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    Predictions of Formation Damage Due to Inorganic Scale Deposition during Water Injection in Oil Reservoirs Using Experimental-Based Mathematical Modeling

    , M.Sc. Thesis Sharif University of Technology Rahbari, Mohammad Reza (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Water flooding is known as a common method to maintain reservoir pressure/enhance oil recovery. The major problem in this process induced from inorganic deposits that caused formation damage around wellbore region. It is due to incompatible nature of injected and formation water which results in permeability reduction and well productivity decrease. Solving this problem is an important issue in the petroleum industry. BaSO4, CaSO4 and SrSO4 are inorganic sediments formed in this process. The physical model of water transport in reservoir and scaling damage due to sediments contains at least two dominant parameters; the kinetics coefficient that specifies the velocity of chemical reaction,... 

    Synthesis and Characterization of TiO2 Nanoparticles for Enhanced Oil Recovery Applications

    , Ph.D. Dissertation Sharif University of Technology Ehtesabi, Hamide (Author) ; Taghikhani, Vahid (Supervisor) ; Ahadian, Mohammad Mahdi (Supervisor) ; Vosoughi, Manouchehr (Co-Advisor)
    Abstract
    Enhanced oil recovery (EOR) techniques are gaining more attention worldwide as the proved oil is declining and the oil price is hiking. Although many giant oil reservoirs around the world were already screened for EOR processes, the main challenges such as low sweep efficiency, costly techniques, possible formation damages, transportation of huge amounts of EOR agents to the fields especially for offshore cases and the lack of analyzing tools in traditional experimental works, hinder the proposed EOR process.It has been shown that recently, nanoparticles are attractive agents to enhance the oil recovery at the laboratory scale.
    In this study TiO2 nanoparticles were used to improve... 

    Numerical Simulation of Cold and Hot Water Injection into Naturally Fractured Reservoirs Using the Extended Finite Element Method

    , M.Sc. Thesis Sharif University of Technology Pirmoradi, Pouriya (Author) ; Khoei, Amir Reza (Supervisor)
    Abstract
    The present article studies the isothermal and non-isothermal water injection into naturally fractured oil reservoirs by numerical simulation. The fractures in naturally fractured reservoirs can possess different characteristics. In addition. a remarkable number of naturally fractured reservoirs contain relatively heavy oils that could not be extracted economically; hence. the thermal recovery methods are extensively used for these reservoirs. Hot water injection is one of the thermal recovery methods that has not been explored enough compared to its alternatives. In this study. the effectiveness of the hot water injection over the cold (isothermal) water injection in oil production is... 

    Microscopic Investigation of the Effect of Low Salinity Waterflooding on Asphaltene Precipitation and Deposition Using Microfluidic Method

    , M.Sc. Thesis Sharif University of Technology Salari, Amir Hossein (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Water injection, as one of the conventional methods to increase the oil recovery factor has always been at the center of research works for Enhanced Oil Recovery (EOR). The conducted studies show that by controlling the amount and type of ions in the injected water, the recovery efficiency can be improved. In the meantime, most of the investigations are focused on the interaction between water/rock/oil to trace the wettability alteration. However, these interactions especially between the injected water and the oil phase, would lead to change of surface charge distribution of the reservoir rock. Besides, this effect can change some of the characteristics of the fluid phases, especially in... 

    Study the Effect of Specific Salt Ions on Interfacial Tension of Water (Lowsalinity/Smart) and Reservoir Fluid in Surface Tension Reducing Materials Flooding by Molecular Dynamic Simulation

    , M.Sc. Thesis Sharif University of Technology Zeighami, Amir Reza (Author) ; Ayatollahi, Shahabodin (Supervisor)
    Abstract
    Water injection is known as one of the most efficient and affordable techniques to displace the oil in the reservoirs. To increase oil recovery efficiency through water injection operation, recently low salinity water injection or water containing a certain amount of effective ions (engineered/low salinity water) is proposed. Besides, improving this technique is also adopted in the oil industry using certain chemicals like surfactants to change the interfacial tension or rock wettability for more oil recovery. In order to study and model the mechanisms involved during surfactant flooding, molecular dynamics simulation is utilized here as a novel technique. The advantage of this method over... 

    Pore-scale Simulation of the Effect of Fluid/fluid and Rock/fluid Interactions During Water Injection on the Residual Oil Distribution and Hysteresis

    , M.Sc. Thesis Sharif University of Technology Ebrahimi Nejad, Mehdi (Author) ; Fatemi, Mobeen (Supervisor)
    Abstract
    Low salinity water injection is one of the new and important methods of enhancing oil recovery. Experimental studies show the fact that the change in water salinity affects the interfacial properties of water-oil (Fluid-fluid interactions) And the change in wettability that represents the porous media (Rock-fluid interactions) is effective for Oil-recovery. Recently, progress have been made in simulating the process of injecting low-salinity water into the field or core dimensions. However, the simulation of the low salinity water injection process has been much less studied considering the fluid / fluid and fluid / rock interactions at the pore scale. The purpose of this study is to... 

    Experimental Investigation and Modeling of Flow ّunction Variation in Enhanced oil Recovery Using Low Salinity/Smart Water Injection in a Carbonate Reservoir

    , Ph.D. Dissertation Sharif University of Technology Farhadi, Hamed (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Fatemi, Mobin (Supervisor)
    Abstract
    Low salinity water flooding (LSWF) as an efficient enhanced oil recovery (EOR) technique is proved to affect both, fluid-fluid and rock-fluid interactions to potentially release the trapped oil from the porous rock. Despite more than one decade of extensive research works on the low salinity water effect (LSWE), there are still many parameters to be studied for very complex cases. Therefore, in the first part of the experimental study of the dissertation, a systematic investigation on the effect of the initial wetting state (water-wet or oil-wet) of pure calcite is conducted to study the importance of fluid/fluid and fluid/rock interactions for LSWE investigation. In the case of initially... 

    Scale Formation in Porous Media and its Impact on Reservoir Performance During Water Flooding

    , M.Sc. Thesis Sharif University of Technology Abedi, Emad (Author) ; Masihi, Mohsen (Supervisor) ; Taghikhani, Vahid (Co-Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Supervisor)
    Abstract
    Mineral scale precipitation and carbonate rock dissolution are among the most important reactions that usually occur during water injection in oil reservoirs. These reactions happen due to incompatibility between formation water and injection water as well as deviation from equilibrium conditions. These reactions must be considered precisely because of the fact that they result in variation of reservoir porosity and permeability which affects recovery factor. In this study, the effect of injection pressure on these variations during single-phase water flooding is examined accurately. Additionally, the changes of ion concentration and the amount of dissolved or precipitated calcite or... 

    Laboratory and Modeling Study of Formation Injectivity Decline Due to Mineral Scale Deposition in Water Injection in one of Iranian Oil Resrvoirs

    , M.Sc. Thesis Sharif University of Technology Hashemkhani, Mohammed (Author) ; Masihi, Mohsen (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    Scale deposition is one of the reasons of formation damage during water injection process. This phenomenon often ocuures when two incompatible waters that interact chemically and precipitate minerals, mix within the reservoir. A typical example is sea water, with high concentration of sulfate ion and formation water, with high concentrations of calcium and/or barium ions. Mixing of these waters, therefore, can cause precipitation of calcium sulfate and/or barium sulfate. This study was conducted to investigate the permeability reduction caused by deposition of calcium and barium sulfates in carbonate cores from mixing of injected sea water and formation water in two flow rates and two... 

    Experimental Investigation of Mechanism of Wettability Alteration Induced By Hot Water and Steam Injection

    , M.Sc. Thesis Sharif University of Technology Salehi, Afshin (Author) ; Masihi, Mohsen (Supervisor)
    Abstract
    One of the most important production mechanisms of fractured reservoirs is wettability alteration. Since most fractured reservoirs are carbonate, and thus are often oil-wet; production of these reservoirs is facing their special challenges. Since most of our country reservoirs are fractured carbonate type, determination of the exact mechanisms of their production is necessary. Thermal EOR methods traditionally have been welcomed by big oil companies. Also, these methods of enhanced oil recovery techniques, have a much greater share in the production history of all EOR methods, rather than other EOR methods. Exponentially decreasing of oil viscosity on heating, is the main reason for using... 

    Experimental and Simulation Study of Water Alternating Hydrocarbon - CO2 Mixture Gas in one of Iranian Oil Reservoirs

    , M.Sc. Thesis Sharif University of Technology Alizadeh, Ali (Author) ; Taghikhani, Vahid (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Badakhshan, Amir (Supervisor)
    Abstract
    In this work the effect of composition changes of the injection gas (Hydrocarbon gas + carbon dioxide) on Water Alternating Gas (WAG) performance in immiscible flooding which has been rarely attended in the available literature is investigated. Core flood experiments are conducted on a 10 cm length Sarvak sandstone core sample at 46 degree C and at immiscible condition, i.e., below the minimum miscible pressure (MMP) of the oil sample using pure CO2 as injected Gas.The influence of injection WAG ratio on oil recovery also is investigated. Artificial injection brine which is made by dissolving NaCl into distilled water with 5000 ppm (mg/L), NaftShahr oil which has about 41 API gravity and... 

    Investigation The Effect Of Wettability Alteration On Increasing Recovery Factor At Fractured Reservoirs

    , M.Sc. Thesis Sharif University of Technology Chahardahcherik, Morteza (Author) ; Jamshidi, Saeid (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    There are a lot of Fractured reservoirs around the world that have large portion of oil production. These reservoirs have complex structure and fractures have important role in production but the remaining oil in matrix causes that the oil recovery decreases. One of the most important factors in these reservois are wettability. Because most of the fractured reservoirs are oil wet and water injection process in these reservoirs are not effective and chemical EOR methods such as surfactant flooding method is used. Surfactant improve oil recovery by two reasons: 1- reduction of interfacial tension between oil and water . 2-Wettability alteration of matrix. The porpose of this project is... 

    Smart Water Injection to the Oil Fields for Enhancing the Recovery Factor

    , M.Sc. Thesis Sharif University of Technology Malekpour, Hossein (Author) ; Farhadi, Alireza (Supervisor)
    Abstract
    The objective of this MSc. thesis is to study the impact of the reactive method and the enhanced reactive method on enhancing the exploitation efficiency of Iran's offshore oil reservoir. This is achieved by enhancing production and the recovery factor of the reactive methods with respect to the currently used proactive method. Unlike the currently used proactive method that implements a fixed rate injection strategy, in this MSc. thesis water is injected to reservoir with multi-rate for the pressure stabilization of the reservoir. In order to scale up this strategy, the ensemble Kalman filter is used to frequently update the reservoir mathematical model using the available measurements from... 

    Monitoring the influence of dispersed nano-particles on oil-water relative permeability hysteresis

    , Article Journal of Petroleum Science and Engineering ; Vol. 124, issue , December , 2014 , p. 222-231 ; ISSN: 09204105 Parvazdavani, M ; Masihi, M ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    In recent years, polysilicon nanoparticles are used to enhance the oil recovery through the water injection process in oilfields. The contributing mechanisms are the reduction of interfacial tension and wettability alteration which lead to improving or decreasing the oil phase relative permeability and can be traced by change of relative permeability curves. However, profound understanding of the effect of dispersed nano-silica particles on the hysteretic behavior of relative permeability curves remains a controversy topic in the literature.The current study illustrates the influence of dispersed silica particles on hysteretic trend of two-phase curves of oil-water relative permeability.... 

    Experimental determination of equilibrium interfacial tension for nitrogen-crude oil during the gas injection process: The role of temperature, pressure, and composition

    , Article Journal of Chemical and Engineering Data ; Vol. 59, issue. 11 , September , 2014 , p. 3461-3469 ; ISSN: 00219568 Hemmati-Sarapardeh, A ; Ayatollahi, S ; Zolghadr, A ; Ghazanfari, M. H ; Masihi, M ; Sharif University of Technology
    Abstract
    Nitrogen has emerged as a competitive gas injection alternative for gas-based enhanced oil recovery processes in the past two decades. The injection of nitrogen into the reservoirs has improved the oil recovery efficiency in various oil reservoirs from heavy to volatile oils. As it is known, interfacial tension (IFT) plays a key role in any enhanced oil recovery process, particularly gas injection processes; therefore, its accurate determination is crucial for the design of any gas injection process especially at reservoir condition. In this study, an axisymmetric drop shape analysis (ADSA) was utilized to measure the equilibrium IFTs between crude oil and N2 at different temperature levels... 

    Toward mechanistic understanding of heavy crude oil/brine interfacial tension: The roles of salinity, temperature and pressure

    , Article Fluid Phase Equilibria ; Vol. 375, issue , August , 2014 , p. 191-200 ; ISSN: 03783812 Moeini, F ; Hemmati-Sarapardeh, A ; Ghazanfari, M. H ; Masihi, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

    Well Placement optimization using hybrid optimization technique combined with fuzzy inference system

    , Article Petroleum Science and Technology ; Vol. 31, issue. 5 , Dec , 2009 , p. 481-491 ; ISSN: 10916466 Darabi, H ; Masihi, M ; Sharif University of Technology
    Abstract
    Decision on the location of new wells through infill drilling projects is a complex problem that depends on the reservoir rock and fluid properties, well and surface facilities specifications, and economic measures. Conventional approach to address this is a direct optimization that uses the numerical flow simulation. However, this is computationally very extensive. In this study the authors use a hybrid genetic algorithm (HGA) optimization technique based on the genetic algorithm (GA) with helper functions based on the polytope algorithm and the neural network. This hybridization introduces hill-climbing into the stochastic search and makes use of proxies created and calibrated iteratively... 

    Investigation of the effect of water based nano-particles addition on hysteresis of oil and-water relative permeability curves

    , Article Society of Petroleum Engineers - SPE International Oilfield Nanotechnology Conference 2012 ; June , 2012 , p. 267-277 Parvazdavani, M ; Masihi, M ; Ghazanfari, M. H ; Sherafati, M ; Mashayekhi, L ; Sharif University of Technology
    Abstract
    It has been shown that one kind of poly silicon particles with sizes ranging from 10-500 nm, can be used in oilfields to enhance the oil recovery of water injection by 15-20%. The contributing mechanism might be reducing the interfacial tension which appears through improving relative permeability of the oil-phase. However, fundamental understanding of how hysteretic behavior of relative permeability curves affected by nanosilica particles remains a topic of debate in the literature. In this study, water as well as water dispersed nanosilica particles floods was performed on sandstone rock sample saturated by light crude oil supplied from one of Iranian oil reservoir, and the relative... 

    Experimental study of miscible displacement with hydrocarbon solvent in shaly heavy oil reservoirs using five-spot micromodels: The role of shale geometrical characteristics

    , Article Journal of Porous Media ; Vol. 15, issue. 5 , 2012 , p. 415-427 ; ISSN: 1091028X Mohammadi, S ; Ghazanfari, M. H ; Masihi, M ; Kharrat, R ; Sharif University of Technology
    Abstract
    Most of the heavy oil reservoirs contain discontinuous shale which affects fluid flow through porous media as well as recovery efficiency during enhanced oil recovery processes. However, the role of shale geometrical characteristics (including orientation, length, discontinuity, and spacing of the shale) on oil recovery remains a topic of debate in the literature, especially during miscible injection of heavy oils and five-spot systems. Here, a series of hydrocarbon solvent injection tests have been performed on various five-spot glass micromodels containing barriers which are initially saturated with heavy oil under fixed flow rate conditions. Oil recoveries as a function of pore volumes of... 

    Prediction of asphaltene precipitation during solvent/CO2 injection conditions: A comparative study on thermodynamic micellization model with a different characterization approach and solid model

    , Article Journal of Canadian Petroleum Technology ; Vol. 50, issue. 3 , March , 2011 , p. 65-74 Tavakkoli, M ; Masihi, M ; Ghazanfari, M. H ; Kharrat, R ; Sharif University of Technology
    Abstract
    There are different thermodynamic models that have been applied for modelling of asphaltene precipitation caused by various reasons, such as solvent/CO2 injection and pressure depletion. In this work, two computer codes based on two different asphaltene precipitation thermodynamic models-the first being the thermodynamic micellization model with a different characterization approach and the second being the solid model-have been developed and used for predicting asphaltene precipitation data reported in the literature as well as in the obtained data for Sarvak reservoir crude, which is one of the most potentially problematic Iranian heavy oil reserves under gas injection conditions. For the...