Sharif Digital Repository

The durability of novel metallic artifacts and buildings is an open issue, and the role of smart protecting coatings in extending these artifacts’ lifetimes is crucial. In this paper, the role of γ-Fe2 O3 nanoparticles and reduced graphene oxide (rGO) nanosheets on enhancing the self-cleaning properties of composite TiO2 films and reducing metal alterations due to contact with acid rain and pollutants is investigated. The photocatalytic assessment of the TiO2 based films indicates that there are optimum contents for γ-Fe2 O3 and rGO, which confer the film lower bandgap and tune the TiO2 anatase/rutile ratio. By adding a proper content of γ-Fe2 O3, wettability is reduced both in dark and... 

Low cycle fatigue is one of the most important phenomena affecting the lifetime of jet engine blades. In this paper, the effect of aluminide diffusion coating (CODEP-B) on low cycle fatigue properties of René 80 has been studied at temperature of 871 °C, R = 0 and strain rate of about 2 × 10-3 s-1. Experimental results show that the applied cyclic strain is lower than 0.8%, the presence of aforesaid coating increases the fatigue lifetime. In coated specimens, while the total cyclic strain is lower than 0.8%, the nucleation of the cracks occurs merely in substrate, but in cyclic strain more than 1%, as a result of simultaneous nucleation of cracks in the coating surface, diffusion layer and... 

This work aims to present an experimentally verified analytical solution to examine damping properties of systems including viscoelastic treatments. Although there are several methods for characterizing the behavior of three-layer damping systems, the RKU method is the most frequently used one. In this paper, this method is modified such a way that to be applied for a five-layer damping system. The achieved analytical relations are then employed to study the effects of a four-layer vibration-absorbing coating on the dynamic behavior of an aluminum sheet with free-free boundary conditions. Since the vibration-damping properties of the coating are unknowns, its loss factor and shear modulus... 

In this study, a novel inorganic/organic hybrid pigment based on zinc cations/Ferula Asafoetida leaves extract (Zn-FALE) was synthesized, and its corrosion protection properties were investigated in a saline solution and an organic coating. Interactions of components between Zn2+ cations and FALE were assessed by thermo-gravimetric analysis (TGA) and ultraviolet-visible (UV–visible) spectroscopy. Corrosion inhibitive performance of FALE and Zn-FALE pigments in the solution phase and coating phase was studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). TGA and UV–visible results revealed the proper chelation between inorganic and organic components of... 

Laser Powder Deposition technique is an advanced production method with many applications. Despite this fact, reliable and accurate control schemes have not yet fully developed for this method. This article presents method for in time identification of the process for modeling and adaptation of proper control strategy. ARMAX structure is chosen for system model. Recursive least square method and Kalman Filter methods are adopted for system identification, and their performance are compared. Experimental data was used for system identification, and proper filtering schemes are devised here for noise elimination and increased estimation results. It was concluded that although both methods... 

In this investigation a computational model has been developed which includes heat and mass transfer as well as effects of backpressure, and mould wall friction for the simulation of incompressible flow with free surfaces in mould cavity filling. The simulation of flow with free surfaces is based on the SOLA-VOF numerical algorithm, utilizing the finite difference method. The solid and free boundary conditions have been modified and a new algorithm has been developed to calculate the effect of cavity pressure and wall-slip ratio, during mould filling. In this algorithm, the effect of wall-slip ratio on filling pattern has been modeled with an experimental function. In order to verify the... 

In this investigation, simulation of the 3D flow of incompressible molten metal in a mould cavity has been carried out. A code has been developed to include heat transfer and permeability of coating utilizing the finite difference method (FDM). To achieve this, solid and free boundary conditions have been modified and a new algorithm has been proposed to calculate the effect of coating permeability during mould filling. In this algorithm, the effect of coating permeability on the filling pattern has been modelled and compared with an experiment. The modelling of molten metal flow and the location of free surfaces has been simulated based on the SOLution Algorithm-Volume Of Fraction... 

The most common reasons for hard-tissue implant failure are structural loosening and prosthetic infections. Hence, in this study, to overcome the first problem, different bioinspired coatings, including dual acid-etched, anodic TiO2 nanotubes array, anodic hierarchical titanium oxide (HO), micro- and nanostructured hydroxyapatite (HA) layers, and HA/chitosan (HA/CS) nanocomposite, were applied to the titanium alloy surfaces. X-ray diffraction and FTIR analysis demonstrated that the in situ HA/CS nanocomposite formed successfully. The MTT assay showed that all samples had excellent cell viability, with cell proliferation rates ranging from 120% to 150% after 10 days. The HO coating... 

In this study, the anticorrosive effect of dodecylbenzenesulfonicacid-doped polyaniline nanoparticles [n-PANI (DBSA)] as a conductive polymer was investigated using electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS) techniques. Initially, the n-PANI (DBSA) were successfully synthesized via inverse microemulsion polymerization leading to the spherical nanoparticles with an average diameter less than 30 nm. Two coating systems including 1 wt% n-PANI(DBSA) blended epoxy ester (n-PANI(DBSA)/EPE) and neat epoxy ester (EPE) were coated on the carbon steal substrate. The anticorrosion performance of the prepared coatings was studied using EIS measurement in 3.5%... 

In the present paper, numerical simulation of thermal barrier coating system under thermo-mechanical loadings is performed, using the finite element method in ABAQUS software. The base material is Aluminum-silicon alloy, A356.0 which is widely used in automotive components such as diesel engine cylinder heads. Thermal barrier coatings (TBCs) are applied to combustion chamber in order to reduce fuel consumption and pollutions and also improve fatigue life of components. The roughness effect of coating layers on stress distribution of test specimens is investigated. Semi-ellipsoid roughness of the interfaces between substrate/bond coat and bond coat/top coat are simulated to get the stress... 

An Al2O3/Si3N4 nanocomposite coating was successfully fabricated on commercial aluminum alloy. Hardness measurements, polarization and electrochemical impedance spectroscopy (EIS) were employed to study the mechanical and corrosion behaviors of the coatings. Field-Emission Scanning Electron Microscopy (FE-SEM) equipped with Energy Dispersive Spectroscopy (EDS) and X-ray diffraction (XRD) were utilized to characterize the surface morphology and phase composition of the coatings. Also, coatings abrasive wear properties were evaluated with a modified ASTM G105 standard. FE-SEM image, EDS and XRD analysis revealed the presence of Si3N4 in the coating. Furthermore, the results showed hardness of... 

Application of corrosion resistant coatings is one of the most widely used means of protecting steel. Zinc coated (galvanize) steel, is well known for galvanic protection of steel substrates and nowadays, particular attention has been paid to the coupling of graphene oxide (GO) with metallic materials, in order to lessen corrosion rate. In this research, an isopropanol supercritical reducing environment prepared to make zinc ions bond directly with graphene oxides, to form a button shape hybrids of ZnO-Graphene (ZnOG). The hybridized bonding between zinc and graphene oxide is confirmed by Fourier Transform Infra-Red analysis. And the morphology revealed, using a Field Emission Scanning... 

Corrosion of steel rebars in concrete can reduce the durability of concrete structures in coastal environments. The corrosion rate of these concrete structures can be reduced by using suitable concrete additives and coating on rebars. This paper investigates the corrosion resistance of steel rebars by the addition of pozzolanic materials including fly ash, silica fume, polypropylene fibers, and industrial 2-dimethylaminoethanol (FerroGard 901) inhibitors to the concrete mixture. Three different types of rebars including mild steel rebar st37, and two stainless steel reinforcements, AISI 304 and AISI 316, were used. Various types of primer and coating including alkyd based primer, hot-dip... 

To improve the biocompatibility and corrosion resistance of 316L SS (Stainless Steel) metal implants, HAp(hydroxyapatite)/TiO2/Al2O3 nanocomposite coating was created using dip sol-gel method sintered at 550 °C. The weight percentage of TiO2+ Al2O3 in these coatings was 20, 30, and 40% wt. In this study, characterization was performed using FTIR (Fourier-Transform Infrared Spectroscopy), XRD, FE-SEM (Field Emission Scanning Electron Microscope), EDS (Energy Dispersive Spectroscopy), DLS (Dynamic Light Scattering), Pull-off, and AFM (Atomic Force Microscopy) analysis. The potentiodynamic polarization and EIS (Electrochemical Impedance Spectroscopy) were performed in the simulated body fluid... 

To improve the biocompatibility and corrosion resistance of 316L SS (Stainless Steel) metal implants, HAp(hydroxyapatite)/TiO2/Al2O3 nanocomposite coating was created using dip sol-gel method sintered at 550 °C. The weight percentage of TiO2+ Al2O3 in these coatings was 20, 30, and 40% wt. In this study, characterization was performed using FTIR (Fourier-Transform Infrared Spectroscopy), XRD, FE-SEM (Field Emission Scanning Electron Microscope), EDS (Energy Dispersive Spectroscopy), DLS (Dynamic Light Scattering), Pull-off, and AFM (Atomic Force Microscopy) analysis. The potentiodynamic polarization and EIS (Electrochemical Impedance Spectroscopy) were performed in the simulated body fluid... 

The high aspect ratio and unique thermal and electrical characteristics of carbon nanofiber (CNF) made it an ideal physical barrier against the penetration of corrosive ions. However, the poor compatibility of the CNF with the polymer matrix and the lack of active corrosion inhibitors are the key limitations of this nanomaterial, resulting in short-term anti-corrosion resistance. An intelligent self-healing epoxy (EP) coating, including CNF modified with a polydopamine (PDA)-La3+ complex, was successfully fabricated to overcome these issues. Electrochemical impedance spectroscopy (EIS) evaluation implied that mild steel (MS) submerged in a 3.5 wt % NaCl solution containing the CNF-PDA-La... 

In this study, the effects of unmodified calcium zinc phosphate (UCZP) and modified calcium zinc phosphate (MCZP) nanopigments (NPs) on the rheological, mechanical, and corrosion protection performance (CPP) of the epoxy (EP) coatings were investigated. Transmission electron microscopy (TEM) coupled with energy-dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS) were used to study morphology and overall chemical structure of synthesized calcium zinc phosphate (CZP) NPs, respectively. The grafting of methyltriethoxysilane (MTES) molecules on the surface of CZP was assessed using Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and... 

Magnesium (Mg) and its alloys have proved promising as biodegradable candidates for the repair of bone tissue. Despite the encouraging bio-related properties of Mg, its high corrosion rate in contact with body fluids still presents a major challenge. An efficient approach to address this issue is to provide a protective coating on Mg. The present research evaluates, for the first time, in vitro bioactivity and biocompatibility of a novel multifunctional composite coating based on poly(methyl methacrylate) (PMMA) biopolymer and bioactive glass (BG) particles on Mg-based implant. Electrophoretic deposition (EPD) was utilized to obtain this coating from a bi-component suspension. Coatings’... 

Bipolar Plates (BPPs) are the most crucial component of the Polymer Electrolyte Membrane (PEM) fuel cell system. To improve fuel cell stack performance and lifetime, corrosion resistance and Interfacial Contact Resistance (ICR) enhancement are two essential factors for metallic BPPs. One of the most effective methods to achieve this purpose is adding a thin solid film of conductive coating on the surfaces of these plates. In the present study, 410 Stainless Steel (SS) was selected as a metallic bipolar plate. The coating process was performed using titanium nitride and chromium nitride by the Cathodic Arc Evaporation (CAE) method. The main focus of this study was to select the best coating... 

To improve the biocompatibility and corrosion resistance of 316L SS (Stainless Steel) metal implants, HAp(hydroxyapatite)/TiO2/Al2O3 nanocomposite coating was created using dip sol-gel method sintered at 550 °C. The weight percentage of TiO2+ Al2O3 in these coatings was 20, 30, and 40% wt. In this study, characterization was performed using FTIR (Fourier-Transform Infrared Spectroscopy), XRD, FE-SEM (Field Emission Scanning Electron Microscope), EDS (Energy Dispersive Spectroscopy), DLS (Dynamic Light Scattering), Pull-off, and AFM (Atomic Force Microscopy) analysis. The potentiodynamic polarization and EIS (Electrochemical Impedance Spectroscopy) were performed in the simulated body fluid...