Sharif Digital Repository

There are different types of sensors for measuring the concentration of gases that usually have high prices because of their complicated method of production. We can produce much cheaper sensors in special conditions by using polymer membranes. Different gases can be separated by using appropriate polymer membranes and the difference between diffusion rate of these gases is the basis of the separation method and gases pass through the membrane with different flow rates in the specific entrance pressure. The flow rate of total gas which flows will be different for a binary gaseous mixture at specific temperature and pressure with different concentrations because the flow rate is relative to... 

In this study, transition metal phosphide, with a high accessible surface and abundant electroactive centers, was used as an electrocatalyst to fabrication an electrochemical sensor of Gloucose. The direct growth of thin film of nanocomposite can be considered as an efficient method to modify the electrode surface, and the application of these modified electrodes as electrochemical sensors. nanocomposite of transition metal phosphide (CuCoP) were directly grown on Cu(OH)2 nanotubes (as-prepared on GCE) in order to design hierarchical core-shell nanostructure with using efficient, inexpensive and fast method. Here, Cu(OH)2 nanotubes not only served as substrate, but also steer the CuCoP to... 

Herein a simple tow step method is developed to design hierarchical binder free structure of binary nickel cobalt carbonate hydroxide decorated hydrothermal carbon sphere. First carbon sphere were synthesized on nickel foam via hydrothermal process using glucose solution followed by carbonization process. Ni Co carbonate hydroxide core shell array were directly grown on binder free carbon spheres using hydrothermal method. The synthesized electrode afforded high specific capacitance (497/83 mAhg-1 at a current density of 1/4 A g-1) and good cyclic stability (85% after 1500 charge / discharge cycles). EIS measurement showed negligible internal resistance (0.638 Ω) which is attributed to the... 

The main purpose of this Ph.D. Thesis is to develop DNA-based biosensors using Label-free approaches applying simple, inexpensive and fast electrochemical techniques to measure the biological markers of cancer.In the first part, a simple protocol for detection of specific-sequence DNA is introduced. In this method carbon nanotube is used as a hybridization indicator. This label-free system provides the advantage of eliminating additional labeling procedure. As the signal enhances in the presence of MWCNT and decreases in the presence of target, the fabricated sensor is known as a signal-off device. The oxidation signal of Fe(CN)63-/4- is followed as an analytical signal to detect target... 

Emission of CO2 and its diffusion into atmosphere is associated with negative effects on the environmental such as Green House Gases effect. Various techniques of CO2 Capture in energy conversion and processing plant are investigated. A method of CO2 Capture could be based on utilization of solar energy for producing methanol. Basic design of such a system and feasibility analysis of developing that system has been considered on the subject of the present research work. Basic design and commercial feasibility of the system producing methanol through capturing CO2 from exhaust gases of a power plant and hydrogen produced by using solar energy have done such an integrated system. The main... 

Nowadays, science of nano technology has been growing quickly in the past decade. Scientists implemented this technology in bioengineering, electronics and medicine extensively. Nano scale engineering is one of the interests of researchers, nano bearing as a nano scale structure and as an important part of nano machining plays an important role in micro and nano devices. The role of nano bearing is to decrease energy dissipation and increase the efficiency of nano machines. The main purpose of this study is to design and analyze an optimized nano ball bearing. In this regard, a new spherical super element is designed and presented. This super element is implemented in simulating the... 

Despite extensive studies on the behavior of reinforced concrete slabs, especially those reinforced with steel rebars, no comprehensive studies have been conducted on the behavior of concrete slabs reinforced with FRP rebars. Therefore, there are some ambiguities regarding the tensile and compressive behavior of these rebars in the load-bearing capacity of reinforced concrete slabs (depending on their amount in the slab and their combination with steel rebars). Hence, in this study, in order to ensure the accuracy of numerical simulations, the numerical 3D simulation of a one-way concrete slab reinforced with tensile FRP rebars was performed using the finite element Abaqus software.... 

The rehabilitation of old structures holds a lot of importance, as many structures with a life span of over 30 years are prone to severe damage and even collapse. To overcome this problem, the use of FRP sheets to strengthen structures is suggested. RC-arches have been used in many structures such as bridges and require specific consideration in terms of strengthening. So far, the influence of the number of FRP layers and location, the height of arch and percentage of reinforcement on strengthened arch behavior have not been investigated. In this research, reinforced concrete arch members strengthened with GFRP and CFRP were investigated. A total of 28 Specimens, including four... 

Evaporative cooling systems are of most common cooling systems which their electricity consumption is much lower than vapor compression cooling systems. Enhancement of these system’s performance could help to propagate these systems and also decrease the electricity consumption and corresponding emissions in large scale. In this thesis, first a modified cycle is proposed for evaporative cooling. Then, in order to use evaporative cooling in humid climates, a desiccant wheel is implemented in this modified evaporative cooler. As using evaporative cooling will cause high water consumption, a novel cycle is proposed for desiccant based evaporative cooling which is able to cover system water... 

Carbon dioxide is one of the main geenhouse gases emitted from factories as well as transportation vehicles that adversely affect the atmosphere and cause global warming. Among the proposed solutions to reduce carbon dioxide in the atmosphere, carbon dioxide separation would be the most viable medium-term approach. However, the high cost of carbon dioxide separation prevents the development of carbon dioxide absorption technologies. Therefore, it seems that integrating separation and production processes is the most efficient way to save energy and reduce carbon emissions. This method decrease a high proportion of the energy consumption in upstream operations (carbon dioxide removal,... 

One of the best stimulation methods for oil and gas wells is matrix acidizing in order to increase the near wellbore permeability. in acidizing, good acid coverage in different layers is one the main goals. so, various methods have been presented. important part in using these methods is to not damage formation and economic matters. modern methods utilize VES acids for this purpose. viscoelastic characteristics of these materials by formation of miscellaneous, increases the apparent viscosity by a large degree. for this reason, VES fluids can be used to improve acid divergence in acid injection operation. acid system based on viscoelastic surfactants that is changed to gel instantly, can be... 

Concerns have increased about global warming caused by CO2 emissions in the atmosphere. At the moment, carbon capture and storage is the best available solution. Among the current technologies for CCS, amine-based chemical absorption appears to be the most common method. Amines show several inherent drawbacks such as high vapor pressure, high energy consumption in regeneration, corrosivity and degradability. So, researchers have developed new solvents with the foresight of being superior to amines. Ionic liquids (ILs) are among the most suitable alternatives. The most prominent feature of ILs is their tunable thermophysical properties. In this work, physical absorption by ILs is chosen as... 

Network design is one of the major strategic decisions of a supply chain which leads to the whole sustainability of the chain. Besides, due to an increase in carbon dioxide emissions and its harmful effects, recently there has been an growing interest in green supply chain network design. In this thesis, a mixed integer linear programming is developed to formulate a closed-loop supply chain with forward and reverse logistics. Moreover, social cost rate of carbon dioxide is used to consider environmental impact. Considering uncertainty in closed-loop supply chains is crucial. To do so, three robust optimization methods including Soyster, Ben-tal and Nemirovski and Bertsimas and Sim approaches... 

Nowadays, due to expansion of the cities, growth in population and developments in technology, energy demand has increased extremely. Therefore responding this increased demand is a great challenge in political and economical management of all countries. Thus in recent years, cogeneration has become so popular between experts in the energy field because of its great efficiency and performance. The goal of this research is to design a controller based on a model which can predict the behavior of the cogeneration system. This controler is called “Mode Based Predictive Controller”. It utilizes the system in such a manner which has the lowest operation costs. This goal is obtained via modeling... 

One of the Advanced Oxidation Process (AOP) is Photocatalyst method. Structure of this method is according to three foundation: 1. Catalyst, 2. Source of energy, 3. Wastewater. Progress of human activity around variety of fields such as pharmaceutical, plastic industry, and medical science has produced some micro pollutants such as Bisphenol A (BPA) that has aroused the public concerns in recent years. The half-life of this components in water, air and soil is too long, so typical methods such as biological method, activated sludge and carbon adsorption are inefficient in removing BPA. This work describes a visible light responsive Carbon Quantum Dots(CQDs) embedded on TiO_2 nanoparticles... 

Nerve damage is one of the factors affecting the quality of life of patients. The nervous system does not have the ability to repair large injuries, and autologous transplantation, which is the standard treatment method for nerve injuries, is faced with a shortage of donors and a decrease in the function of the donor site. Tissue engineering hydrogels, due to their similarity to the natural tissue of the stomatal body, are a hope for the repair of nerve tissue. In this research, an injectable, minimally invasive and temperature-sensitive hydrogel based on chitosan-etaglycerophosphate-sodium hydrogen carbonate salt or trisodium phosphate salt containing aligned nanofibers made of gelatin and... 

Hydrogen peroxide (H2O2) is of great importance in numerous fields such as pharmaceuticals, mining, textile, environmental and food industry. Therefore, the development of low cost, on-site, and uncomplicated H2O2 sensors are of high interest. To date, colloidal quantum dots (QDs) have been used to detect H2O2 based on the quenching of fluorescence intensity in a single wavelength. However, intensity of fluorescent signal could be easily disturbed by various factors. To overcome these undesirable effects, here, a ratiometric sensor has been developed by adding a second fluorophore (as reference) to QDs. For this purpose TGA-capped CdTe QDs were prepared. To detect H2O2, the ratiometric... 

In this study, the viability of handling flue gas streams as a source of CO2 for the thermocatalytic conversion was investigated as a CO2 emissions reduction strategy and an intermittent energy storage solution. A transient mathematical model for dynamic catalyst deactivation was validated with experimental results and then used to study HEX membrane reactor. A simulation-based study of novel Sabatier reactor configurations was performed to study the effect of distributed H2 supply on Ni-based catalyst deactivation and to optimize the production of CH4. First, a heat-exchanger type, actively cooled Sabatier reactor is analyzed using a transient mathematical model to assess its feasibility.... 

n the present study, the optimal design of feeding system in steel sand-mold castings is considered. The first part of this research includes fundamental studies on the physics of shrinkage defect formation during the casting process. The results of these studies lead to new findings on the mechanism of shrinkage defect formation, effect of melt quality on the distribution of defects within the castings and the connection between shrinkage and gases defects. The theoretical analysis of thermal criterion functions for the prediction of shrinkage defects in castings and introducing new criterion function with fewer shortcomings can be accounted as the other finding of this part. A new model... 

Considering the supply and demand market of natural gas, methanol, propylene and ethylene and the propylene value chain, it is expected that the design of the propylene production process from methanol produced from natural gas and its implementation in Iran country can significantly flourish the production of polypropylene, acrylonitrile and Etc. On the other hand, with the industrialization of this process, the uncontrolled export of methanol from Iran to countries such as China and the devaluation of methanol will be prevented. In this report, the process of producing synthetic gas from natural gas using autothermal reactor and heat exchange reforming, separation and storage of carbon...