity in renewable energy sources, and the restrictions of energy storage systems make system sizing a challenging task. Optimum size of a stand-alone system depends on several factors including energy demand function. In this paper, different types of demand functions are addressed for optimising a solar-hydrogen supply system. Different parameters are defined to investigate the impact of household population on the power generation cost, and also to determine the optimum...