Sharif Digital Repository

The reaction of oxygen evolution, in other words, the process of water oxidation in the presence of heterogeneous photocatalysts such as g-C3N4, Co/g-C3N4 /rGO, Ni/g-C3N4/rGO, CoNi/g-C3N4 / rGO, Co2Ni1/g-C3N4/rGO, and Co1Ni2 /g-C3N4 /rGO were studied. The characterization of these nanocatalysts was done by XRD, SEM, FT-IR, BET, DRS, CHN, and TGA techniques. Thermogravimetric analysis (TGA) was used to check the thermal stability of these nanocatalysts. The FT-IR spectroscopy was used to identify the functional groups in graphitic carbon nitride and to confirm g-C3N4 synthesis. According to BET results, the pore sizes were determined which were at the nano and macro scale. It was found that... 

Polyamides have found great attraction in the wide variety of application due to their desireable and tribological properties and appropriate processability. Due to their low mechanical strength reinforcing of these types of polymers has always been one of the important academic and industrial issues. In order to improve mechanical properties of such polymers, different kinds of reinforcement particles such as titaniom diaoxide, Nano clay, glass fibers (Short or long glass fiber), etc were used. Carbon nano tubes have high thermal and electrical conduction and mechanical properties; they are widely used as a reinforcement particle for polymer matrix. In this study, carbon nano tube and... 

The major objectives of this study are to analytically and experimentally investigate the rheological behavior of polymers in the fractured carbonate medium based on the polymer solution properties and operational conditions. The intrinsic and apparent viscosity of high molecular weight-partially hydrolyzed poly (acrylamide) which is mainly used in enhanced oil recovery (EOR) processes hasbeen investigated in reservoir conditions. Since, the EOR efficiency of hydrolyzed poly (acrylamide) is very sensitive to the temperature and salinity of petroleumreservoirs; investigations have been carried out at different possible reservoirtemperatures using high saline polymer solutions. The parameters... 

Regarding to the effect of nanoparticles on mass transfer and hydrodynamics characteristics, limited number of studiesavailableinthe literature.In this work, mass transfer performanceand hydrodynamic characteristics nanofluidshavebeeninvestigated in the liquid−liquid extraction process. The chemical system of toluene-acetic acid-water was used, and two Extraction columnswith diameter of 10cm and height of 55cm and 6 cm were designed. The drops were organic nanofluids containing silica nano-particles and carbon nano-tubes.Synthesized silica nanoparticles by sol-gel methods, were modified with Triethoxyoctylsilane and Polydimethylsiloxane as well as Carbon nano-tubes were modified with dodecyl... 

In the first work, a stable composite film of silver nanoparticles decorated on reduced graphene oxide is easily prepared. The surface morphology of the modified electrode is characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The electrochemical behavior of TNZ on the surface of the modified electrode is investigated by using linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The prepared modified electrode acts as a highly sensitive platform for the voltammetric determination of tinidazole (TNZ). Voltammetric investigations demonstrated that, in comparison to the glassy carbon electrode individually coated with... 

Splitting in ingot cast structures and transverse cracks in continuous cast structures are the main problems of hot rolling of low carbon resulfurized free-cutting (LCRF) steels. Presence of high volume fraction of manganese sulfide inclusions in cast structure increases the risk of alligatoring in hot rolling. Because of high sulfur content of these steels and probability of formation of low melting point phases, minimum level of manganese and maximum level of copper and tin is necessary. Morphology of manganese sulfide is another important factor in hot forming of these steels, which can be controlled by level of deoxidation in steel making. In fact, MnS2 is present in fully killed... 

In this research convective heat transfer coefficient enhancement of nanofluids prepared from high surface area graphene has been investigated in laminar flow in the developing region. The nanofluid has been prepared from nanoporous graphene with high surface area and with concentration of 0.025 to 0.1 %wt. Deionized water has been used as the base fluid and a type of Ter-Polymer has been utilized as the surfactant. The results indicate that thermal conductivity of nanofluid with concentration of 0.1 %wt remains quite constant, with only %3.8 enhancement, while convective heat transfer coefficient improves significantly, with 34% enhancement. The behavior of this enhancement related to the... 

Inrecent years,research onionic liquidsarehighly developed. Because ofthe uniqueproperties ofionic liquidssuch asnegligiblevapor pressureandthermalstability for use inlarge areasofmajor industries have been considered.However,ionic liquids because they have lessenvironmental wasteas an alternative to convention alorganic solventssuch asaminesalkanolanarise.Ionic liquid sassolventsfor theremoval ofacid gases such as water and gasare investigated. The solubility of CO2 and H2S in the [Emim] [OTF] (1-ethyl-3-methylimidazolium triflate) in the temperature range 303.15 to 343.15 K and pressures up to 2 MPa has been studied experimentally. In order to capture modeling, the model equations of state... 

Carbon dioxide photocatalytic reduction is one of the promising methods used to produce a wide range of renewable hydrocarbon fuels using sunlight in the presence of photocatalysts. In this study, a series of Nickel and Bismuth doped titanium dioxide samples were synthesized by Sol-gel method. After performing photocatalytic carbon dioxide recovery experiments and finding the optimum percentage of Nickel and Bismuth doped titanium dioxide,Ni and Bi co-doped TiO2 sample showed the highest photocatalytic activity. Amount of methane production was 21.13 μmol/gcat in the presence of co-doped sample that was about 6.5 times higher than the amount of methane produced in the presence of pure TiO2... 

One of the most common methods for enhancing oil recovery is gas injection. Because of greenhouse effect and environmental problems, carbon dioxide can be used as injected gas. Low viscosity and high relative permeability of gas make the gas injection as an ineffective EOR method. Foam injection is a good replacement because its mobility is much higher than gas. Usually surfactants are used as foam generator agent but the generated foam is not so stable. Using nanoparticles can improve foam stability for a longer time. In this research study fly ash particles is used as a new stabilizer agent to improve carbon dioxide foam stability. This particles are made of silica, aluminum, iron …... 

The purpose of the present study is to plan an industrial system, over a period of 10 years, so that over time, while supplying the required demand, to optimal resource utilization with regard to material reuse and recovery flows of losses as well as the use of renewable resources move to implement the concept of a circular economy. One of the main incentives for the transition to a circular economy is carbon tax policy, which has been taken into account. The results of the decision-making model based on cost and flow constraints indicate that the use of carbon dioxide as a by-product of Pars Petrochemical Extraction Unit in order to produce urea in Pardis petrochemical industry in addition... 

Nowadays, science of nano technology has been growing quickly in the past decade. Scientists implemented this technology in bioengineering, electronics and medicine extensively. Nano scale engineering is one of the interests of researchers, nano bearing as a nano scale structure and as an important part of nano machining plays an important role in micro and nano devices. The role of nano bearing is to decrease energy dissipation and increase the efficiency of nano machines. The main purpose of this study is to design and analyze an optimized nano ball bearing. In this regard, a new spherical super element is designed and presented. This super element is implemented in simulating the... 

With the growing population and the development of human societies, the demand for energy increases. And it is expected that for the next few decades, fossil fuels will continue to be recognized as the main sources of energy supply and used to meet energy demand. One of the biggest disadvantages of fossil fuel consumption is the emission of greenhouse gases such as carbon dioxide, which raises the Earth's temperature and has devastating effects on the climate and the lives of its inhabitants. On the other hand, fossil fuels are recognized as non-renewable sources and their lifespan is only for the next few decades. Today, one of the major concerns of societies, especially in developed... 

Due to a rapid growth in the consumption of fossil fuels, the emission of greenhouse gases has multiplied in the atmosphere in the past few decades. This issue can directly affect on the rise of global temperature. Because of the intensification of the global warming, international organizations are looking for ways to reduce the greenhouse effect. One of these methods is injecting and trapping greenhouse gases, especially carbon dioxide, resulting from the operation of power plants and other large industries and preventing it from entering the atmosphere. The injection of carbon dioxide in underground salt water reservoirs can have various effects such as mechanical, hydraulic, thermal, and... 

In this study, the properties of super-hydrophobic Ni coating on carbon steel including wetting behavior and corrosion resistance of Nickel coatings deposited on the steel substrate were investigated. For this purpose, Nickel coatings deposited by electrodeposition method in deferent current density (10,20,30,50, 70 mA /cm2) in bath containing 1.5 mol of ethylene de-ammonium de-chloride, 0.5 mol H3BO3, 1 mol Nicl2.6H2o and then immersed in a bath containing 0.01 mol per liter myristic acid and ethanol for 24 hours and then placed in the room temperature for 14 days. Deferent tests were used for characterization, wettability properties, corrosion behavior and morphology of Ni coatings. The... 

Formation acidizing is one of the best well stimulation methods to remove reservoir damage and improve recovery of oil and gas well. The proper design of acidizing operations can significantly improve the production of a formation. In the meantime, causing formation damage and precipitation in oil flowlines, which may be caused by the incompatibility of the stimulation fluid with the reservoir fluid and rocks, is one of the most serious problems in the operation, which reduces permeability and oil/gas production. As a result, the success of the acidizing operation requires to study the interaction of components of operation (acid, reservoir water, formation rock, and acid additive)... 

The adsorption equilibria of carbon dioxide, methane, and nitrogen on pelletized cation-exchanged faujasite zeolite (with alkali, alkaline earth, and transition metal ions) have been investigated by a volumetric apparatus. The standard instrumental analytical techniques, including X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) coupled with energy dispersive X-ray spectroscopy (EDX), and atomic absorption spectroscopy (AAS) were utilized to characterize binder-free modified zeolites. The EDX spectra and AAS results revealed that the ion-exchange was successfully achieved with expected tendencies. The results indicate that the type of cation present in the zeolite... 

During the last decade, thanks to a combination of exploding computational power and improved physical insight into material behavior, continuum and atomistic simulations improved greatly. Both classes of methods are now used to solve problems, which are more complicated than ever with greater accuracy than ever before. Nevertheless, there still exist problems for which neither method alone is sufficient. In general, atomistic simulations cannot be used for such length scales due to the restrictions on the number of atoms that can be simulated, along with the time scales, which they can be simulated for. In contrast, continuum simulations tend to fail at the atomic scale, for example due to... 

The concentration of air pollutants in the environment is variable according to different factors, including distances from main sources. Vehicles in streets and highways are one of the most important sources of the air pollutants. Hemmat highway is one of the most significant highways in Tehran with traffic congestion of 15000 to 18000 vehicle/hour. In this research, the concentrations of PM10 and CO were determined in different distances of Shahid Hemmat highway and the relationship diagrams of traffic and meteorology to the amount and emission of air pollutants were drawn. The concentration gradient diagrams showed exponential decay, which demonstrated that more than of 50% of air... 

The PM2.5 particles are considered as one the most important pollutants of Tehran’s air due to their undesirable effect on health and environment. The particular matters which are in Tehran’s air are distributed from different sources. Because of lack of sufficient data about amount and chemical compounds of such matters in different areas, this study considers only concentration of particular matter and their composing elements in Sharif University, Tehransar, Mahalati, and Shahriyar station. By use of field measuring between 2015 to 2016 mass concentration of PM2.5 pollutant was calculated and then with the help of IC, GC/MS, and ICP chemical analysis which were conducted in University of...