Sharif Digital Repository

This work concerns with experimental and analytical investigation of role of ultrasonic wave radiation in relative permeability of both wetting and non-wetting phases in a free gravity drainage process in porous media under the influence of ultrasonic wave. Glass beads ranged from 70 to 100 mesh sizes were packed and used in the tests. The working fluids consist of distilled water, kerosene and Doroud and Paidar crude oils as wetting and air as non-wetting phase. The measured oil recovery data along with Hagoort (1984) backward methodology were used to determine and to compare the relative permeability of wetting phases in presence and absence of ultrasonic radiation. In addition, the... 

The present work investigated the outdoor performance of a basin type multi-stage solar still as well as the effect of collector over basin area (CBA) ratio on the distillate production. The effect of CBA was studied in outdoor experiments for the first time. The system consisted of a still coupled with one, two or three flat-plate solar collectors. In order to study the effect of CBA more accurately, the experiments were conducted in both winter and summer. In these experiments, the distilled water production of the multi-stage still was measured during the whole 24. h of a day on an hourly basis. The results revealed that in the winter, the basin coupled to one solar collector (CBA. =... 

In the current work, synthesis of an environmental-sensitive superabsorbent hydrogel using γ-rays is described. Grafted polyacrylonitrile onto a homogeneous solution of starch and kappa-Carrageenan hybrid backbones created a smart material with reversible behavior. The reaction parameters (i.e. acrylonitrile, starch and kappa-Carrageenan concentration, as well as γ-irradiation time) affecting the. water absorbency of the. hydrogel were optimized using the. Taguchi method, in order to achieve a hydrogel with high swelling capacity. FTIR spectroscopy was used for confirming the. structure of the final product and the morphology of the synthesized hydrogel was examined by a scanning electron... 

The aim of the work reported was to investigate the effect of bases and neutralization steps on hydrogel microstructures. A series of porous hydrogels with various pore sizes were prepared by neutralizing a conventional hydrogel after gel formation. Scanning electron microscopy was used to characterize the microstructure of the porous hydrogels. The morphology of the samples showed the pores were induced into the hydrogels by water evaporation and gas release resulting from the neutralization process. Experimental results indicated that the hydrogels had an absorbency of 200-220 and 48-50 g g-1 for distilled water and sodium chloride solutions, respectively. A simple method was used to... 

Petroleum production often involves simultaneous flow of three immiscible fluids through porous rock formations. The objective of this work is to experimentally measure two and three phase relative permeabilities and to evaluate the existing relative permeability prediction models. We used typical Berea sandstone with refined mineral oil, distilled water and nitrogen gas. The measurements were carried out at temperature of 23°C and pressure of 800 psi. Two and three phase relative permeability measurements were obtained using the steady state technique. The three-phase experiments are conducted in the imbibition mode. The flow rates of brine and gas were increased gradually and the oil rate... 

This study deals with the large-scale production of biosurfactant from soybean oil soapstock by Pseudomonas aeruginosa MR01. The production of biosurfactant was carried out in a newly designed bioreactor equipped with recycling flow under three operational conditions. Kinetic studies were conducted at both shake flask and 5-L bioreactor scales during fermentation in a soapstock medium. Mathematical equations were developed to model the kinetic patterns at both scales. RESULT: Statistical analyses demonstrated the goodness of fit, with regression r-squared, R2, between 0.97and 0.99 for different models. Furthermore, biosurfactant concentration in the bioreactor including the recycling flow,... 

A new unbreakable solid-phase microextraction fiber coating based on polyethylene terephthalate/graphene nanocomposite was developed. The nanocomposite coatings were prepared by an electrospinning technique using a polyethylene terephthalate (PET) polymer solution containing the dispersed graphene on the outer surface of a stainless-steel rod. The applicability of polyethylene terephthalate/graphene nanocomposite coatings was examined by extraction of organochlorine compounds (OCs) including heptachlor epoxide, aldrin, γ-HCH, and β-HCH from aqueous samples in headspace mode. Influential parameters on extraction efficiency such as polymer concentration, the weight ratio of components, the... 

Nowadays, one of the biggest concerns in the world is increasing the CO2 emissions and global warming due to the over-consumption of fossil fuels. In addition, under the intense market competition, the demand for more efficient systems with higher performance and lower energy consumption has escalated. Since the drag force contributes to a considerable percentage of the energy loss and reducing the performance, a large number of studies have been conducted to improve the surface characteristics and, subsequently, declining the drag force. Making the surface superhydrophobic is one of the most effective ways for this purpose. In this work, two different superhydrophobic surfaces using SiO2... 

The aim of this study is to provide a solution for supplying distilled water used in indirect water bath heaters in the pressure reduction stations. A particular type of distilled water production system consists of a typical solar still and a heat pipe heat exchanger was constructed for recovering heat from the exhaust of an indirect gas heater. The system was tested under the climatic conditions of Semnan-Iran. Experimental results showed that in active type, the average daily production rate of distilled water would be 2.06 times higher than passive type. Also, in the proposed system, the average daily energy efficiency and the exergy efficiency would be 65.5% and 41% higher than the... 

Temperature-sensitive hydrogels based on N-t-butylacrylamide (TBA), acrylamide (AAm), and sodium alginate were prepared by free radical polymerization method. Methylenebisacrylamide (MBA) and amonium persulfate (APS) were applied as water soluble crosslinker and initiator, respectively. The chemical structure of the hydrogels was confirmed by FT-IR spectroscopy and thermogravimetric analysis (TCA) methods. Morphology of the samples was examined by scanning electron microscopy (SEM). By changing the initial TBA/AAm mole ratios, hydrogels with different swelling properties were obtained. The rate parameters were found to be 2.0, 2.4, and 3.5 min for the superabsorbents with AAm/TBA weight... 

It is well known that the displacement efficiency of EOR processes is mainly affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of pores surfaces remains a topic of debate in the literature. Furthermore, a little is known about how the dispersed silica nanoparticles affect the microscopic/macroscopic recovery efficiency of heavy oils during common immiscible EOR processes such as water flooding. In this study, a series of injection experiments was performed on five-spot glass micromodel which is initially saturated with the heavy oil. Distilled water and dispersed silica nanoparticles in water (DSNW) at different values of weight percent... 

It is well known that the displacement efficiency of EOR processes is mainly affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of pores surfaces remains a topic of debate in the literature. Furthermore, a little is known about how the dispersed silica nanoparticles affect the microscopic/macroscopic recovery efficiency of heavy oils during common immiscible EOR processes such as water flooding. In this study, a series of injection experiments was performed on five-spot glass micromodel which is initially saturated with the heavy oil. Distilled water and dispersed silica nanoparticles in water (DSNW) at different values of weight percent... 

It is well known that the oil recovery is affected by wettability of porous medium; however, the role of nanoparticles on wettability alteration of medium surfaces has remained a topic of debate in the literature. Furthermore, there is a little information of the way dispersed silica nanoparticles affect the oil recovery efficiency during polymer flooding, especially, when heavy oil is used. In this study, a series of injection experiments were performed in a five-spot glass micromodel after saturation with the heavy oil. Polyacrylamide solution and dispersed silica nanoparticles in polyacrylamide (DSNP) solution were used as injected fluids. The oil recovery as well as fluid distribution in... 

The heat transfer characteristics and entropy generation rate of hybrid graphene-magnetite nanofluids under forced laminar flow that subjected to the permanent magnetic fields were investigated. For this purpose, a nanoscale reduced graphene oxide-Fe3O4 hybrid was synthesized by using graphene oxide, iron salts and tannic acid as the reductant and stabilizer. The thermophysical and magnetic properties of the hybrid nanofluid have been widely characterized and thermal conductivity has shown an enhancement of 11%. The experimental results indicated that the heat transfer enhancement of hybrid magnetite nanofluid compared to the case of distilled was negligible when no magnetic field was... 

Hydroxyapatite nanorods aligned with ultrahigh crystallinity and high-yield were successfully synthesized through a hydrothermal approach. In this experiment, a new composition of cetyltrimethylammonium bromide ((CH 3(CH2)15N+(CH3) 3Br-) was designated as CTAP)/Ca(NO3) 2/ (NH4)2HPO4/NaOH and distilled water under hydrothermal condition, to synthesize single crystal HAp nanorods with diameter of 20 ± 10 nm and length of 80 ± 20 nm, was introduced. Crystal phases were determined by X-ray diffraction (XRD). Scanning electron microscope (SEM) was applied to investigate the morphology. The microstructure of the HAp products were further observed by transmission electron microscope (TEM) and high... 

Covalently functionalized carbon nanoplatelets and non-covalent functionalized metal oxides nanoparticles (surfactant-treated) have been used to synthesize water-based nanofluids in this paper. To prove nanofluid stability, ultraviolet–visible (UV–vis) spectroscopy is used, and the results show that nanofluid is stable for sixty days for carbon and thirty days for metal oxides. The thermophysical properties are evaluated experimentally and validated with theoretical models. Thermal conductivities of f-GNPs, SiO2, and ZnO nanofluids are enhanced by 25.68%, 11.49%, and 15.42%, respectively. Lu-Li and Bruggeman's thermal conductivity models are correctly matched with the experimental data.... 

Covalently functionalized carbon nanoplatelets and non-covalent functionalized metal oxides nanoparticles (surfactant-treated) have been used to synthesize water-based nanofluids in this paper. To prove nanofluid stability, ultraviolet–visible (UV–vis) spectroscopy is used, and the results show that nanofluid is stable for sixty days for carbon and thirty days for metal oxides. The thermophysical properties are evaluated experimentally and validated with theoretical models. Thermal conductivities of f-GNPs, SiO2, and ZnO nanofluids are enhanced by 25.68%, 11.49%, and 15.42%, respectively. Lu-Li and Bruggeman's thermal conductivity models are correctly matched with the experimental data.... 

An aniline-based polymer was electrochemically prepared and applied as a new fiber coating for solid phase microextraction (SPME) of some priority phenols from water samples. The polyaniline (PANI) film was directly electrodeposited on the platinum wire surface in sulfuric acid solution using cyclic voltammetry (CV) technique. The efficiency of new coating was investigated using a laboratory-made SPME device and gas chromatography with flame ionization detection for the extraction of some phenols from the headspace of aqueous samples. The scanning electron microscopy (SEM) images showed the homogeneity and the porous surface structure of the film. The results obtained proved the ability of... 

Objective(s): Bioresorbable scaffolds have been advocated as the new generation in interventional cardiology because they could provide temporary scaffolds and then disappear with resorption. Although, the available stents in clinical trials exhibited biosafety, efficacy, no death, and no apparent thrombosis, Mg-substrate degradation on drug release has not been investigated. Materials and Methods: Therefore, more research has been needed to legitimize the replacement of current stents with Mg-based stents. UV-Vis spectrophotometer, scanning electron microscope (SEM), X-ray diffraction (XRD), pH measurement, H2 evolution, and corrosion tests determined the change in hybrid properties and... 

In the present work, the roles of inorganic oxide nanoparticles on the extraction efficiency of polyethylene terephthalate-based nanocomposites were extensively studied. Four fiber coatings based on polyethylene terephthalate nanocomposites containing different types of nanoparticles along with a pristine polyethylene terephthalate polymer were conveniently electrospun on stainless steel wires. The applicability of new fiber coatings were examined by headspace-solid phase microextraction of some environmentally important volatile organic compound such as benzene, toluene, ethylbenzene and xylene (BTEX), as model compounds, from aqueous samples. Subsequently, the extracted analytes were...