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    In vitro biological outcome of laser application for modification or processing of titanium dental implants

    , Article Lasers in Medical Science ; Volume 32, Issue 5 , 2017 , Pages 1197-1206 ; 02688921 (ISSN) Hindy, A ; Farahmand, F ; Tabatabaei, F. S ; Sharif University of Technology
    Abstract
    There are numerous functions for laser in modern implant dentistry including surface treatment, surface coating, and implant manufacturing. As laser application may potentially improve osseointegration of dental implants, we systematically reviewed the literature for in vitro biological responses to laser-modified or processed titanium dental implants. The literature was searched in PubMed, ISI Web, and Scopus, using keywords “titanium dental implants,” “laser,” “biocompatibility,” and their synonyms. After screening the 136 references obtained, 28 articles met the inclusion criteria. We found that Nd:YAG laser was the most commonly used lasers in the treatment or processing of titanium... 

    Efficient removal of some anionic dyes from aqueous solution using a polymer-coated magnetic nano-adsorbent

    , Article Journal of Water Supply: Research and Technology - AQUA ; Volume 66, Issue 4 , 2017 , Pages 239-248 ; 00037214 (ISSN) Kiani, A ; Haratipour, P ; Ahmadi, M ; Zare Dorabei, R ; Mahmoodi, A ; Sharif University of Technology
    Abstract
    For the efficient removal of some anionic dyes, a novel adsorbent was developed. The adsorbent was prepared by coating a synthetic polymer on magnetite nanosphere surface as a magnetic carrier. The synthesized nano-adsorbent was fully characterized using Fourier transform infrared spectroscopy (FT-IR), vibrating sample magnetometer, X-ray diffractometer, scanning electron microscope, and transmission electronic microscopy measurements. The synthesized nano-adsorbent showed high adsorption capacity towards removal of some anionic dyes (221.4, 201.6, and 135.3 mg g-1 for reactive red 195, reactive yellow 145, and reactive blue 19 dye, respectively) from aqueous samples. The dye adsorption was... 

    Electrodeposition of nanocrystalline Zn/Ni multilayer coatings from single bath: influences of deposition current densities and number of layers on characteristics of deposits

    , Article Applied Surface Science ; Volume 404 , 2017 , Pages 101-109 ; 01694332 (ISSN) Bahadormanesh, B ; Ghorbani, M ; Lotfi Kordkolaei, N ; Sharif University of Technology
    Abstract
    Zn/Ni nanocrystalline multilayer coatings were electrodeposited using single bath method and switching current densities. Effect of deposition current densities (i1 and i2) and number of layers (n) on composition, surface morphology and roughness, microhardness, phase structure and corrosion resistance of Zn/Ni multilayers were studied and compared with that of single layer. Analyzing and optimizing the influences of mentioned parameters on corrosion resistance of multilayers carried out through Response Surface Methodology. The model based on RSM results demonstrated that improvement in corrosion resistance due to increase in “difference of deposition current densities” was more effective... 

    Copper immobilized onto polymer-coated magnetic nanoparticles as recoverable catalyst for ‘click’ reaction

    , Article Applied Organometallic Chemistry ; Volume 31, Issue 5 , 2017 ; 02682605 (ISSN) Banan, A ; Bayat, A ; Valizadeh, H ; Sharif University of Technology
    Abstract
    Copper supported on polymer-coated magnetic nanoparticles was designed and synthesized as a separable heterogeneous catalyst. The catalyst was fully characterized using several techniques such as Fourier transform infrared and energy-dispersive X-ray spectroscopies, scanning and transmission electron microscopies, X-ray diffraction, vibrating sample magnetometry, thermogravimetric analysis and inductively coupled plasma atomic emission spectrometry. All results showed that copper was successfully supported on the polymer-coated magnetic nanoparticles. Also, results showed that the synthesized material can be used as an efficient catalyst for the preparation of a series of 1,4-disubstituted... 

    Structural and corrosion characterization of hydroxyapatite/zirconium nitride-coated AZ91 magnesium alloy by ion beam sputtering

    , Article Applied Surface Science ; Volume 401 , 2017 , Pages 172-180 ; 01694332 (ISSN) Kiahosseini, S. R ; Afshar, A ; Mojtahedzadeh Larijani, M ; Yousefpour, M ; Sharif University of Technology
    Abstract
    The adhesion of hydroxyapatite (HA) as a coating for the AZ91 magnesium alloy substrate can be improved by using the sputtering method and an intermediate layer, such as ZrN. In this study, HA coatings were applied on ZrN intermediate layers at a temperature of 300 °C for 180, 240, 300, 360, and 420 min by ion beam sputtering. A profilometer device was used to study the HA coating thickness, which changed from 2 μm for the 180-min deposition to 4.7 μm for 420-min deposition. The grazing incidence X-ray diffraction analysis method and the Williamson–Hall analysis were used for structural investigation. As the deposition time increased, the crystalline size increased from 50 nm to 690 nm.... 

    Axisymmetric time-harmonic response of a surface-stiffened transversely isotropic half-space

    , Article Meccanica ; Volume 52, Issue 1-2 , 2017 , Pages 183-196 ; 00256455 (ISSN) Eskandari, M ; Samea, P ; Ahmadi, S. F ; Sharif University of Technology
    Abstract
    This study deals with the elastodynamic response of a surface-stiffened transversely isotropic half-space subjected to a buried time-harmonic normal load. The half-space is reinforced by a Kirchhoff thin plate on its surface. By virtue of a displacement potential function and appropriate time-harmonic Green’s functions of transversely isotropic half-spaces, a robust solution corresponding to two plate-medium bonding assumptions, namely (a) frictionless interface, and (b) perfectly bonded interface is obtained for the first time. All elastic fields of the problem are expressed explicitly in the form of semi-infinite line integrals. Results of some limiting cases including isotropic materials,... 

    Mechanism of Al-Si codeposition on In738LC through single-step diffusion process

    , Article International Journal of Surface Science and Engineering ; Volume 11, Issue 1 , 2017 , Pages 1-11 ; 1749785X (ISSN) Nikzad, S ; Abdi, M ; Rastegari, S ; Sharif University of Technology
    Abstract
    The out-of-pack cementation method was applied to coat the Nickel-based super alloy IN738LC with Si-modified aluminide. Different mixtures of the pack containing pure Al, Si, alumina powders as an inert filler, and NH4Cl as a halide salt activator were used for co-deposition at 950 and 1,050°C. The results showed although the amount of subhalide vapour pressures of Al and Si were equal at 1,050°C, Al atoms diffused only after Si atoms had been deposited. Before heat treatment, the coating thickness formed by the pack containing 2.3 wt.% Al was 6 μm more than that containing 3.5 wt.% Al. After heat treatment, thickening coatings formed within the pack containing 2.3 wt.% Al was less than that... 

    Facile fabrication of superhydrophobic nanocomposite coating using modified silica nanoparticles and non-fluorinated acrylic copolymer

    , Article Polymer Bulletin ; Volume 75, Issue 10 , 2018 , Pages 4641-4655 ; 01700839 (ISSN) Pourjavadi, A ; Esmaili, H ; Nazari, M ; Sharif University of Technology
    Abstract
    A superhydrophobic nanocomposite coating was fabricated using a simple procedure. The nanocomposite is composed of an acrylic copolymer and modified silica nanoparticles. The acrylic copolymer was prepared by free radical copolymerization of methyl methacrylate and dodeycl methacrylate monomers. Silica nanoparticles were synthesized and modified with an alkyl silane reagent, hexadecyltrimethoxysilane. A mixture of acrylic copolymer and modified silica nanoparticles, dispersed in dichloromethane, was then sprayed on glass and filter paper surface. Chemical composition and structure of the coatings were investigated by FTIR, FESEM, AFM, 1H-NMR and GPC. The wettability of the prepared coating... 

    Preparation of new superhydrophobic and highly oleophobic polyurethane coating with enhanced mechanical durability

    , Article Applied Surface Science ; Volume 454 , 2018 , Pages 201-209 ; 01694332 (ISSN) Yousefi, E ; Ghadimi, M. R ; Amirpoor, S ; Dolati, A ; Sharif University of Technology
    Abstract
    In this study, a noble robust superhydrophobic and highly oleophobic polyurethane (PU)–SiO2 nanoparticle (NP) coating is specially designed using sol-gel process. For this purpose the effective parameters on surface tension and durability of the synthesized coating investigated and optimized. This new superhydrophobic and highly oleophobic coating exhibits good pensile hardness as high as 6H with adhesive force grade of 5B and repels water and oil with contact angles (CAs) of 159° and 140° respectively. The synthesized PU-SiO2 composite also retains an excellent amphiphobicity after a 7 days immersion in water with water and oil with CAs of 150° and 130°. Facile fabrication of PU–SiO2...