Sharif Digital Repository

A generic framework is developed to study the application of energy hubs and its related network model to demonstrate the optimal design and operation of distributed energy systems (DESs) in urban areas. A novel multi-objective approach based on augmented epsilon constraint technique is employed to carry out this work. As an illustrative example, the proposed model is applied to an urban area in Ontario, Canada. Different scenarios are defined to investigate the effect of energy storage systems and energy exchange within a network on the optimal configuration and operation of the system. Moreover, multi-objective optimization is carried out based on two conflicting objectives, namely, total... 

Miniaturization of electronic devices with portable, flexible and wearable characteristics created a great demand for high-performance microscale energy storage devices with lightweight and flexible properties. Among the energy storage devices, wire-shaped supercapacitors (WSSCs) have recently received tremendous attention due to their tiny volume, wearability, high flexibility and potential applications in the next-generation portable/wearable electronic devices. Herein, we successfully fabricated a porous dendritic Ni-Cu film on Cu wire substrate (CWE) for fabrication of high-performance wire-type supercapacitors. The porous structure with dendritic morphology provides a high surface area,... 

In the field of energy storage by high-rate supercapacitors, there has been an upper limit for the total interfacial capacitance of carbon-based materials. This upper limit originates from both quantum and electric double-layer capacitances. Surpassing this limit has been the focus of intense research in this field. Here, we precisely investigate the effect of chemical functional groups and physical confinement on the electrochemical performance of graphene nanoribbons. We present the results of a quasi-one-dimensional single-layer graphene nanoribbon (120 nm in width and -100 μm in length) microelectrode fabricated by mechanical exfoliation of graphite, followed by electron beam lithography... 

Demand increasing for next generation portable and miniaturized electronics has aroused much interest to explore microscale and lightweight energy storage devices. Herein, we demonstrate successful development of flexible wire-shaped micro-supercapacitors (micro-SCs) based on novel CoNi2S4/E-NZP film@Cu wire electrode. The etched Ni-Zn-P (E-NZP) film was synthesized by directly deposition of NZP film on Cu wire, followed by a chemical etching process. Alkaline etching treatment provides a micro- and mesoporous structure with high surface area and facilitates the penetration of electrolyte ions into the electrode matrix. Then, CoNi2S4 nanosheets as electroactive material are electrochemically... 

Imidazolium-based ionic liquids (ILs) have been perceived as a promising candidate for bridging polyaniline (PANI) on well-dispersed carbon nanotubes (CNTs) via formation of IL-stabilized multiwalled carbon nanotubes (MWCNTs) dispersion in which outer walls of CNTs, as well as benzene rings of the aniline monomer and the growing polymer, have been potently effective in such procurement. The sulfonated water-soluble PANI-[C16C1im]Cl-MWCNT nanocomposites (SPANI-IL-MWCNTs) are directly deposited on a graphite-based current collector using a simple and cost-effective electrophoretic deposition (EPD) method. The SPANI-IL-MWCNT electrodes exhibit remarkable electrochemical performance compared to... 

The development of asymmetric supercapacitors requires the design of electrode construction and the utilization of new electroactive materials. In this regard, an effective strategy is the loading of active materials on an integrated 3D porous graphene-based substrate such as graphene foam (GF). Herein, we successfully designed and fabricated a novel ternary binder-free nanocomposite consisting of polypyrrole, Fe-Co sulfide, and reduced graphene oxide on a nickel foam electrode (PPy/FeCoS-rGO/NF) via a facile, cost-effective, and powerful electrodeposition method for application in high-performance asymmetric supercapacitors. The monolithic 3D porous graphene foam (GF) obtained by the facile... 

Inkjet-printing (IJP) technology is recognized as a significant breakthrough in manufacturing high-performance electrochemical energy storage systems. In comparison to conventional fabrication protocols, this printing technique offers various advantages, such as contact-less high-resolution patterning capability; low-cost, controlled material deposition; process simplicity; and compatibility with a variety of substrates. Due to these outstanding merits, significant research efforts have been devoted to utilizing IJP technology in developing electrochemical energy storage devices, particularly in supercapacitors (SCs). These attempts have focused on fabricating the key components of SCs,... 

Nickel-zinc batteries as safe and economic energy storage devices suffer from lack of high electrochemical performance of cathode materials. Herein, a new cathode material for rechargeable Ni/Zn batteries is introduced based on various compositions of mixed metal oxide (MMO) through a calcination process of nickel-vanadium layered double hydroxide at different temperatures. The results demonstrated that the prepared sample at 500 °C presents the best electrochemical properties such as a good electrochemical discharge capacity (278.4 mAh g-1 at 0.5 A g-1), good cycle life (capacity retention of 74% after 1000 cycles at 5 A g-1), and excellent rate capability (177 mAh g-1 at 5 A g-1). These... 

Demand for high-capacity, long cycle life, and aqueous batteries based on abundant metals such as nickel, zinc, aluminum, and so on is rising in the energy storage field. In this study, we design a hierarchical morphology as a nanosheet-built microsphere of nickel vanadium layered double hydroxide (NiV LDH) with conductive agents graphene oxide (GO) and multiwalled carbon nanotubes (CNTs) through a low-cost hydrothermal synthesis method. The experimental results demonstrate that the graphitic structures and functional groups of the GO and CNT play an important role in controlling nucleation, growth speed, size, and finally morphology of hierarchical nanosheets. The electrochemical results... 

Interest in carbon nanomaterials for energy storage systems such as supercapacitors has enormously risen due to their attractive electrical conductivity, chemical inertness, and charge storage capacity. The reduction of graphitic oxide is a versatile procedure to prepare 3D graphene. Despite many green methods, the dynamics behind ultrafast thermal graphitization have remained elusive. Here, we demonstrate an effort to understand the graphitization mechanism of graphitic oxide under ultrafast thermal reduction induced by electromagnetic radiation and probably via Ar+ cation collisions. The low photon energy (10.5 μeV) locally removes oxygen functionalities and restores the π-conjugated... 

Wire-shaped micro-supercapacitors attracted extensive attentions in next-generation portable and wearable electronics, due to advantages of miniature size, lightweight and flexibility. Herein, NiMoO 4 nanorods supported on Ni film coated Cu wire are successfully fabricated thorough direct deposition of Ni film onto Cu wire as the conductive substrate, followed by growth of the NiMoO 4 nanorods on Ni film coated Cu wire substrate by means a hydrothermal annealing process. The prepared 3D, porous electrode demonstrates extremely high areal specific capacitance of 12.03F cm −2 at the current density of 4 mA cm −2 and retained capacitance of 8.23 F cm −2 at a much higher current density of 80... 

Evolution of renewable energies in the era of the modernized world has been strongly tied up to the incessant development of high-performance energy storage systems benefiting from both high energy and power densities. In the present work, binder-free positive electrodes are fabricated via a facile electrochemical deposition route in which copper oxide nanorods (CuO NRs) directly grown onto the copper foam (CF) are decorated with bimetallic cobalt-zinc sulfide nanoarrays (Co-Zn-S NAs). The fabricated Co-Zn-S@CuO-CFs represent promising specific capacity of 317.03 C.g−1 at 1.76 A.g−1, along with superior cyclic stability (113% retention after 4500 cycles). Negative electrodes were further... 

Evolution of renewable energies in the era of the modernized world has been strongly tied up to the incessant development of high-performance energy storage systems benefiting from both high energy and power densities. In the present work, binder-free positive electrodes are fabricated via a facile electrochemical deposition route in which copper oxide nanorods (CuO NRs) directly grown onto the copper foam (CF) are decorated with bimetallic cobalt-zinc sulfide nanoarrays (Co-Zn-S NAs). The fabricated Co-Zn-S@CuO-CFs represent promising specific capacity of 317.03 C.g−1 at 1.76 A.g−1, along with superior cyclic stability (113% retention after 4500 cycles). Negative electrodes were further... 

To attain superior energy density concurrently with high power density, high-performance supercapacitors have been developed. Herein an innovative strategy has been adopted to fabricate unique binder-free electrodes composed of a unique porous structure of binary metal carbonate hydroxide nanomace-decorated hydrothermal porous carbon spheres (PCSs). Hierarchical nickel-cobalt carbonate hydroxide (NiCOCH) nanomaces, directly grown on PCSs, are used as positive electrodes for supercapacitors fabrication. Furthermore, Fe2O3@PCS composites, having benefits of highly reversible redox reaction in the negative potential window and highly porous structure, are employed as the negative electrode in... 

To attain superior energy density concurrently with high power density, high-performance supercapacitors have been developed. Herein an innovative strategy has been adopted to fabricate unique binder-free electrodes composed of a unique porous structure of binary metal carbonate hydroxide nanomace-decorated hydrothermal porous carbon spheres (PCSs). Hierarchical nickel-cobalt carbonate hydroxide (NiCOCH) nanomaces, directly grown on PCSs, are used as positive electrodes for supercapacitors fabrication. Furthermore, Fe2O3@PCS composites, having benefits of highly reversible redox reaction in the negative potential window and highly porous structure, are employed as the negative electrode in... 

Owing to wind power inherent characteristics and technical constraints of power systems operation, a considerable amount of wind energy cannot be delivered to load centers and gets curtailed. Transmission congestion together with temporal mismatch between load and available wind power can be accounted as the main reasons for this unpleasant event. This paper aims to concentrate on the wind energy curtailment for which it provides a combinatorial planning model to maximize wind power utilization. Jointly operating the wind power generation system with pumped hydro energy storage (PHES), the planning procedure tries to reach schemes with the minimum level of wind energy curtailment as well as... 

Electric energy storage (EES) installations in power systems are migrating from large centralized systems to more distributed installations for microgrid applications. This trend signifies modular EES installations for the local control of buildings and processes. A centralized EES system is often dispatched by grid operators for increasing the overall efficiency and enhancing the security of power systems. The distributed EES (DEES) is locally managed by aggregators to maximize the local impact of EES, before the aggregators' adjusted load profiles are submitted to grid operators for the day-ahead scheduling. In this paper, we present and analyze two models for the hourly scheduling of... 

In this research, a site selection method for wind-compressed air energy storage (wind-CAES) power plants was developed and Iran was selected as a case study for modeling. The parameters delineated criteria for potential wind development localities for wind-CAES power plant sites. One important consequence of this research was the identification of the wind energy potential for wind-CAES sites. The theoretical wind energy potential of Iran of greater than 50 W/m2 was identified from a wind atlas of Iran. The model produced factor maps by considering the boundary conditions of the input data and created geo-databases from the outputs maps. The main factor maps were electrical grids and... 

Aquifers are underground porous formations containing water. Confined aquifers are the formations surrounded by two impermeable layers, called cap rocks and bed rocks. These aquifers are suitable for seasonal thermal energy storage. In the present study, a confined aquifer was considered to meet the cooling and heating energy needs of a residential complex located in Tehran, Iran. Three different alternatives were analyzed in this aquifer thermal energy storage (ATES), including: using ATES for cooling alone, for cooling and heating, as a heat pump, and for heating alone, employing flat plate solar energy collectors. A numerical simulation, based on the finite difference method, was carried... 

The present study was aimed at performance and energy analysis of a hybrid wind-hydrogen power system. Such system consists of wind turbines, batteries for the short time energy storage, electrolyzer, fuel cell and hydrogen tank for long time energy storage. The proposed configuration is used to supply energy demand of a region with discrete seasonal wind speed regime. Temporary wind energy profiles restrict using batteries for electricity storage as they lose much electrical stored energy for the long time. Based on direct wind turbine usage, batteries and hydrogen storage, different energy supply strategies are introduced and analyzed to power the household electricity demand. The energy...