Sharif Digital Repository

LiNi0.8Co0.1Mn0.1O2 (NCM811) has been considered as a promising cathode for Li-ion batteries (LIBs) due to its high electrochemical capacity and low cost; however, poor cycling stability is one of the main restricting factors in industrial applications of the NCM811 cathode material. Notably, the capacity fading and low structural stability of NCM811 are intensified at elevated temperatures. ZrO2- and composite rGO-ZrO2-coated NCM811 were fabricated by a facile wet chemical method and evaluated at 25 and 55 °C to overcome these impediments. The ZrO2 coating provides superior cycling and thermal stability and perfectly protects the cathode active material from deleterious side reactions, and... 

Digital Elevation Models (DEMs) play a significant role in hydraulic modeling and flood risk management. This study initially investigated the effect of Unmanned Aerial Vehicle (UAV) DEM resolutions, ranging from 1 m to 30 m, on flood characteristics, including the inundation area, mean flow depth, and mean flow velocity. Then, the errors of flood characteristics for global DEMs, comprising ALOS (30 m), ASTER (30 m), SRTM (30 m), and TDX (12 m) were quantified using UAV DEM measurements. For these purposes, the HEC-RAS 2D model in steady-state conditions was used to simulate the flood with return periods of 5- to 200 years along 20 km reach of Atrak River located in northeastern Iran.... 

In this research, a site selection method for wind-compressed air energy storage (wind-CAES) power plants was developed and Iran was selected as a case study for modeling. The parameters delineated criteria for potential wind development localities for wind-CAES power plant sites. One important consequence of this research was the identification of the wind energy potential for wind-CAES sites. The theoretical wind energy potential of Iran of greater than 50 W/m2 was identified from a wind atlas of Iran. The model produced factor maps by considering the boundary conditions of the input data and created geo-databases from the outputs maps. The main factor maps were electrical grids and... 

Cardiovascular diseases are very common and are one of the main reasons of death. Being among the major types of these diseases, correct and in-time diagnosis of coronary artery disease (CAD) is very important. Angiography is the most accurate CAD diagnosis method; however, it has many side effects and is costly. Existing studies have used several features in collecting data from patients, while applying different data mining algorithms to achieve methods with high accuracy and less side effects and costs. In this paper, a dataset called Z-Alizadeh Sani with 303 patients and 54 features, is introduced which utilizes several effective features. Also, a feature creation method is proposed to... 

Two different hydroxyapatite based composites reinforced by oxide ceramic (20 wt%) nano crystals were synthesized by high-energy ball milling and sintered by pressure less technique. Alumina and titania nanoparticles as secondary phases improved densification and mechanical behavior of apatite and postponed its decomposition to the tricalcium phosphate (TCP) phases at elevated temperatures. Increasing the relative density of apatite using nano reinforcements leads to enhance the bending strength by more than 40% and 27% (as compared to the pure HA) and increase the hardness from 2.52 to 5.12 (Al2O3 composite) and 4.21 (TiO2 addition) GPa, respectively. Transmission electron microscopy (TEM),... 

Urmia Lake in the northwest of Iran is the second largest hyper-saline lake worldwide. During the past two decades, a significant water level decline has occurred in the lake. The existing estimations for the lake water balance are widely variable because the lake bathymetry is unknown. The main focus of this study is to extract the volume-area-elevation (V-A-L) characteristics of Urmia Lake utilizing remote sensing data and analytical models. V-A-L equations of the lake were determined using radar altimetry data and their concurrent satellite-derived surface data. Next, two approximate models, a power model (PM) and a truncated pyramid model (TPM), were parameterized for Urmia Lake and... 

Tungsten composites are interesting materials for high temperature applications. These composites are conventionally produced by solid state reaction, where elevated temperatures and long sintering processes are inevitable, and generally produce volatile components that increase defects and impair the properties of the composites for high temperature applications. In the present paper, synthesis of dense near net-shaped transition metal-metal carbide by reaction casting is studied, which creates a potential application for the composite at 2000 C. Since the pores of the ceramic preform are filled with reaction products, this technique is referred to as displacive compensation porosity (DCP).... 

Aluminum reinforced with a large amount (up to about 55 vol.%) of Al 3Ti particles can be fabricated from Al-20Ti elemental nanometer-sized powder mixture via in-situ two step hot press sintering (TSS). For production of intermetallic reinforced in-situ composite, TSS can provide elevated temperature to facilitate the formation of intermetallic phase in situ and hot consolidation to form a fully dense solid. The first step sintering was employed at a higher temperature to obtain an initial high density, and the second step was held at a lower temperature by isothermal sintering for more time than the first one to increase bulk density without significant grain growth. The optimum TSS regime... 

Elevation angle is one of the most significant parameters of land mobile satellite channels, subject to rapid variations in the case of Low Earth Orbit (LEO) satellite systems. In this paper a novel trace-based framework is proposed and analyzed which is capable of predicting elevation angle as a function of time during satellite visibility window. Trace-time based modeling makes the framework practical for real-time evaluation of elevation angle and its alteration incurred by communication links in LEO satellite systems. The proposed method is particularly suitable for development of communication channel models and services in mobile LEO satellite networks where path variability is of... 

Variational principle is used to derive the nonlinear response of the floating roof of cylindrical liquid storage tanks due to harmonic base excitations. The formulation accounts for nonlinearity due to large deflections of the floating roof. The derived nonlinear governing equation for the sloshing response of the floating roof has a cubic nonlinear stiffness term similar to the well known Duffing equation. It is shown that accounting for large deflections could substantially reduce the wave elevation for near resonance harmonic excitations. Evaluating the response of the nonlinear model for increasing amplitudes of near resonance harmonic excitations gives rise to the appearance of sub and... 

A simple bio-conjugation procedure to surround a single horseradish peroxidase (HRP) enzyme molecule with dendritic polyester macromolecules (polyester-32-hydroxyl-1-carboxyl bis-MPA dendron, generation 5) was proposed. The characterization of resultant nanoparticles entitled HRP dendrozyme, was performed by transmission electron microscopy, dynamic light scattering, gel permeation chromatography and Fourier transform infrared spectroscopy. The results showed that HRP nanoparticles were spherical in shape and have an average size of 14 ± 2. nm in diameter. Furthermore, bio-conformational characterization of HRP dendrozyme was performed by means of circular dichroism and fluorescence... 

The main attempt of this paper is to present a new methodology to model a generic low-level flight close to terrain, which guarantees terrain collision avoidance. Benefiting the advantages of high-speed computer technology, this method uses satellite elevation maps to generate so-called "quad-tree forms". The latter is then used to find the optimal trajectories for low-level flights. The novelty of this approach, entitled the "cost map," lies in the integration of aircraft dynamics into the segmented map. This procedure results in some near-optimal trajectories with respect to aircraft dynamics that could easily be used for minimization of flight path together with pilot effort. Different... 

A simple and efficient method was developed for fabricating spherical granules of CuO catalyst via a three-step procedure. In the first step, copper oxide nanoparticles were synthesized by hydrothermal decomposition of copper nitrate solution under supercritical condition. Then, they were immobilized in the polymeric matrix of calcium alginate, and followed by high-temperature calcination in an air stream as the third step, in which carbonaceous materials were oxidized, to result in a pebble-type catalyst of high porosity. The produced CuO nanoparticles were characterized by transmission electron microscopy (TEM) that revealed an average size of 5 nm, X-ray diffractometry (XRD), and thermo... 

In this paper, a constitutive model with a temperature and strain rate dependent flow stress (Bergstrom hardening rule) and modified Armstrong-Frederick kinematic evolution equation for elastoplastic hardening materials is introduced. Based on the multiplicative decomposition of the deformation gradient,new kinematic relations for the elastic and plastic left stretch tensors as well as the plastic deformation-dependent spin tensor are proposed. Also, a closed-form solution has been obtained for the elastic and plastic left stretch tensors for the simple shear problem.To evaluate model validity, results are compared with known experimental data for SUS 304 stainless steel, which shows a good... 

Microstructural development and phase formation at the interface of yttria stabilized zirconia (3Y-TZP)/430L stainless steel composite layers produced by co-sintering method were studied by SEM, HRTEM, micro-focus XRD, and EPMA. Formation of a rich chromium boundary layer at the interface was noticed, which revealed Cr aggregation at the interface at the elevated temperatures. Misfit dislocations were also observed at the joint interface to tackle the mismatch crystallographic orientations between the ceramic and metal layer. The results of the micro-focus XRD showed formation of no new phases at the boundary zone. Microstructural studies also revealed a retarded grain growth in the... 

The aim of the present study is to provide an Atlas of IRAN Offshore Renewable Energy Resources (hereafter called 'the Atlas') to map out wave and tidal resources at a national scale, extending over the area of the Persian Gulf and Sea of Oman. Such an Atlas can provide necessary tools to identify the areas with greatest resource potential and within reach of present technology development. To estimate available tidal energy resources at the site, a two-dimensional tidally driven hydrodynamic numerical model of Persian Gulf was developed using the hydrodynamic model in the MIKE 21 Flow Model (MIKE 21HD), with validation using tidal elevation measurements and tidal stream diamonds from... 

In this paper the main goal is to evaluate the vertical and slant bolted endplate connections performance in steel moment frame structures under thermal effect in elastic field, and by a finite element software. the connections are simulated to complete and verify simple modeling of analytical and numerical analysis of the behavior of vertical and slant bolted endplate connections due to increase in temperature. The results that are obtained from performance of a vertical bolted endplate connection and a slant bolted endplate connection due to increase in temperature will be compared  

Evaporation of polymeric solid fuels in backward facing step geometry subject to an inlet oxidizer flow at elevated temperatures is considered and convective heating of the fuel surface by the hot oxidizing inlet flow and subsequent mixing of the evaporated fuel with the oxidizer flow and its combustion is numerically studied. The objective of this work is to gain insight into the auto-ignition of the fuel and its controlling parameters in this configuration. The system of governing equations is solved with a finite volume approach using a structured grid in which the AUSM scheme is used to calculate the gas phase convective fluxes. The flowfield is turbulent and the SpalartAllmaras... 

In this paper, dynamic ageing characteristics associated with the application of equal channel angular pressing (ECAP) to Al6061 alloy at elevated temperatures was investigated. Followed by ECAP, Vickers microhardness measurement on the cross-sectional planes and microstructural observations were undertaken using transmission electron microscopy. The combination of the ECAP process with dynamic ageing at both 100°C and 150°C resulted in a significant increase in hardness. The grain size was measured as ∼160. nm after four passes. A comparison with the published data on the same alloy processed by ECAP at room temperature and statically aged, suggests several advantages in incorporating... 

Friction and wear behaviors of artificially aged 2024 Al and 2024 Al/20 vol.% SiC composite prepared by powder metallurgy method were investigated in the temperature range 20250 °C. Dry sliding wear tests were conducted at a constant sliding velocity of 0.5 m/s, an applied load of 20 N, and a sliding distance of 2500m using a pin-on-disc apparatus. Worn surfaces and wear debris were also examined by using SEM and EDS techniques. All specimens showed a transition from mild-to-severe wear above a critical temperature. In the mild wear regime, the wear rate and the friction coefficient of the composite specimen were higher than those of the unreinforced alloy. The SiC particles led to an...